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US 12,168,748 B2Granted
Treated geothermal brine compositions with reduced concentration of silica, iron and lithium
AssigneeTerralithium LLC
InventorsStephen Harrison, John Burba, III
Life of this patent
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Abstract
This invention relates to treated geothermal brine compositions containing reduced concentrations of lithium, iron and silica compared to the untreated brines. Exemplary compositions contain concentration of lithium ranges from 0 to 200 mg/kg, concentration of silica ranges from 0 to 30 mg/kg, concentration of iron ranges from 0 to 300 mg/kg. Exemplary compositions also contain reduced concentrations of elements like arsenic, barium, and lead.
Claims9
A method for producing lithium hydroxide or lithium carbonate from a brine solution, the method comprising the steps of,
- providing a brine solution comprising lithium and silica;
- supplying the brine solution to a silica management step to remove silica from the brine solution to produce a silica-lean lithium containing solution;
- supplying the silica-lean lithium containing solution to a lithium capture step, the lithium capture step being operable to capture lithium from the silica-lean lithium containing solution, wherein the lithium capture step selectively isolates lithium from the silica-lean lithium containing solution;
- wherein the lithium capture step includes the step of contacting the silica-lean lithium containing solution with an intercalate operable to capture the lithium from the silica-lean lithium containing solution;
- recovering the lithium from the lithium capture step using wash water to produce a lithium-rich stream comprising at least one of calcium, magnesium, manganese or zinc, and
- contacting the lithium-rich stream with a base and a carbonate such that a portion of the at least one of calcium, magnesium, manganese or zinc present in the lithium-rich stream is removed as a solid precipitate to produce a purified lithium-rich stream comprising lithium hydroxide or lithium carbonate.
3 more elements
Dependencies are inferred from the claim text.