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US 12,163,031 B2Granted
Pigment preparations
AssigneeLANXESS Deutschland GmbH
InventorsStephan Michaelis, Sabine Endert, Frank Linke, Hans-Ulrich Borst
Life of this patent
Estimating the term…
Abstract
The novel pigment preparations containing at least one metal azo pigment A) and at least one aliphatic monocarboxylic acid B) having 10 to 22 carbon atoms are suitable for the colouring of plastics and in this connection feature improved heat stability.
Claims17
A pigment preparation comprising:
- i) a metal azo pigment A) containing the components
- a) at least two metal azo compounds of the formula (I) which differ at least in the metal ion Me, or the tautomeric forms thereof,
- in which
- R1 and R2 are each independently OH, NH2 or NHR5,
- R3 and R4 are each independently ═O or ═NR5,
- R5 is hydrogen or alkyl, and
- Me is a metal ion Me1 or Me2,
- wherein
- Me1 is Cu2+ or Ni2+ and Me2 is Zn2+, Al3+2/3, Fe2+, Fe3+2/3, Co2+, Co3+2/3, La3+2/3, Ce3+2/3, Pr3+2/3, Nd2+, Nd3+2/3, Sm2+, Sm3+2/3, Eu2+, Eu3+2/3, Gd3+2/3, Tb3+2/3, Dy3+2/3, Ho3+2/3, Yb2+, Yb3+2/3, Er3+2/3, Tm3+2/3, Mg2+, Ca2+, Sr2+, Mn2+, Y3+2/3, Sc3+2/3, Ti2+, Ti3+2/3, Nb3+2/3, Mo2+, Mo3+2/3, V2+, V3+2/3, Zr2+, Zr3+2/3, Cd2+, Cr3+2/3, Pb2+ or Ba2+,
- with the proviso that the amount of metal ions Me1 in total is 97 to 100 mol % and the amount of metal ions selected from the series Me2 in total is 0 to 3 mol %, based in each case on one mole of all compounds of the formula (I),
- and
- wherein the molar ratio of Cu to Ni metal ions in the sum total of the compounds of the formula (I) is 99.9:0.1 to 0.1:99.9,
- and
- b) at least one compound of the formula (II)
- in which
- R6 is hydrogen or alkyl,
- or a metal azo pigment A) prepared by reacting component a) with component b),
- and
- ii) at least one aliphatic monocarboxylic acid B) having 10 to 22 carbon atoms in an amount of from 70 to 210 g based on 1 mol of all metal azo compounds (I) present in the metal azo pigment A).
16 more elements
Dependencies are inferred from the claim text.