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US 12,145,906 B2Granted
Renewable chemical production engaging metathesis and microbial oxidation
AssigneeNeste Oyj
InventorsJukka Hietala, Jukka Räsänen, Anja Leminen, Virpi Rämö
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Abstract
A process for combined renewable 1-decene and renewable carboxylic diacid production from a fatty acid ester containing feedstock, wherein the feedstock is first subjected to metathesis reaction conditions, recovery of 1-decene and then to microbial oxidation to yield diacids in a fermentation broth. Diacids of unusual carbon chains lengths are thereby obtainable.
Claims23
A process for producing 1-decene and renewable carboxylic diacids from a C6-C22 fatty acid ester containing feedstock, the process comprising:
- a) providing the C6-C22 fatty acid ester containing feedstock, wherein the feedstock contains at least one unsaturated fatty acid ester;
- b) subjecting the feedstock to metathesis reaction conditions in a presence of (1) an alkene selected from the group consisting of a C2 alkene, a C3 alkene, a C4 alkene and a combination thereof, and (2) a metathesis catalyst, to obtain metathesis products containing renewable alkenes and fatty acid esters;
- c) recovering C10 alkenes, containing 1-decene from the metathesis products;
- d) subjecting a part of the metathesis products including the fatty acid esters to a pretreatment, wherein the pretreatment includes producing fatty acids from the fatty acid esters, and subjecting the fatty acids to microbial oxidation in a presence of genetically engineered microorganisms cultured in a liquid medium containing a carbon source and other nutrients, to yield a plurality of renewable diacids each having a carbon number from C10 to C15 in a fermentation broth;
- and
- e) recovering the plurality of renewable diacids from the fermentation broth.
3 more elements
Dependencies are inferred from the claim text.