Lubricating composition and method of lubricating an internal combustion engine
AssigneeThe Lubrizol Corporation
InventorsJohn G. Loop, Mary Galic Raguz
Life of this patent
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Abstract
The disclosed technology provides a lubricating composition and a method of lubricating an internal combustion engine where the lubricating composition contains an oil of lubricating viscosity, one or more metal-containing, sulfur-free, alkyl-phenol based detergents, an alkaline earth metal sulfonate detergent, a polyisobutenyl succinimide dispersant, and a dispersant viscosity modifier having a number average molecular weight of at least 20,000. The lubricating composition of the present invention can be formulated to have lower HTHS viscosity, and reduced phosphorous content, while providing protection against adhesive wear.
Claims15
A low viscosity lubricating composition, comprising:
- a) an oil having a viscosity of 4.5 to 6.5 cSt;
- b) up to 0.45 weight percent of one or more metal-containing sulfur-free alkyl-phenol based detergents derived from an alkylphenol in an amount to deliver at least 0.2 wt % alkylphenol-containing soap to the composition;
- c) one or more alkaline earth metal sulfonate detergents in an amount to deliver at least 0.8 wt % by weight sulfonate soap to the composition;
- and
- d) 1 wt % to 4 wt % of one or more polyisobutylene succinimide dispersants;
- and
- e) 0.2 wt % to 1 wt % of a mixture of dispersant viscosity modifiers-, wherein the mixture of dispersant viscosity modifiers comprises at least one low molecular weight dispersant viscosity modifier having a number average molecular weight of less than 8,000 and one high molecular weight dispersant viscosity modifier having a number average molecular weight of 60,000 to 100,000;
- wherein the lubricating composition contains less than 0.2 wt % of a sulfur-coupled phenate detergent and wherein the lubricating composition has a high temperature high shear viscosity measured by ASTM D4683 of less than 3.5 cP at 150° C.
A method of lubricating a compression ignition internal combustion engine comprising supplying to the engine a low phosphorus lubricant composition comprising:
- a) an oil having a viscosity of 4.5 to 6.5 cSt;
- b) up to 0.45 weight percent of one or more metal-containing sulfur-free alkyl-phenol based detergents in an amount to deliver at least 0.2 wt % alkylphenol-containing soap to the composition;
- c) one or more alkaline earth metal sulfonate detergents in an amount to deliver at least 0.8 wt % sulfonate soap to the composition;
- d) 1 wt % to 4 wt % of one or more polyisobutylene succinimide dispersants;
- e) 0.2 wt % to 1 wt % of a mixture of dispersant viscosity modifiers wherein the mixture of dispersant viscosity modifiers comprises at least one low molecular weight dispersant viscosity modifier having a number average molecular weight of less than 8,000 and one high molecular weight dispersant viscosity modifier having a number average molecular weight of 60,000 to 100,000;
- wherein the composition contains less than 0.2 wt % of a sulfur-coupled phenate detergent and wherein the lubricant composition has a high temperature high shear viscosity measured by ASTM D4683 of less than 3.5 cP at 150° C.
A method of reducing adhesive wear in a compression engine lubricated with a low phosphorus lubricant composition, comprising supplying to the engine a lubricant composition comprising:
- a) an oil having a viscosity of 4.5 to 6.5 cSt;
- b) up to 0.45 weight percent of one or more metal-containing sulfur-free detergents derived from an alkylphenol in an amount to deliver at least 0.2 wt % alkylphenol-containing soap to the composition;
- c) one or more alkaline earth metal sulfonate detergents in an amount to deliver at least 0.8 wt % by weight sulfonate soap to the composition;
- d) 1 wt % to 4 wt % of one or more polyisobutylene succinimide dispersants;
- and
- e) 0.1 wt % to 1 wt % of a mixture of dispersant viscosity modifiers wherein the mixture of dispersant viscosity modifiers comprises at least one low molecular weight dispersant viscosity modifier having a number average molecular weight of less than 8,000 and one high molecular weight dispersant viscosity modifier having a number average molecular weight of 60.000 to 100,000;
- wherein the lubricant composition contains less than 0.2 wt % of a sulfur-coupled phenate detergent and wherein the lubricant composition has a high temperature high shear viscosity measured by ASTM D4683 of less than 3.5 cP at 150° C.
Dependencies are inferred from the claim text.