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US 12,122,976 B2Granted
Refrigerating machine oil
AssigneeEneos Corporation
InventorsFumiyuki Nara, Yohei Shono, Hidetoshi Ogata
Life of this patent
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Abstract
An aspect of the present invention provides a refrigerating machine oil containing: a lubricating base oil; a phosphorus-containing additive; and a polymer comprising an unsaturated carboxylic acid ester as a monomer unit.
Claims5
A refrigerating machine oil comprising:
- a lubricating base oil comprising a mineral oil;
- a phosphorus-containing additive comprising at least one selected from the group consisting of triphenyl phosphate, tricresyl phosphate and triphenyl phosphorothionate;
- and
- a polymer selected from the group consisting of:
- (I) a copolymer comprising at least one of a first (meth)acrylic acid ester and at least one of a second (meth)acrylic acid ester, as monomer units, the first (meth)acrylic acid ester having a linear alkyl group having 1 to 18 carbon atoms, and the second (meth)acrylic acid ester having a 2-position branched alkyl group having 4 or more and less than 20 carbon atoms, wherein the copolymer of (I) is selected from:
- (i) a copolymer consisting of the first (meth)acrylic acid alkyl ester and the second (meth)acrylic acid alkyl ester, as monomer units, and
- (ii) a copolymer consisting of the first (meth)acrylic acid alkyl ester, the second (meth)acrylic acid alkyl ester and an α-olefin having 8 to 12 carbon atoms, as monomer units;
- and
- (II) a copolymer consisting of a maleic acid ester and an α-olefin having 8 to 12 carbon atoms, as monomer units, wherein the maleic acid ester is an ester of maleic acid and an alcohol comprising a linear aliphatic alcohol having 4 to 10 carbon atoms,
- wherein the polymer has a number average molecular weight (Mn) of 4000 or more and 20000 or less, a weight average molecular weight (Mw) of 8000 or more and 30000 or less, and an Mw/Mn of 1.2 or more and 2.5 or less,
- wherein the refrigerating machine oil has a kinematic viscosity at 40° C. of 10 mm2/s or less, and is used with a refrigerant, and
- wherein
- a content of the lubricating base oil is 90% by mass or more,
- a content of the phosphorus-containing additive is 0.1% by mass or more and 3% by mass or less, and
- a content of the polymer is 0.5% by mass or more and 5% by mass or less, based on the total amount of the refrigerating machine oil.
12 more elements
Dependencies are inferred from the claim text.