# US 12,117,769 B2 · Method for producing recycled carrier, method for producing recycled electrostatic charge image developer, image forming method, and recycled carrier

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- Number: US 12,117,769 B2
- Document ID: US12117769B2
- Status: Granted
- Kind: B2
- Application number: 17/459,258
- Filed: 2021-08-27
- Published: 2022-09-29
- Granted: 2024-10-15
- Earliest claimed: 2021-03-23
- Assignees: FUJIFILM Business Innovation Corp.
- Applicants: FUJIFILM Business Innovation Corp.
- Inventors: Takeshi Tanabe; Yosuke Tsurumi; Shintaro Anno
- Web page: https://patentgrep.com/patent/US12117769B2

## CPC

- G03G 9/1131: {Coating methods; Structure of coatings}
- G03G 9/108: {Ferrite carrier, e.g. magnetite}
- G03G 9/1133: {obtained by reactions only involving carbon-to-carbon unsaturated bonds}
- G03G 15/08: using a solid developer, e.g. powder developer
- G03G 15/75: {Details relating to xerographic drum, band or plate, e.g. replacing, testing (electrographic recording members per se G03G5/00)}
- G03G 15/752: {with renewable photoconductive layer}
- G03G: ELECTROGRAPHY; ELECTROPHOTOGRAPHY; MAGNETOGRAPHY

## Abstract

A method for producing a recycled carrier includes: performing classification, the classification including separating a carrier having a coating layer from a collected developer by a centrifugal air classifier, the collected developer containing the carrier and being obtained by collecting an electrostatic charge image developer remaining after image formation; and performing recoating, the recoating including dissolving or thermally melting a coating resin of the separated and classified carrier and then coating the resulting carrier again to produce a recycled carrier.

## Claims

### Claim 1

A method for producing a recycled carrier, the method comprising:
performing classification, the classification including separating a carrier having a coating layer from a collected developer by a centrifugal air classifier, the collected developer containing the carrier and being obtained by collecting an electrostatic charge image developer remaining after image formation; and
performing recoating, the recoating including dissolving or thermally melting a coating resin of the separated and classified carrier and then immediately coating the resulting carrier with the resulting coating resin again to produce a recycled carrier.

### Claim 2 (depends on 1)

The method for producing a recycled carrier according to claim 1, wherein the classification involves eliminating particles having a particle size of 10 μm or less from the carrier contained in the collected developer by using the centrifugal air classifier.

### Claim 3 (depends on 1)

The method for producing a recycled carrier according to claim 1, wherein the recoating involves adding a coating resin to adjust a coating resin amount to the same as that of a new carrier.

### Claim 4 (depends on 2)

The method for producing a recycled carrier according to claim 2, wherein the recoating involves adding a coating resin to adjust a coating resin amount to the same as that of a new carrier.

### Claim 5 (depends on 1)

The method for producing a recycled carrier according to claim 1, wherein the recoating involves mixing the classified carrier with new magnetic particles under stirring, adding a coating liquid containing a solvent and a resin for coating the magnetic particles to the resulting mixture, and evaporating the solvent while simultaneously mixing the classified carrier and the magnetic particles under stirring to form a coating layer of the classified carrier again, and
wherein the classified carrier has a coating layer.

### Claim 6 (depends on 2)

The method for producing a recycled carrier according to claim 2, wherein the recoating involves mixing the classified carrier with new magnetic particles under stirring, adding a coating liquid containing a solvent and a resin for coating the magnetic particles to the resulting mixture, and evaporating the solvent while simultaneously mixing the classified carrier and the magnetic particles under stirring to form a coating layer of the classified carrier again, and
wherein the classified carrier has a coating layer.

### Claim 7 (depends on 5)

The method for producing a recycled carrier according to claim 5, wherein a ratio Mnew/Mold of an amount Mnew of the new magnetic particles added to an amount Mold of the classified carrier added in the recoating is 1 or more.

### Claim 8 (depends on 6)

The method for producing a recycled carrier according to claim 6, wherein a ratio Mnew/Mold of an amount Mnew of the new magnetic particles added to an amount Mold of the classified carrier added in the recoating is 1 or more.

### Claim 9 (depends on 7)

The method for producing a recycled carrier according to claim 7, wherein the ratio Mnew/Mold of the amount Mnew of the new magnetic particles added to the amount Mold of the classified carrier added in the recoating is 2 or more and 20 or less.

### Claim 10 (depends on 8)

The method for producing a recycled carrier according to claim 8, wherein the ratio Mnew/Mold of the amount Mnew of the new magnetic particles added to the amount Mold of the classified carrier added in the recoating is 2 or more and 20 or less.

### Claim 11 (depends on 1)

The method for producing a recycled carrier according to claim 1, wherein the centrifugal air classifier is a forced vortex-type classifier with a rotary blade.

### Claim 12 (depends on 2)

The method for producing a recycled carrier according to claim 2, wherein the centrifugal air classifier is a forced vortex-type classifier with a rotary blade.

### Claim 13 (depends on 3)

The method for producing a recycled carrier according to claim 3, wherein the centrifugal air classifier is a forced vortex-type classifier with a rotary blade.

### Claim 14 (depends on 4)

The method for producing a recycled carrier according to claim 4, wherein the centrifugal air classifier is a forced vortex-type classifier with a rotary blade.

### Claim 15 (depends on 5)

The method for producing a recycled carrier according to claim 5, wherein the centrifugal air classifier is a forced vortex-type classifier with a rotary blade.

### Claim 16 (depends on 6)

The method for producing a recycled carrier according to claim 6, wherein the centrifugal air classifier is a forced vortex-type classifier with a rotary blade.

### Claim 17 (depends on 11)

The method for producing a recycled carrier according to claim 11, wherein, in the classification, a centrifugal force F applied by the rotary blade satisfies Formula 1 below, and a peripheral speed of the rotary blade satisfies Formula 2 below:
F(N)=m·(2πdN)2/d≥1.5×10−8 Formula 1
Peripheral speed(m/s)=2πdN≤50 Formula 2
where m represents a mass (kg) of one carrier particle, N represents the number of revolutions (rps) of the rotary blade, d represents a radius (m) of the rotary blade, and x represents a ratio of a circumference of a circle to its diameter.

### Claim 18 (depends on 1)

A method for producing a recycled electrostatic charge image developer, the method comprising the method for producing a recycled carrier according to claim 1.

### Claim 19 (depends on 1)

An image forming method using a recycled carrier produced by the method for producing a recycled carrier according to claim 1.

### Claim 20 (depends on 1)

A recycled carrier produced by the method for producing a recycled carrier according to claim 1.

### Claim 21 (depends on 1)

The method for producing a recycled carrier according to claim 1, wherein the recoating including dissolving a coating resin of the separated and classified carrier with a solvent and then coating the resulting carrier again to produce a recycled carrier.

### Claim 22 (depends on 1)

The method for producing a recycled carrier according to claim 1, wherein the recoating including dissolving a coating resin of the separated and classified carrier with a solvent and then coating the resulting carrier with the same solvent containing the dissolved coating resin again to produce a recycled carrier, wherein the solvent is at least one selected from the group consisting of toluene, xylene, acetone, methyl ethyl ketone, tetrahydrofuran, and dioxane.
