Laminate and production method therefor

A laminate comprising:

• a substrate (s) having an anti-reflection layer;
• an intermediate layer (c) placed on the anti-reflection layer side of the substrate;
• and
• a water-repellent layer (r), in this order, wherein
• the intermediate layer (c) is a cured layer of a mixture composition (cc) of an organosilicon compound (C), or a vapor deposition layer of the organosilicon compound (C),
• the organosilicon compound (C) contains a silicon atom together with an amino group and/or an amine skeleton,
• the organosilicon compound (C) is an organosilicon compound represented by the following formula (c2),
• in the formula (c2),
• Rx20 and Rx21 each independently represent a hydrogen atom or an alkyl group having 1 to 4 carbon atoms,
• when the number of Rx20s is plural, the plurality of Rx20s may be different from each other,
• when the number of Rx21s is plural, the plurality of Rx21s may be different from each other,
• Rfx20 and Rfx21 each independently represent a fluorine atom, or an alkyl group having 1 to 20 carbon atoms in which one or more hydrogen atom is substituted by a fluorine atom,
• when the number of Rfx20s is plural, the plurality of Rfx20s may be different from each other,
• when the number of Rfx21s is plural, the plurality of Rfx21s may be different from each other,
• Rx22 and Rx23 each independently represent an alkyl group having 1 to 20 carbon atoms,
• when the numbers of Rx22s and Rx23s are plural, the plurality of Rx22s and the plurality of Rx23s may be different from each other,
• X20 and X21 each independently represent a hydrolyzable group,
• when the numbers of X20s and X21s are plural, the plurality of X20s and the plurality of X21s may be different from each other,
• p20 represents an integer of 1 to 30,
• p21 represents an integer of 0 to 30,
• at least one of repeating units bracketed with p20 or p21 is replaced by an amine skeleton —NR100,
• R100 in the amine skeleton represents a hydrogen atom or an alkyl group,
• p22 and p23 each independently represent an integer of 1 to 3, and
• —{C(Rx20)(Rx21)}— whose number is p20 and —{C(Rfx20)(Rfx21)}— whose number is p21 are aligned and bound in any order, p20 or p21 units may not necessarily be continuous, and both ends are —Si(X20)p22(Rx22)3-p22 and —Si(X21)p23(Rx23)3-p23,
• the water-repellent layer (r) is a cured layer of a mixture composition (ca) of an organosilicon compound (A) in which a monovalent group having a perfluoropolyether structure is bound to a silicon atom through a linking group located therebetween or without a linking group located therebetween, and a hydrolyzable group is bound to the silicon atom through a linking group located therebetween or without a linking group located therebetween, and
• the laminate satisfies the following requirement (1),
• (1) a water sliding angle is not larger than 50° after a abrasion resistance test in which a 200 g load per 1.5 cm×1.5 cm area is applied to a surface on the water-repellent layer (r) side of the laminate and the surface is rubbed 20,000 times.