Method for purifying (meth)acrylic acid
AssigneeArkema France
InventorsSerge Tretjak, Aurelien Huve
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Abstract
The invention relates to a process for the continuous production of acrylic acid, in the absence of organic solvent and in the absence of chemical treatment of the aldehydes, and without employing a dividing-wall column, from a gaseous reaction mixture comprising acrylic acid obtained by gas-phase oxidation of a precursor of acrylic acid.
Claims16
A process for the purification of (meth)acrylic acid in an absence of organic solvent and in an absence of a chemical treatment of aldehydes, from a gaseous reaction mixture comprising (meth)acrylic acid obtained by gas-phase oxidation of a precursor of (meth)acrylic acid, said process comprising the following stages:
- subjecting said reaction mixture to a dehydration, without using azeotropic solvent, in a dehydration column, resulting in a top stream and a bottom stream being obtained,
- sending at least a portion of said bottom stream from the dehydration column into an upper part of a finishing column, where light products are distilled, heavy products are removed at a bottom of the finishing column and a side stream is withdrawn,
- sending said side stream from the finishing column to a lower third of a third distillation column, resulting in a top stream, a side stream and a bottom stream being obtained, said top stream being subjected to a condensation and then returned after condensation, partly in the third distillation column in reflux form and partly being recovered, said side stream being withdrawn in a half of a lower part of said third distillation column.
Dependencies are inferred from the claim text.