# US 12,113,223 B2 · Method for producing a gas diffusion device having improved electrical properties > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 12,113,223 B2 - Document ID: US12113223B2 - Status: Granted - Kind: B2 - Application number: 17/623,793 - Filed: 2020-07-01 - Published: 2022-08-04 - Granted: 2024-10-08 - Earliest claimed: 2019-07-01 - Assignees: Commissariat A L'energie Atomique Et Aux Energies Alternatives - Applicants: Commissariat A L'éNergie Atomique Et Aux Energies Alternatives - Inventors: Ludovic Rouillon; Joël Pauchet; Jean-Philippe Poirot-Crouvezier - Web page: https://patentgrep.com/patent/US12113223B2 ## CPC - H01M 4/8807: {Gas diffusion layers} - H01M 4/8605: {Porous electrodes} - H01M 8/0239: Organic resins; Organic polymers - H01M 8/0245: in the form of layered or coated products - H01M 8/026: characterised by grooves, e.g. their pitch or depth - Y02E 60/50: Fuel cells - Y02P 70/50: Manufacturing or production processes characterised by the final manufactured product - H01M: PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY - Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION - Y02P: CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS ## Abstract A process for manufacturing a gas diffusion device includes providing a superposition of a composite layer and of an electrically conductive element, the composite layer including electrically conductive fibers and a polymerizable resin impregnating the conductive fibers, and the electrically conductive element having an open porosity between a first face and a second face. The process also includes compressing the superposition of the composite layer and of the conductive element so as to bring said conductive fibers into contact with the first face of the element, so as to make said resin flow into said element without the resin impregnating all the volume of said conductive element; and polymerizing the resin. ## Claims ### Claim 1 A process for manufacturing a gas diffusion device, comprising: providing a superposition of a composite layer and an electrically conductive element, the composite layer including electrically conductive fibers and a polymerizable resin impregnating the electrically conductive fibers, and the electrically conductive element having an open porosity between a first face and a second face; compressing the superposition of the composite layer and the electrically conductive element so as to bring the electrically conductive fibers into contact with the first face of the electrically conductive element, so as to make the resin flow into the electrically conductive element without the resin impregnating all of a volume of said electrically conductive element; and polymerizing the resin having flowed and polymerizing the resin of the composite layer so that the composite layer becomes impermeable to hydrogen. ### Claim 2 (depends on 1) The manufacturing process as claimed in claim 1, wherein the superposed electrically conductive element takes a form of a plate having first and second lateral borders forming the first face and second face of the electrically conductive element, respectively. ### Claim 3 (depends on 2) The manufacturing process as claimed in claim 2, wherein the superposed electrically conductive element is compressible, the compressing including compression of the electrically conductive element in a direction normal to an external surface extending between the first and second lateral borders. ### Claim 4 (depends on 3) The manufacturing process as claimed in claim 3, wherein the superposed electrically conductive element and composite layer have different thicknesses at rest, the compression of the electrically conductive element in the direction normal to the external surface being implemented so that the electrically conductive element and the composite layer have a same thickness during the compression. ### Claim 5 (depends on 1) The manufacturing process as claimed in claim 1, wherein the superposed composite layer comprises a groove covered by the superposed electrically conductive element. ### Claim 6 (depends on 5) The manufacturing process as claimed in claim 5, comprising a prior step of forming the groove in the composite layer and of polymerizing the resin on faces of the groove. ### Claim 7 (depends on 6) The manufacturing process as claimed in claim 6, wherein forming the groove and polymerizing the resin on the faces of the groove are carried out by laser engraving the composite layer. ### Claim 8 (depends on 6) The manufacturing process as claimed in claim 6, wherein polymerizing the resin on the faces of the groove includes applying a gas flow to the groove at a temperature above 35° C. ### Claim 9 (depends on 1) The manufacturing process as claimed in claim 1, wherein the superposed electrically conductive element has a thickness comprised between 40 and 350 micrometers. ### Claim 10 (depends on 1) The manufacturing process as claimed in claim 1, wherein the electrically conductive element is a layer of foam, felt or fabric. ### Claim 11 (depends on 1) The manufacturing process as claimed in claim 1, wherein the resin is a phenolic resin. ### Claim 12 (depends on 1) The manufacturing process as claimed in claim 1, wherein the superposition is compressed with a pressure comprised between 0.5 and 1.5 MPa. ### Claim 13 (depends on 1) The manufacturing process as claimed in claim 1, wherein the compression is carried out so as to make the resin flow into the electrically conductive element without the resin reaching the second face. ### Claim 14 (depends on 1) The manufacturing process as claimed in claim 1, wherein the compression is carried out so that the resin impregnates at most 30% of a volume of the electrically conductive element. ### Claim 15 (depends on 1) A process for manufacturing a bipolar plate, comprising forming a first gas diffusion device using the process as claimed in claim 1; forming a second gas diffusion device using the process as claimed in claim 1; and, superposing the first and second gas diffusion devices. ### Claim 16 (depends on 15) The process for manufacturing a bipolar plate as claimed in claim 15, wherein polymerizable resins used to form the first gas diffusion device and to form the second gas diffusion device have different chemical compositions. ### Claim 17 (depends on 15) The process for manufacturing a bipolar plate as claimed in claim 15, comprising introducing a metal layer between the superposed first and second gas diffusion devices.