# US 12,113,178 B2 · Separators, batteries, battery strings with improved performance, and related methods

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- Number: US 12,113,178 B2
- Document ID: US12113178B2
- Status: Granted
- Kind: B2
- Application number: 15/232,898
- Filed: 2016-08-10
- Published: 2017-02-23
- Granted: 2024-10-08
- Earliest claimed: 2015-08-10
- Assignees: Daramic, LLC
- Applicants: Daramic, LLC
- Inventors: Eric H. Miller; Yanxia Wu
- Web page: https://patentgrep.com/patent/US12113178B2

## CPC

- H01M 10/121: {Valve regulated lead acid batteries [VRLA]}
- H01M 50/417: Polyolefins
- H01M 50/437: Glass
- H01M 50/44: Fibrous material
- H01M 50/454: comprising a non-fibrous layer and a fibrous layer superimposed on one another
- H01M 50/463: Separators, membranes or diaphragms characterised by their shape
- H01M 10/14: Assembling a group of electrodes or separators
- H01M 2220/10: Batteries in stationary systems, e.g. emergency power source in plant
- H01M 2220/20: Batteries in motive systems, e.g. vehicle, ship, plane
- Y02E 60/10: Energy storage using batteries
- Y02P 70/50: Manufacturing or production processes characterised by the final manufactured product
- Y02T 10/70: Energy storage systems for electromobility, e.g. batteries
- H01M: PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02P: CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02T: CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO TRANSPORTATION

## Abstract

Improved battery separators are disclosed herein for use in various lead acid batteries, and in particular lead acid battery strings. The improved separators, batteries, battery strings, methods, and vehicles disclosed herein provide substantially increased battery life, substantially reduced battery fail rate, and substantially higher voltage uniformity among the various batteries in a battery string. The improved battery strings may be advantageously employed in high depth of discharge applications such as electric bicycles, golf carts (or golf cars), uninterrupted power supply (UPS) backup power battery strings, and the like.

## Claims

### Claim 1

A battery string comprising:
four or more monoblock valve regulated lead-acid (VRLA) batteries wired in series, wherein a total voltage of the battery string is 48 volts or greater;
each VRLA monoblock battery comprises
an alternating sequence of positive and negative electrodes, and
a separator disposed between each of the positive and negative electrodes, the separator consists of a microporous polyolefin layer including a surfactant sandwiched between a first absorptive glass mat and a second absorptive glass mat, wherein the first absorptive glass mat has a thickness from 1.0 to 3.3 mm and the second absorptive glass mat has a thickness of 0.6 mm, wherein the microporous polyolefin layer is a polyethylene layer with a ribbed or embossed backweb, a backweb thickness of the microporous polyolefin layer not including the thickness of the ribs or embossments is from 0.05 mm to 0.25 mm, and the microporous polyolefin layer with the ribbed or embossed backweb of the separator has a bi-modal pore size distribution consisting of a first region of pores consisting of larger pores having a size of 1 to 6 microns and a second region of pores consisting of smaller pores having a size of less than 0.9 micron, wherein 90% of the pores are smaller pores.

### Claim 2

A battery string consisting of:
four or more monoblock valve regulated lead-acid (VRLA) batteries wired in series, wherein a total voltage of the battery string is 48 volts or greater;
each VRLA monoblock battery consists of
an alternating sequence of positive and negative electrodes, and
a separator disposed between each of the positive and negative electrodes, the separator consists of a microporous polyolefin layer including a surfactant sandwiched between a first absorptive glass mat and a second absorptive glass mat, wherein the first absorptive glass mat has a thickness from 1.0 to 3.3 mm and the second absorptive glass mat has a thickness of 0.6 mm,
wherein the microporous polyolefin layer is a polyethylene layer with a ribbed or embossed backweb, a backweb thickness of the microporous polyolefin layer not including the thickness of the ribs or embossments is from 0.05 mm to 0.25 mm, the microporous polyolefin layer with the ribbed or embossed backweb of the separator has a bi-modal pore size distribution consisting of a first region of pores consisting of larger pores having a size of 1 to 6 microns and a second region of pores consisting of smaller pores having a size of less than 0.9 micron, wherein 90% of the pores are smaller pores.

### Claim 3 (depends on 1)

The battery string according to claim 1, wherein the first absorptive glass mat and the second absorptive glass mat each comprise polymeric fibers.

### Claim 4 (depends on 1)

An electric vehicle comprising a battery comprising the battery string of claim 1.