# US 12,113,163 B2 · Method of using an electric field for roll-to-roll separator coating

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- Number: US 12,113,163 B2
- Document ID: US12113163B2
- Status: Granted
- Kind: B2
- Application number: 17/506,446
- Filed: 2021-10-20
- Published: 2023-04-20
- Granted: 2024-10-08
- Earliest claimed: 2021-10-20
- Assignees: GM Global Technology Operations LLC
- Applicants: GM Global Technology Operations LLC
- Inventors: Ruchira Dharmasena; Shuru Chen; Fang Dai; Mei Cai; Sanaz Ketabi
- Web page: https://patentgrep.com/patent/US12113163B2

## CPC

- H01M 10/0404: {Machines for assembling batteries}
- H01M 10/0525: Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
- H01M 50/403: Manufacturing processes of separators, membranes or diaphragms
- H01M 50/406: Moulding; Embossing; Cutting
- H01M 50/414: Synthetic resins, e.g. thermoplastics or thermosetting resins
- H01M 50/417: Polyolefins
- H01M 50/431: Inorganic material
- H01M 50/434: Ceramics
- H01M 50/446: Composite material consisting of a mixture of organic and inorganic materials
- H01M 50/449: having a layered structure
- H01M 50/451: comprising layers of only organic material and layers containing inorganic material
- H01M 50/457: comprising three or more layers
- H01M 50/46: Separators, membranes or diaphragms characterised by their combination with electrodes
- Y02E 60/10: Energy storage using batteries
- H01M: PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

## Abstract

A system for coating a separator for a battery includes a separator feed and collection assembly configured to dispense the separator, a coating distribution device configured to flow a coating material toward the separator, and an electric field generator configured to generate an electric field in a gap between the coating distribution device and the separator.

## Claims

### Claim 1

A system for coating a separator for a battery, the system comprising:
a separator feed and collection assembly configured to dispense the separator;
a coating distribution device configured to flow a coating material toward the separator; and
an electric field generator configured to generate an electric field in a gap between the coating distribution device and the separator,
wherein the coating material includes a metal oxide and carbon.

### Claim 2 (depends on 1)

The system of claim 1, wherein the separator feed and collection assembly includes a spool assembly, and wherein the spool assembly comprises:
a source spool configured to hold the separator prior to being coated with the coating material;
a collector spool configured to hold the separator subsequent to being coated with the coating material; and
a coating drum arranged between the source spool and the collector spool, wherein the coating drum is configured to hold the separator while the separator is coated with the coating material.

### Claim 3 (depends on 2)

The system of claim 2, wherein the electric field generator is configured to negatively charge the coating drum to generate the electric field.

### Claim 4 (depends on 1)

The system of claim 1, wherein the electric field generator includes a power supply connected to the coating distribution device and the separator feed and collection assembly.

### Claim 5 (depends on 4)

The system of claim 4, wherein the power supply includes a positive terminal connected to the coating distribution device and a negative terminal connected to a coating drum of the separator feed and collection assembly.

### Claim 6 (depends on 4)

The system of claim 4, wherein the power supply is configured to generate at least a 3 kV/m electric field.

### Claim 7 (depends on 1)

The system of claim 1, wherein the coating distribution device includes a syringe configured to flow the coating material into the gap.

### Claim 8 (depends on 7)

The system of claim 7, wherein the syringe is configured to flow the coating material at between 0 and 1 microliters per minute.

### Claim 9 (depends on 1)

The system of claim 1, wherein the coating material includes the metal oxide and carbon dissolved in a polymer solution.

### Claim 10 (depends on 9)

The system of claim 9, wherein the metal oxide includes titanium dioxide.

### Claim 11 (depends on 9)

The system of claim 9, wherein the electric field generator is configured to charge particles of the metal oxide and the carbon.

### Claim 12 (depends on 1)

The system of claim 1, further comprising a coating control module to control a rate of movement of the separator through the separator feed and collection assembly, a flow rate of the coating material from the coating distribution device, and the generation of the electric field such that the coating material is applied to the separator at a thickness between 2 and 20 μm.

### Claim 13

A method for coating a separator for a battery, the method comprising:
using a separator feed and collection assembly, dispensing the separator at a controlled movement rate;
flowing a coating material from a coating distribution device toward the separator; and
generating an electric field in a gap between the coating distribution device and the separator,
wherein the coating material includes a metal oxide and carbon.

### Claim 14 (depends on 13)

The method of claim 13, further comprising generating the electric field using a power supply connected to the coating distribution device and the separator feed and collection assembly.

### Claim 15 (depends on 14)

The method of claim 14, further comprising connecting a positive terminal of the power supply to the coating distribution device and a negative terminal of the power supply to a coating drum of the separator feed and collection assembly.

### Claim 16 (depends on 13)

The method of claim 13, wherein the electric field is at least 3 kV/m.

### Claim 17 (depends on 13)

The method of claim 13, further comprising flowing the coating material into the gap using a syringe.

### Claim 18 (depends on 13)

The method of claim 13, wherein the metal oxide and carbon is dissolved in a polymer solution.

### Claim 19 (depends on 18)

The method of claim 18, further comprising controlling the movement rate of the separator, a flow rate of the coating material from the coating distribution device, and the generation of the electric field such that the coating material is applied to the separator at a thickness between 2 and 20 μm.

### Claim 20

A system for coating a separator for a battery, the system comprising:
a separator feed and collection assembly configured to dispense the separator;
a coating distribution device configured to flow a coating material toward the separator;
an electric field generator configured to generate an electric field in a gap between the coating distribution device and the separator; and
a coating control module to control a rate of movement of the separator through the separator feed and collection assembly, a flow rate of the coating material from the coating distribution device, and the generation of the electric field such that the coating material is applied to the separator at a thickness between 2 and 20 μm.
