# US 12,112,945 B2 · Semiconductor wafer, electronic device, method of performing inspection on semiconductor wafer, and method of manufacturing electronic device

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- Number: US 12,112,945 B2
- Document ID: US12112945B2
- Status: Granted
- Kind: B2
- Application number: 17/381,992
- Filed: 2021-07-21
- Published: 2021-11-18
- Granted: 2024-10-08
- Earliest claimed: 2017-02-26
- Assignees: Sumitomo Chemical Company, Limited
- Applicants: Sumitomo Chemical Company, Limited
- Inventors: Noboru Fukuhara; Yasuyuki Kurita; Takayuki Inoue
- Web page: https://patentgrep.com/patent/US12112945B2

## CPC

- H10P 14/3458: {Monocrystalline}
- H10D 30/475: {having wider bandgap layer formed on top of lower bandgap active layer, e.g. undoped barrier HEMTs such as i-AlGaN/GaN HEMTs}
- H10D 62/357: {of FETs}
- H10D 62/8503: {Nitride Group III-V materials, e.g. AlN or GaN}
- H10D 64/514: {characterised by the insulating layers}
- H10P 74/277: {Circuits for electrically characterising or monitoring manufacturing processes, e.g. circuits in tested chips or circuits in testing wafers}
- G01R 31/2644: {Adaptations of individual semiconductor devices to facilitate the testing thereof}
- H10D 30/60: Insulated-gate field-effect transistors [IGFET] (H10D30/40 takes precedence)
- H10P 74/207: {Electrical properties, e.g. testing or measuring of resistance, deep levels or capacitance-voltage characteristics}
- H10P: GENERIC PROCESSES OR APPARATUS FOR THE MANUFACTURE OR TREATMENT OF DEVICES COVERED BY CLASS H10
- H10D: INORGANIC ELECTRIC SEMICONDUCTOR DEVICES
- G01R: MEASURING ELECTRIC VARIABLES; MEASURING MAGNETIC VARIABLES (indicating correct tuning of resonant circuits H03J3/12)

## Abstract

A semiconductor substrate in includes a buffer layer and a first crystalline layer. A bandgap of the first crystalline layer is smaller than a bandgap of a second layer. When a semiconductor wafer is formed as a transistor wafer, a channel of a transistor is formed at or near an interface between the first crystalline layer and the second layer. With a first electrode and a second electrode provided and a third electrode provided, when space charge redistribution, for emitting electrons and holes from a bandgap of a crystal positioned in the spatial region, is achieved by applying negative voltage to the third electrode or by applying positive voltage to the second electrode with the first electrode serving as a reference, an electron emission speed in the space charge redistribution is higher than a hole emission speed.

## Claims

### Claim 1

A method of performing inspection on a semiconductor wafer, the method comprising:
preparing a semiconductor wafer including a substrate, a buffer layer, a first crystalline layer, and a second layer, the substrate, the buffer layer, the first crystalline layer, and the second layer being positioned in order of the substrate, the buffer layer, the first crystalline layer and the second layer, the buffer layer and the first crystalline layer being made of a group III nitride layer, a bandgap of the first crystalline layer being smaller than a bandgap of the second layer, when the semiconductor wafer is formed as a transistor wafer, a channel of a transistor being formed at or near an interface between the first crystalline layer and the second layer;
providing a first electrode and a second electrode, electrically connected to the channel, to be closer to a front surface than the channel is and providing a third electrode, at which an electric field is applicable to a spatial region positioned between the channel and the substrate, to be closer to a back surface than the channel is;
applying negative voltage to the third electrode or applying positive voltage to the second electrode with the first electrode serving as a reference to achieve a space charge redistribution for emitting electrons and holes from a bandgap of a crystal positioned in the spatial region; and
determining that the semiconductor wafer has passed the inspection when an electron emission speed in space charge redistribution is higher than a hole emission speed, and determining that the semiconductor wafer has failed to pass the inspection when the electron emission speed in space charge redistribution is not higher than the hole emission speed.

### Claim 2

A method of performing inspection on a semiconductor wafer, the method comprising:
preparing a semiconductor wafer including a substrate, a buffer layer, a first crystalline layer, and a second layer, the substrate, the buffer layer, the first crystalline layer, and the second layer being positioned in order of the substrate, the buffer layer, the first crystalline layer and the second layer, the buffer layer and the first crystalline layer being made of a group III nitride layer, a bandgap of the first crystalline layer being smaller than a bandgap of the second layer, when the semiconductor wafer is formed as a transistor wafer, a channel of a transistor being formed at or near an interface between the first crystalline layer and the second layer;
providing a first electrode and a second electrode, electrically connected to the channel, to be closer to a front surface than the channel is and providing a third electrode, at which an electric field is applicable to a spatial region positioned between the channel and the substrate, to be closer to a back surface than the channel is;
applying voltage between the first electrode and the second electrode, the voltage being at a level not causing saturation of the current flowing between the first electrode and the second electrode and applying negative voltage to the wafer, with a lower one of potentials of the first electrode and the second electrode serving as a reference; and
determining that the semiconductor wafer has passed the inspection, when current flowing between the first electrode and the second electrode does not decrease with time, and determining that the semiconductor wafer has failed to pass the inspection, when current flowing between the first electrode and the second electrode decreases with time.

### Claim 3 (depends on 1)

The method of performing inspection on a semiconductor wafer according to claim 1, wherein
the second layer is a second crystalline layer made of a group III nitride layer, and
the channel is two-dimensional electron gas.

### Claim 4 (depends on 1)

The method of performing inspection on a semiconductor wafer according to claim 1, wherein
the second layer is an insulating layer that functions as a gate insulating film for the transistor when the transistor is formed.

### Claim 5 (depends on 1)

A method of manufacturing an electronic device, the method comprising:
inspecting a semiconductor wafer with the method of performing inspection according to claim 1; and
forming an electronic device by using a semiconductor wafer that has passed the inspecting.

### Claim 6 (depends on 2)

The method of performing inspection on a semiconductor wafer according to claim 2, wherein
the second layer is a second crystalline layer made of a group III nitride layer, and
the channel is two-dimensional electron gas.

### Claim 7 (depends on 2)

The method of performing inspection on a semiconductor wafer according to claim 2, wherein
the second layer is an insulating layer that functions as a gate insulating film for the transistor when the transistor is formed.

### Claim 8 (depends on 2)

A method of manufacturing an electronic device, the method comprising:
inspecting a semiconductor wafer with the method of performing inspection according to claim 2; and
forming an electronic device by using a semiconductor wafer that has passed the inspecting.
