Painted metal plate and method for producing same
AssigneeNippon Steel Corporation
InventorsKeiko Takiguchi, Masaki Satou, Seiju Suzuki, Shuichi Sugita
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Abstract
The present invention addresses the problem of providing a painted metal plate having rain-streak-stain resistance and a good appearance, and a method for producing the same. To solve this problem, the method for producing a painted metal plate includes a step for forming a coating by applying a paint containing a silicone resin and a fluorine-containing resin to the surface of a metal plate and curing the paint, and a step for performing flame treatment on the coating. The silicone resin contains 5 to 50 mol % of a silanol group with respect to the total molar mass of Si atoms.
Claims7
A coated metal sheet, comprising:
- a metal sheet;
- and a fluorinated coating film formed on the metal sheet, wherein
- the coating film contains a cured product of a silicone resin, and a fluorine-containing resin;
- an amount of the cured product of the silicone resin is 1 to 10 parts by mass of a total mass of the coating film;
- the silicone resin contains Si atoms derived from trialkoxysilane in an amount of 50 to 100 mol % relative to the total number of moles of Si atoms;
- a weight average molecular weight of the silicone resin is 1000 to 10000;
- when a surface of the coating film is analyzed with X-ray electron spectroscopy using an A1Kα ray as an X-ray source, Sia and x satisfy the following expressions respectively, wherein Sia is a proportion of Si atoms based on a total amount of Si atoms, F atoms, C atoms, and O atoms, and x is a ratio of an amount of O atoms to an amount of C atoms:
- Sia≥8 atm %
- x≥0.8;
- and
- when a C1s peak top in an X-ray photoelectron spectroscopic spectrum obtained through the analysis with X-ray electron spectroscopy is corrected to be 285 eV and a Si2p spectrum is separated into a peak corresponding to 103.5 eV and a peak corresponding to 102.7 eV, y satisfies the following expression, wherein y is a ratio of a peak area of 103.5 eV to a peak area of the entire Si2p spectrum:
- y≥0.6.
Dependencies are inferred from the claim text.