# US 12,109,784 B2 · Polymer coating layers for use with holographic optical elements

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- Number: US 12,109,784 B2
- Document ID: US12109784B2
- Status: Granted
- Kind: B2
- Application number: 17/596,631
- Filed: 2020-07-24
- Published: 2022-05-26
- Granted: 2024-10-08
- Earliest claimed: 2019-07-26
- Assignees: Solutia Inc.
- Applicants: Solutia Inc.
- Inventors: Francois Andre Koran; Steven V. Haldeman
- Web page: https://patentgrep.com/patent/US12109784B2

## CPC

- B32B 17/10935: {as a preformed layer, e.g. formed by extrusion}
- B32B 17/10036: {comprising two outer glass sheets}
- B32B 17/1044: {Invariable transmission}
- B32B 17/10605: {Type of plasticiser}
- B32B 17/10633: {Infrared radiation absorbing or reflecting agents}
- B32B 17/10651: {comprising colorants, e.g. dyes or pigments}
- B32B 17/10761: {containing vinyl acetal}
- B32B 17/1077: {containing polyurethane}
- B32B 2457/20: Displays, e.g. liquid crystal displays, plasma displays
- B32B: LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM

## Abstract

Tie layers and structures that exhibit superior properties and that provide desirable optical properties when incorporated into laminates, such as windshields, windows or other glazings containing a holographic optical element (HOE) are disclosed. The tie layers, when used in a laminate in conjunction with the HOE film, optionally with additional polymer layers, maintain and do not detract from the HOE film properties.

## Claims

### Claim 1

A manufacturing process comprising the steps of: providing a first polymer layer, a tie layer comprising a low refractive index compound, and a polymeric volume hologram, assembling the first polymer layer, the tie layer and the polymeric volume hologram to form an assembly, providing at least a first substrate wherein the first substrate is adjacent the first polymer layer, and laminating the assembly with the at least first substrate to form a laminated structure, wherein the laminated structure has partitioned low refractive index compound levels within the polymeric volume hologram such that the light modification properties of the polymeric volume hologram following lamination and low refractive index compound equilibration with the tie layer are greater than 70% of the magnitude of the original light modification properties of the polymeric hologram prior to assembly, in at least one wavelength range,
wherein the initial polymeric volume hologram comprises at least one low refractive index compound, and
wherein the tie layer comprises a concentration of low refractive index compound within a range of −25 to +25 weight percent of the concentration of low refractive index compound in the polymeric volume hologram.

### Claim 2 (depends on 1)

The manufacturing process of claim 1, further comprising one or more additional polymer layers.

### Claim 3 (depends on 1)

The manufacturing process of claim 1, wherein the polymeric volume hologram is disposed on a second substrate.

### Claim 4 (depends on 1)

The manufacturing process of claim 1, further comprising a second substrate.

### Claim 5 (depends on 1)

The manufacturing process of claim 1, wherein the low refractive index compound in the tie layer is different from the low refractive index compound in the polymeric volume hologram.

### Claim 6 (depends on 1)

The manufacturing process of claim 1, wherein the tie layer comprises a total quantity of low refractive index compound within a range of greater than 0 to less than 50 weight percent of the laminated structure.

### Claim 7 (depends on 1)

The manufacturing process of claim 1, wherein the tie layer comprises polymers or elastomers or blends of polymers or elastomers selected from polyurethanes, poly(vinyl acetal)s such as poly(vinyl butyral), ethylene vinyl acetate copolymers, polyvinyl alcohols, cellulose esters, polyolefin elastomers, acrylic resins, polysiloxanes and ionomers.

### Claim 8 (depends on 1)

The manufacturing process of claim 1, wherein the low refractive index compound in the tie layer is selected to have a refractive index within a range of −0.1 to +0.1 of the refractive index of the low refractive index compound in the polymeric volume hologram.

### Claim 9

A manufacturing process comprising the steps of: providing a first polymer layer, a tie layer comprising a low refractive index compound, and a polymeric volume hologram, assembling the first polymer layer, the tie layer and the polymeric volume hologram to form an assembly, providing at least a first substrate wherein the first substrate is adjacent the first polymer layer, and laminating the assembly with the at least first substrate to form a laminated structure, wherein the laminated structure has partitioned low refractive index compound levels within the polymeric volume hologram such that the light modification properties of the polymeric volume hologram following lamination and low refractive index compound equilibration with the tie layer are greater than 70% of the magnitude of the original light modification properties of the polymeric hologram prior to assembly, in at least one wavelength range,
further comprising providing a polymer film adjacent the tie layer, wherein the polymer film is disposed between the first polymer layer and the tie layer,
wherein the polymer film prevents migration of the low refractive index compound to the polymer layer from the tie layer and/or the polymeric volume hologram.

### Claim 10 (depends on 1)

The manufacturing process of claim 1, wherein the tie layer further comprises an adhesion promoter.

### Claim 11 (depends on 1)

The manufacturing process of claim 1, wherein at least a portion of the polymer layer has at least one of: an interlayer that is tapered, acoustic dampening properties, or elements to selectively block portions of the electromagnetic spectrum, or wherein the polymer layer comprises at least one of the following: dyes, colorants, pigments, particles, infrared or solar absorbers.

### Claim 12 (depends on 1)

The manufacturing process of claim 1, wherein the low refractive index compound comprises at least two different low refractive index compounds.

### Claim 13 (depends on 1)

The manufacturing process of claim 1, wherein the polymeric volume hologram comprises a patterned or an unpatterned photopolymer film, wherein the polymeric volume hologram comprises no low refractive index compound prior to the assembly step.

### Claim 14

A manufacturing process comprising the steps of: providing a first polymer layer, a tie layer comprising a low refractive index compound, a polymeric volume hologram, and a second polymer layer, assembling the first polymer layer, the tie layer, the polymeric volume hologram and the second polymer layer to form an assembly wherein the polymeric volume hologram is between the tie layer and the second polymer layer, providing at least a first substrate, and laminating the assembly with the at least first substrate to form a laminated structure, wherein the laminated structure has partitioned low refractive index compound levels within the polymeric volume hologram such that the light modification properties of the polymeric volume hologram following lamination and low refractive index compound equilibration with the tie layer are greater than 100% of the magnitude of the original light modification properties of the polymeric hologram prior to assembly, in at least one wavelength range.

### Claim 15

A manufacturing process comprising the steps of: providing a first polymer layer, a tie layer comprising a low refractive index compound, and a polymeric volume hologram, assembling the first polymer layer, the tie layer and the polymeric volume hologram to form an assembly, providing at least a first substrate wherein the first substrate is adjacent the first polymer layer, and laminating the assembly with the at least first substrate to form a laminated structure, wherein the laminated structure has partitioned low refractive index compound levels within the polymeric volume hologram such that the light modification properties of the polymeric volume hologram following lamination and low refractive index compound equilibration with the tie layer are greater than 100% of the magnitude of the original light modification properties of the polymeric hologram prior to assembly, in at least one wavelength range.

### Claim 16 (depends on 1)

A laminated structure made by the manufacturing process of claim 1.

### Claim 17 (depends on 1)

The manufacturing process of claim 1, further comprising providing a layer that selectively blocks a portion of the electromagnetic spectrum.