# US 12,098,336 B2 · Drag reducing agent

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- Number: US 12,098,336 B2
- Document ID: US12098336B2
- Status: Granted
- Kind: B2
- Application number: 18/115,134
- Filed: 2023-02-28
- Published: 2023-07-20
- Granted: 2024-09-24
- Earliest claimed: 2022-01-04
- Assignees: Iris Tech, Inc.
- Applicants: Iris Tech, Inc.
- Inventors: Roman Nikolaevich Kostromin; Aleksandr Aleksandrovich Nikitin; Vladimir Dmitrievich Morozov; Igor Aleksandrovich Malykhin
- Web page: https://patentgrep.com/patent/US12098336B2

## CPC

- C10G 71/00: Treatment by methods not otherwise provided for of hydrocarbon oils or fatty oils for lubricating purposes
- C08F 2/26: anionic
- C08F 210/14: Monomers containing five or more carbon atoms
- C08F 220/1804: {C4-(meth)acrylate, e.g. butyl (meth)acrylate, isobutyl (meth)acrylate or tert-butyl (meth)acrylate}
- C08F 220/1808: {C8-(meth)acrylate, e.g. isooctyl (meth)acrylate or 2-ethylhexyl (meth)acrylate}
- C08L 33/08: Homopolymers or copolymers of acrylic acid esters
- C10G 75/04: by addition of antifouling agents
- C10G 2300/4075: Limiting deterioration of equipment
- C10G 2300/80: Additives
- C10G: CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION (cracking to hydrogen or synthesis gas C01B; cracking or pyrolysis of hydrocarbon gases to individual hydrocarbons or mixtures thereof of definite or specified constitution C07C; cracking to cokes C10B); RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
- C08F: MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
- C08L: COMPOSITIONS OF MACROMOLECULAR COMPOUNDS (compositions based on polymerisable monomers C08F, C08G; artificial filaments or fibres D01F; textile treating compositions D06)

## Abstract

This invention relates to drag reducing agents used in case of transportation of crude oil products, in particular, to solid dry poly(meth)acrylate with dry poly alpha-olefins powders based agents. The technical result of the solution involves the preparation of an effective, fast-dissolving, stable solid dry drag reducing agent suitable for use in heavy crude oil. The drag reducing agents compositions have better drag reducing performance in heavy crude applications as compared with traditional drag reducing slurries is also disclosed, which consists of the following components, wt %: a mixture of at least two drag reducing polymers, from 65 to 90 a separating agent from 3 to 25 anti-agglomerating agent from 3 to 25 a surfactant from 3 to 25, where the first polymer is poly(meth)acrylate, the second polymer is poly alpha-olefin, the ratio of the polyacrylate weight and polyalphaolefin weight varies in the range from 2:1 to 5:1.

## Claims

### Claim 1

An agent for reducing a hydrodynamic drag of a turbulent flow of hydrocarbon liquids in pipelines, comprising solid dry form of the following components, wt %:
a mixture in a form of powder or flakes, the mixture of at least two drag reducing polymers from 65 to 90
a separating agent from 3 to 25
an anti-agglomerating agent from 3 to 25
a surfactant from 3 to 25,
wherein the first polymer is at least one poly(meth)acrylate derivatives such as 1-adamantyl methacrylate, benzyl methacrylate, methylmethacrylate, butyl methacrylate, decyl methacrylate, diethylene glycol ether methacrylate, 2-(diethyl amino) ethyl methacrylate, 2-(diisopropyl amino) ethyl methacrylate, 2-(dimethyl amino) ethyl methacrylate, diethylene glycol ether butyl methacrylate, dodecyl methacrylate, ethylene glycol phenyl ether methacrylate, 2-ethyl-2-adamantyl methacrylate, 2-ethyl hexyl methacrylate, glycol methacrylate phosphate, hexyl methacrylate, octyl methacrylate, 2-hydroxy ethyl methacrylate, isobutyl methacrylate, iso-octyl methacrylate, isodecyl methacrylate, stearyl methacrylate, 1-adamantyl acrylate, benzyl acrylate, butyl acrylate, decyl acrylate, diethylene glycol ether acrylate, 2-(diethyl amino) ethyl acrylate, 2-(diisopropyl amino) ethyl acrylate, 2-(dimethyl amino) ethyl acrylate, diethylene glycol ether butyl acrylate, dodecyl acrylate, ethylene glycol phenyl ether acrylate, 2-ethyl-2-adamantyl acrylate, 2-ethyl hexyl acrylate, hexyl acrylate, octyl acrylate, 2-hydroxy ethyl acrylate, isobutyl acrylate, iso-octyl acrylate, isodecyl acrylate, stearyl acrylate, acrylic acid, 2-acylamido-2-methyl-1-propanesulfonic acid, 2-acylamido-2-methyl-1-propanesulfonic acid sodium or potassium salts, C1 to C6 alcohol esters of acrylic acid or methacrylic acid, styrene, and combinations thereof;
the second polymer is at least one polyalphaolefin selected from the group consisting of 1-hexene, 1-octene, 1-decene, 1-dodecene, 1-tetradecene and combinations of thereof,
the ratio of the poly(meth)acrylate weight and poly alpha-olefin weight varies in the range from 2:1 to 5:1;
the agent being in a form of powder or flakes.

### Claim 2 (depends on 1)

The agent of claim 1, wherein the anti-agglomerating agent is at least one anti-agglomerating agent selected from a group consisting of a monofunctional heteroatomic organic compound with a carbon skeleton having a length from 4 to 28 units, a bifunctional heteroatomic glycol containing from 4 to 28 carbon atoms, a polydimethylsiloxane.

### Claim 3 (depends on 2)

The agent of claim 2, wherein the monofunctional heteroatomic organic compound is fatty alcohol containing from 4 to 28 carbon atoms, aliphatic esters containing from 4 to 28 carbon atoms, aliphatic hydroxy carboxylic containing from 4 to 28 carbon atoms; the bifunctional heteroatomic organic compound is at least one of phosphates or phosphonates mono, di and tri ester derivatives and their isomers containing from 3 to 84 carbon atoms.

### Claim 4 (depends on 2)

The agent of claim 2, wherein the monofunctional heteroatomic organic compound is at least one of isomers of propanol, butanol, pentanol, hexanol, heptanol, octanol, nonanol, decanol, undecanol, dodecanol, tridecanol, tetradecanol, pentadecanol, hexadecanol, the isomers of propylamine, butylamine, pentylamine, hexylamine, heptylamine, octylamine, nonylamine, decylamine, undecylamine, dodecylamine, tridecylamine, tetradecylamine, pentadecylamine, hexadecylamine; dipropylamine, dibutylamine, dipentylamine, dihexylamine, diheptylamine, dioctylamine, dinonylamine, didecylamine, diundecylamine, didodecylamine, ditridecylamine, ditetradecylamine, dipentadecylamine, dihexadecylamine; tripropylamine, tributylamine, tripentylamine, trihexylamine, triheptylamine, trioctylamine, trinonylamine, tridecylamine, triundecylamine, tridodecylamine, tritridecylamine, tritetradecylamine, tripentadecyl amine, trihexadecylamine.

### Claim 5 (depends on 2)

The agent of claim 2, wherein the bifunctional heteroatomic organic compound is at least one of tripropyl phosphate, tributyl phosphate, tripentyl phosphate, propylene glycol, butylene glycol, butyl cellosolve, hexylene glycol, ethyl cellosolve, texanol, diethylene glycol, triethylene glycol, isophorone, morpholine, dioxane, dimethyl sulphoxide, dimethylformamide.

### Claim 6 (depends on 1)

The agent of claim 1, wherein the total content of polymers is from 85 to 90 wt %.

### Claim 7 (depends on 1)

The agent of claim 1, wherein the ratio of the poly(meth)acrylate weight and poly alpha-olefin weight varies in a range from 3:1 to 5:1.

### Claim 8 (depends on 1)

The agent of claim 1, wherein the ratio of the poly(meth)acrylate weight and poly alpha-olefin weight varies in a range from 3:1 to 4:1.

### Claim 9 (depends on 1)

The agent of claim 1, wherein the mixture of at least two drag reducing polymers from 75 to 90.

### Claim 10 (depends on 1)

The agent of claim 1, wherein the mixture of at least two drag reducing polymers from 80 to 90.

### Claim 11 (depends on 1)

The agent of claim 1, wherein the mixture of at least two drag reducing polymers from 85 to 90.