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US 12,085,552 B2Granted
Device for detecting hydrosulfide
AssigneeUniversity of Oregon
InventorsMichael M. Haley, Michael Pluth, Darren W. Johnson, Sean Fontenot
Life of this patent
Estimating the term…
Abstract
A device that includes a polymeric layer, wherein the polymeric layer comprises (A) a polymer and, incorporated within the polymeric layer, (B) a compound, or a protonate or salt thereof, wherein the compound, or a protonate or salt thereof, has a structure that includes at least one moiety configured for reversible, non-covalent binding of the anionic sulfide species.
Claims15
A device comprising:
- a source;
- a drain;
- a gate;
- a bulk layer, wherein the source contacts a first portion of the bulk, and the drain contacts a second portion of the bulk that is physically distinct from the first portion and the gate is disposed on a surface of the bulk in a position between the source and the drain forming a gate/bulk interface;
- and
- a polymeric layer disposed on a surface of the gate that opposes the gate/bulk interface, wherein the polymeric layer comprises a (A) polymer and, incorporated within the polymeric layer,
- (B)(i) a compound, or a protonate or salt thereof, having a structure represented by:
- wherein Y represents an aromatic group or a substituted aromatic group;
- n is 1 or 2;
- R is independently H, alkyl, substituted alkyl, a polyether moiety, carboxyl, substituted carboxyl, carbamate, substituted carbonate, carbonyloxy, alkoxy, substituted alkoxy, haloalkyl, halogen, nitro, amino, amido, aryloxy, cyano, hydroxyl, or sulfonyl;
- R1 is H, substituted lower alkyl, lower alkyl, substituted aralkyl or aralkyl;
- R2 is selected from H, acyl, substituted aralkyl, aralkyl, phosphonyl, —SO2R3;
- —C(O)R5;
- —C(O)OR7 or —C(O)NR9R10;
- R3;
- R5;
- R7;
- R9 and R10 are each independently selected from H, substituted lower alkyl, lower alkyl, substituted aralkyl, aralkyl, substituted aryl or aryl;
- or
- (B)(ii) a compound, or a protonate or salt thereof, having a structure represented by:
- wherein Y represents a substituted aromatic group or an aromatic group;
- each R15 is independently H, alkyl, substituted alkyl, a polyether moiety, carboxyl, substituted carboxyl, carbamate, substituted carbonate, carbonyloxy, alkoxy, substituted alkoxy, haloalkyl, halogen, nitro, amino, amido, aryloxy, cyano, hydroxyl, or sulfonyl;
- each X is independently halogen, alkoxy, substituted alkoxy, alkyl, substituted alkyl or a polyether moiety;
- and
- m is 0 to 5.
22 more elements
A device comprising:
- a source;
- a drain;
- a gate;
- a bulk layer, wherein the source contacts a first portion of the bulk, and the drain contacts a second portion of the bulk that is physically distinct from the first portion and the gate is disposed on a surface of the bulk in a position between the source and the drain forming a gate/bulk interface;
- and
- a polymeric element disposed on a surface of the gate that opposes the gate/bulk interface, wherein the polymeric element comprises a (A) polymer and
- (B)(i) a compound, or a protonate or salt thereof, having a structure represented by:
- wherein Y is
- wherein R50, R51, R52, R53, R54 and R55 are each independently selected from hydrogen, alkyl, substituted alkyl, a polyether moiety, carboxyl, substituted carboxyl, carbamate, substituted carbonate, carbonyloxy, alkoxy, substituted alkoxy, haloalkyl, halogen, nitro, amino, aryloxy, cyano, hydroxyl, or sulfonyl;
- n is 1 or 2;
- R is independently H, alkyl, substituted alkyl, a polyether moiety, carboxyl, substituted carboxyl, carbamate, substituted carbonate, carbonyloxy, alkoxy, substituted alkoxy, haloalkyl, halogen, nitro, amino, amido, aryloxy, cyano, hydroxyl, or sulfonyl;
- R1 is H, substituted lower alkyl, lower alkyl, substituted aralkyl or aralkyl;
- R2 is selected from H, acyl, substituted aralkyl, aralkyl, phosphonyl, —SO2R3;
- —C(O)R5;
- —C(O)OR7 or —C(O)NR9R10;
- R3;
- R5;
- R7;
- R9 and R10 are each independently selected from H, substituted lower alkyl, lower alkyl, substituted aralkyl, aralkyl, substituted aryl or aryl;
- or
- (B)(ii) a compound, or a protonate or salt thereof, having a structure represented by:
- wherein Y is
- wherein R50, R51, R52, R53, R54 and R55 are each independently selected from hydrogen, alkyl, substituted alkyl, a polyether moiety, carboxyl, substituted carboxyl, carbamate, substituted carbonate, carbonyloxy, alkoxy, substituted alkoxy, haloalkyl, halogen, nitro, amino, aryloxy, cyano, hydroxyl, or sulfonyl;
- each R15 is independently H, alkyl, substituted alkyl, a polyether moiety, carboxyl, substituted carboxyl, carbamate, substituted carbonate, carbonyloxy, alkoxy, substituted alkoxy, haloalkyl, halogen, nitro, amino, amido, aryloxy, cyano, hydroxyl, or sulfonyl;
- each X is independently halogen, alkoxy, substituted alkoxy, alkyl, substituted alkyl or a polyether moiety;
- and
- m is 0 to 5.
24 more elements
Dependencies are inferred from the claim text.