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US 12,077,703 B2Granted
Heteroaromatic isothiocyanates
AssigneeMerck Patent GmbH
InventorsAmir Hossain Parham, Constanze Brocke, Carsten Fritzsch, Dagmar Klass
Life of this patent
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Abstract
The present invention relates to heteroaromatic isothiocyanates of formula N as defined in claim 1, to liquid-crystalline media comprising one or more compounds of formula N and to high-frequency components comprising these media, especially microwave components for high-frequency devices, such as devices for shifting the phase of microwaves, tunable filters, tunable metamaterial structures, and electronic beam steering antennas, e.g. phased array antennas.
Claims17
A compound of formula N
- in which
- RN denotes H, alkyl or alkoxy each having 1 to 12 C atoms, or alkenyl, alkenyloxy or alkoxyalkyl each having 2 to 12 C atoms, in which one or more CH2-groups may be replaced by
- or denotes a group RP,
- RP denotes halogen, CN, NCS, RF, RF—O— or RF—S—, wherein
- RF denotes fluorinated alkyl having 1 to 9 C atoms or fluorinated alkenyl having 2 to 9 C atoms,
- ZN1 and ZN2, identically or differently, denote —CH═CH—, —CF═CF—, —CH═CF—, —CF═CH—, —C≡C—, —C≡C—C≡C— or a single bond,
- X denotes C—H, N, C—F or C—Cl,
- Y1 and Y2, identically or differently, denote H, Cl, F, methyl or ethyl,
- denote a radical selected from the following groups:
- a) the group consisting of 1,4-phenylene, 1,4-naphthylene and 2,6-naphthylene, in which one or two CH groups may be replaced by N and in which one or more H atoms may be replaced by L,
- b) the group consisting of trans-1,4-cyclohexylene, 1,4-cyclohexenylene, bicyclo [1.1.1]pentane-1,3-diyl, 4,4′-bicyclohexylene, bicyclo[2.2.2]octane-1,4-diyl and spiro[3.3]heptane-2,6-diyl, in which one or more non-adjacent CH2 groups may be replaced by —O— and/or —S— and in which one or more H atoms may be replaced by F,
- c) the group consisting of thiophene-2,5-diyl, thieno[3,2-b]thiophene-2,5-diyl and selenophene-2,5-diyl, each of which may also be mono- or polysubstituted by L,
- L on each occurrence, identically or differently, denotes F, CI, CN, SCN, SF5 or straight-chain, in each case optionally fluorinated, alkyl, alkoxy, alkylcarbonyl, alkoxycarbonyl, alkylcarbonyloxy or alkoxycarbonyloxy having 1 to 12 C atoms, or branched, in each case optionally fluorinated, alkyl, alkoxy, alkylcarbonyl, alkoxycarbonyl, alkylcarbonyloxy or alkoxycarbonyloxy having 3 to 12 C atoms, and
- t is 0, 1 or 2.
11 more elements
Dependencies are inferred from the claim text.