Inorganic particle coating composition including binder, silane-based dispersant, fatty acid, and polymer polyol, method for preparing separator using the same, and separator and lithium battery employing the separator
AssigneeSamsung SDI Co., Ltd.
InventorsDaehyun Hong, Dowon Kim
Life of this patent
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Abstract
A coating composition is used to prepare a separator for a rechargeable lithium battery. The coating composition includes inorganic particles, a binder, a silane-based dispersant, and a polymeric additive, the silane-based dispersant includes a silane-based compound having fewer than 8 carbons in an alkyl main chain, and the polymeric additive includes a fatty acid compound and a polymer polyol. The coating composition may have secured or improved long-term storage stability, and may thus provide for a composite separator having a reduced number of black spot defects after coating the separator.
Claims19
A coating composition for a separator, the coating composition comprising:
- inorganic particles;
- a binder;
- a silane-based dispersant;
- and
- a polymeric additive,
- wherein:
- the silane-based dispersant consists of a silane-based compound comprising an alkyl main chain having one to seven carbons,
- the polymeric additive comprises a fatty acid compound and a polymer polyol,
- the silane-based compound comprises at least one selected from a vinyl alkyl alkoxysilane, an epoxy alkyl alkoxysilane, an amino alkyl alkoxysilane, a mercaptoalkyl alkoxysilane, a halogenated alkyl alkoxysilane, and an alkyl acyloxysilane,
- the fatty acid compound comprises a C15 to C30 unsaturated fatty acid compound, a C15 to C30 saturated fatty acid compound, or a combination thereof,
- the polymer polyol comprises one or more selected from a polycarbonate polyol, a polyester polyol, polyether polyol, a poly(meth)acryl polyol, and a polydiene polyol,
- wherein an acid value of the fatty acid compound is about 20 mg KOH/g to about 600 mg KOH/g, and
- wherein:
- an amount of the polymeric additive is about 1 to about 20 parts by weight, based on 100 parts by weight of the inorganic particles,
- a weight ratio of the fatty acid compound and the polymer polyol is about 1:0.2 to about 1:2, and
- the polymer polyol has a number average molecular weight of about 500 to about 5000, and has no alicyclic structure.
Dependencies are inferred from the claim text.