US 12,060,311 B2 · Method for producing aromatic nitrile by ammoxidation reaction

Abstract

The present invention can provide a method for producing an aromatic nitrile in which a fixed-bed reactor including a plurality of reaction tubes is used to subject a gaseous mixture comprising an aromatic hydrocarbon, ammonia, and oxygen by contact catalytic reaction on a catalyst to thereby produce the corresponding aromatic nitrile, wherein the catalyst is composed of an oxide containing vanadium, chromium, and boron and one or more supports selected from among alumina, silica-alumina, zirconia, and titania. One of the reaction tubes is filled with the catalyst of one kind and examined as to where a hot spot lies therein. An inert substance is filled into that portion of each of the plurality of reaction tubes which corresponds at least to the hot spot, and the catalyst is filled into the remaining portions.

Claims18

Dependent claims

A method for producing an aromatic nitrile, the method comprising:

contacting a gaseous mixture comprising an aromatic hydrocarbon, ammonia, and oxygen with a catalyst within a fixed bed reactor comprising a plurality of reaction tubes to produce the corresponding aromatic nitrile,
wherein the catalyst comprises an oxide comprising vanadium, chromium, and boron, and at least one support selected from the group consisting of alumina, silica-alumina, zirconia, and titania, and
wherein one of the reaction tubes is filled with the catalyst to identify a site of a hot spot, and then, for each of the other reaction tubes, a part in each of the other reaction tubes corresponding at least to the hot spot is filled with an inert substance while a part other than that in each of the other reaction tubes is filled with the catalyst.

A method for producing an aromatic nitrile, the method comprising:

contacting a gaseous mixture comprising an aromatic hydrocarbon, ammonia, and oxygen with a catalyst within a fixed bed reactor comprising a plurality of reaction tubes to produce the corresponding aromatic nitrile,
wherein the catalyst comprises an oxide comprising vanadium, chromium, and boron, and at least one support selected from the group consisting of alumina, silica-alumina, zirconia, and titania, and
wherein one of the reaction tubes is filled with the catalyst to identify a site of a hot spot, and then, for each of the other reaction tubes, a part in each of the other reaction tubes corresponding at least to the hot spot is filled with a mixture of the catalyst and an inert substance while a part other than that in each of the other reaction tubes is filled with the catalyst.

A method for producing an aromatic nitrile, the method comprising:

contacting a gaseous mixture comprising an aromatic hydrocarbon, ammonia, and oxygen with a catalyst within a fixed bed reactor comprising a plurality of reaction tubes to produce the corresponding aromatic nitrile,
wherein the catalyst comprises an oxide comprising vanadium, chromium, and boron, and at least one support selected from the group consisting of alumina, silica-alumina, zirconia, and titania, and
wherein one of the reaction tubes is filled with the catalyst to identify a site of a hot spot, and then, for each of the other reaction tubes, a part in each of the other reaction tubes corresponding at least to the hot spot is filled with the catalyst while a part other than that in each of the other reaction tubes is filled with a catalyst free of boron or a catalyst having a lower concentration of boron than the catalyst.

A method for producing an aromatic nitrile, the method comprising:

contacting a gaseous mixture comprising an aromatic hydrocarbon, ammonia, and oxygen with a catalyst within a fixed bed reactor comprising a plurality of reaction tubes to produce the corresponding aromatic nitrile,
wherein the catalyst comprises an oxide comprising vanadium, chromium, and boron, and at least one support selected from the group consisting of alumina, silica-alumina, zirconia, and titania, and
wherein one of the reaction tubes is filled with the catalyst to identify a site of a hot spot, and then, for each of the other reaction tubes, a part in each of the other reaction tubes corresponding at least to the hot spot is filled a first catalyst while a part other than that in each of the other reaction tubes is filled with a second catalyst having a higher calcination temperature than the first catalyst, and
wherein the catalyst is the same as the first catalyst or the second catalyst, or is different from the first catalyst and the second catalyst.

1 more element

Dependencies are inferred from the claim text.

Method for producing aromatic nitrile by ammoxidation reaction

Life of this patent

Method for producing aromatic nitrile by ammoxidation reaction

Life of this patent

Abstract

Claims18