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US 12,049,434 B2Granted
Even carbon number paraffin composition and method of manufacturing same
AssigneeReg Synthetic Fuels, LLC
InventorsRamin Abhari, H. Lynn Tomlinson, Vladimir Gruver
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Abstract
Paraffin compositions including mainly even carbon number paraffins, and a method for manufacturing the same, is disclosed herein. In one embodiment, the method involves contacting naturally occurring fatty acid/glycerides with hydrogen in a slurry bubble column reactor containing bimetallic catalysts with equivalent particle diameters from about 10 to about 400 micron. The even carbon number compositions are particularly useful as phase change material.
Claims20
A method comprising:
- feeding naturally occurring fatty acids and esters to a slurry bubble column reactor containing a gas phase and a catalyst in a slurry phase, where the catalyst comprises nickel, molybdenum, cobalt, tungsten, or a combination of any two or more thereof, and the catalyst has an equivalent particle diameter of about 10 microns to about 400 microns;
- partially hydrogenating/hydrogenolyzing the naturally occurring fatty acids and esters in the slurry bubble column reactor to produce a partially converted product;
- transferring the partially converted product to a fixed-bed reactor;
- hydrogenating/hydrogenolyzing the partially converted product in the fixed-bed reactor;
- and
- withdrawing a liquid product stream from the reactor;
- wherein
- the slurry bubble column reactor contains the catalyst in an amount of 1% to 30% based on dry bulk catalyst volume per total slurry volume;
- the slurry bubble column reactor is controlled to be within 315° C. to 343° C. and within 200 psig to about 2,000 psig;
- and
- the liquid product stream comprises at least 75 wt % even carbon number paraffins selected from the C12-C24 range.
8 more elements
Dependencies are inferred from the claim text.