Polymer, composition, molded article, cured product and laminate
AssigneeJsr Corporation
InventorsRyouyuu Hifumi, Toshiaki Kadota, Nobuyuki Miyaki, Shintarou Fujitomi, Yasutaka Yoshida, Ryouji Tatara
Life of this patent
Estimating the term…
Abstract
A novel polymer having high glass transition temperature and an excellent balance between heat resistance, high refractive index and mechanical properties, and a composition and molded article containing the polymer are provided. The polymer according to the invention has a first structural unit represented by at least one of formulae (1-1), (1-2) and (1-3) below and a second structural unit having either a secondary amino structure or a tertiary amino structure at two or more terminals.
Claims8
A polymer comprising:
- a first structural unit represented by at least one of formulae (1-1), (1-2) and (1-3) below;
- and
- a second structural unit represented by formula (2-A) below;
- wherein in the first structual unit is directly bonded to the second structural unit,
- wherein in formulae (1-1) to (1-3), R1 is each independently a halogen atom, a monovalent hydrocarbon group having 1 to 20 carbon atoms, a monovalent halogenated hydrocarbon group having 1 to 20 carbon atoms, a nitro group, a cyano group, any of primary to tertiary amino groups or a salt of any of primary to tertiary amino groups;
- n is each independently an integer of 0 to 2;
- and when n is 2, two or more R1 may be the same or different and may be joined together in any combination to form a part of a cyclic structure,
- in formula (2-A), R2 and R3 are respectively and independently a hydrogen atom or a monovalent hydrocarbon group having 1 to 20 carbon atoms;
- and X is a group represented by formulae (2-1) and (2-5) to (2-8) below,
- in formula (2-1), R4 and R5 are respectively and independently a halogen atom, a monovalent hydrocarbon group having 1 to 20 carbon atoms, a monovalent halogenated hydrocarbon group having 1 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, an alkylthio group having 1 to 20 carbon atoms, a nitro group, a cyano group, a carboxy group, a sulfonic acid group, a phosphonic acid group, a phosphoric acid group, a hydroxy group, any of primary to tertiary amino groups, a salt of carboxy group, a salt of sulfo group, a salt of phosphonic acid group, a salt of phosphate group, a salt of hydroxy group or a salt of any of primary to tertiary amino groups;
- c and d are respectively and independently an integer of 0 to 2;
- a and b are respectively and independently an integer of 0 to 8;
- when a is 2 or more, two or more R4 may be the same or different and may be joined together in any combination to form a part of a cyclic structure;
- when b is 2 or more, two or more R5 may be the same or different and may be joined together in any combination to form a part of a cyclic structure;
- Q and Z are respectively and independently a single bond, —O—, —S— or —N(R17) —;
- R17 is a hydrogen atom, a monovalent hydrocarbon group having 1 to 20 carbon atoms or a monovalent halogenated hydrocarbon group having 1 to 20 carbon atoms;
- L is —O—, —S—, —C(O)—, —S(O)—, —S(O)2—, —C(O)—NH—, —C(O)—O—, a methylene group, an alkylene group having 2 to 20 carbon atoms, a halogenated methylene group, a halogenated alkylene group having 2 to 20 carbon atoms, bivalent groups derived from fluorene, bivalent groups derived from phenolphthalein, or a group represented by formula (L1);
- y is 1;
- R6 and R7 are respectively and independently a single bond, a methylene group or an alkylene group having 2 to 4 carbon atoms;
- in formula (L1), Rc is a 5- to 15-membered bivalent alicyclic hydrocarbon group;
- in formula (2-5), R21 and R22 are respectively and independently a halogen atom, a monovalent hydrocarbon group having 1 to 20 carbon atoms, a monovalent halogenated hydrocarbon group having 1 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, an alkylthio group having 1 to 20 carbon atoms, a nitro group, a cyano group, a carboxy group, a sulfonic acid group, a phosphonic acid group, a phosphoric acid group, a hydroxy group, any of primary to tertiary amino groups, a salt of carboxy group, a salt of sulfo group, a salt of phosphonic acid group, a salt of phosphate group, a salt of hydroxy group or a salt of any of primary to tertiary amino groups;
- k and I are respectively and independently an integer of 0 to 3;
- when k is 2 or 3, two or more R21 may be the same or different;
- when 1 is 2 or 3, two or more R22 may be the same or different;
- R23 is a single bond, —O—, —S—, —C(O)—, —S(O)— or —S(O)2—;
- in formula (2-6), R24 and R25 are respectively and independently a halogen atom, a monovalent hydrocarbon group having 1 to 20 carbon atoms, a monovalent halogenated hydrocarbon group having 1 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, an alkylthio group having 1 to 20 carbon atoms, a nitro group, a cyano group, a carboxy group, a sulfonic acid group, a phosphonic acid group, a phosphoric acid group, a hydroxy group, any of primary to tertiary amino groups, a salt of carboxy group, a salt of sulfo group, a salt of phosphonic acid group, a salt of phosphate group, a salt of hydroxy group or a salt of any of primary to tertiary amino groups;
- m and n are respectively and independently an integer of 0 to 3;
- when m is 2 or 3, two or more R24 may be the same or different;
- when n is 2 or more, two or more R25 may be the same or different;
- R26 and R27 are respectively and independently a single bond, —O—, —S—, —C(O)—, —S(O)— or —S(O)2—;
- in formula (2-7), R28 and R29 are respectively and independently a halogen atom, a monovalent hydrocarbon group having 1 to 20 carbon atoms, a monovalent halogenated hydrocarbon group having 1 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, an alkylthio group having 1 to 20 carbon atoms, a nitro group, a cyano group, a carboxy group, a sulfonic acid group, a phosphonic acid group, a phosphoric acid group, a hydroxy group, any of primary to tertiary amino groups, a salt of carboxy group, a salt of sulfo group, a salt of phosphonic acid group, a salt of phosphate group, a salt of hydroxy group or a salt of any of primary to tertiary amino groups;
- o is an integer of 0 to 3;
- p is an integer of 0 to 4;
- when o is 2 or more, two or more R28 may be the same or different;
- when p is 2 or more, two or more R29 may be the same or different;
- n is an integer of 0 to 6;
- R30 is a monovalent hydrocarbon group having 1 to 20 carbon atoms or a monovalent halogenated hydrocarbon group having 1 to 20 carbon atoms;
- q is an integer of 0 to 15;
- when q is 2 or more, two or more R30 may be the same or different;
- in formula (2-8), R31 and R32 are respectively and independently a halogen atom, a monovalent hydrocarbon group having 1 to 20 carbon atoms, a monovalent halogenated hydrocarbon group having 1 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, an alkylthio group having 1 to 20 carbon atoms, a nitro group, a cyano group, a carboxy group, a sulfonic acid group, a phosphonic acid group, a phosphoric acid group, a hydroxy group, any of primary to tertiary amino groups, a salt of carboxy group, a salt of sulfo group, a salt of phosphonic acid group, a salt of phosphate group, a salt of hydroxy group or a salt of any of primary to tertiary amino groups, r and s are respectively and independently an integer of 0 to 4;
- when r is 2 or more, two or more R31 may be the same or different;
- when s is 2 or more, two or more R32 may be the same or different;
- m is an integer of 1 to 5;
- n is an integer of 0 to 5;
- R33 is a monovalent hydrocarbon group having 1 to 20 carbon atoms or a monovalent halogenated hydrocarbon group having 1 to 20 carbon atoms, tis an integer of 0 to 20;
- when tis 2 or more, two or more R33 may be the same or different.
A composition comprising:
- a polymer having a structural unit represented by at least one of formulae (1-1), (1-2) and (1-3) below and a second structural unit represented by formula (2) below;
- a curable compound;
- and
- a curing auxiliary agent,
- wherein formulae (1-1) to (1-3), R1 is each independently a halogen atom, a monovalent hydrocarbon group having 1 to 20 carbon atoms, a monovalent halogenated hydrocarbon group having 1 to 20 carbon atoms, a nitro group, a cyano group, any of primary to tertiary amino groups or a salt of any of primary to tertiary amino groups;
- n is each independently an integer of 0 to 2;
- and when n is 2, two or more R1 may be the same or different and may be joined together in any combination to form a part of a cyclic structure;
- in formula (2), A1 and A2 are respectively and independently —O—, —S— or —N(R2) —;
- R2 is a hydrogen atom or a monovalent hydrocarbon group having 1 to 20 carbon atoms;
- and X is a group represented by formula (2-1) below;
- in formula (2-1), R4 and R5 are respectively and independently a halogen atom, a monovalent hydrocarbon group having 1 to 20 carbon atoms, a monovalent halogenated hydrocarbon group having 1 to 20 carbon atoms, an alkoxy group having 1 to 20 carbon atoms, an alkylthio group having 1 to 20 carbon atoms, a nitro group, a cyano group, a carboxy group, a sulfonic acid group, a phosphonic acid group, a phosphoric acid group, a hydroxy group, any of primary to tertiary amino groups, a salt of carboxy group, a salt of sulfo group, a salt of phosphonic acid group, a salt of phosphate group, a salt of hydroxy group or a salt of any of primary to tertiary amino groups;
- c and d are respectively and independently an integer of 0 to 2;
- a and b are respectively and independently an integer of 0 to 8;
- when a is 2 or more, two or more R4 may be the same or different and may be joined together in any combination to form a part of a cyclic structure;
- when b is 2 or more, two or more R5 may be the same or different and may be joined together in any combination to form a part of a cyclic structure;
- Q and Z are respectively and independently a single bond, —O—, —S— or —N(R17) —;
- R17 is a hydrogen atom, a monovalent hydrocarbon group having 1 to 20 carbon atoms or a monovalent halogenated hydrocarbon group having 1 to 20 carbon atoms;
- L is a group represented by formula (L1) below;
- y is 1;
- R6 and R7 are respectively and independently a single bond, a methylene group or an alkylene group having 2 to 4 carbon atoms;
- in formula (L1), Rc is 5- to 15-membered monocyclic alicyclic hydrocarbon group;
- wherein the curable compound is at least one selected from the group consisting of a cyanate ester compound, a vinyl compound, a silicone compound, an oxazine compound, a maleimide compound and an allyl compound;
- when the curable compound used is the cyanate ester compound, the curing auxiliary agent is a basic active hydrogen compound, polymercaptan curing agents, or urea resins;
- when the curable compound used is the vinyl compound, the curing auxiliary agent is compounds that generate radical active species by heat or light;
- when the curable compound used is the silicone compound, the curing auxiliary agent is zinc benzoate, zinc octylate, platinum black, platinic chloride, chloroplatinic acid, reaction products of chloroplatinic acid and monohydric alcohols, complexes of chloroplatinic acid and olefins and platinum bisacetoacetate, palladium catalysts, rhodium catalysts, or photoreaction initiator;
- when the curable compound used is the oxazine compound, the curing auxiliary agent is p-toluenesulfonate esters, aromatic amine compounds, or boron trifluoride;
- when the curable compound used is the maleimide compound, the curing auxiliary agent is imidazole, 1-methylimidazole, 1-benzyl-2-methylimidazole, 2-methylimidazoline, N,N-diisopropylethylamine, 1,4-dimethylpiperazine, quinoline, triazole, benzotriazole, DBU, phosphorus compounds or azobisisobutylnitrile;
- when the curable compound used is the allyl compound, the curing auxiliary agent is azo initiators, peroxides, acetophenone curing agents, benzoin curing agents, phosphorus curing agents, sulfur curing agents, benzyl curing agents, or peroxycarbonate curing agents.
Dependencies are inferred from the claim text.