Magnesium silicate processing
AssigneeAspiring Materials Limited
InventorsAllan Charles Nye Scott, Christopher John-Paul Oze
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Abstract
Methods of processing magnesium silicate materials are described to produce a number of products including magnesium hydroxide. Related methods of use of processed magnesium silicate and other reaction products are described for energy production, cement manufacture and carbon sequestration. In one embodiment the method comprises subjecting a magnesium silicate source to an acid digestion; increasing the digested liquid pH to produce a magnesium salt solution; subjecting the magnesium salt solution to electrolysis; and recovering magnesium hydroxide produced from electrolysis. By-products such as silica, iron oxy(oxides) and others are also described along with further reaction products such as magnesium oxide and magnesium carbonate.
Claims17
A method of processing a magnesium silicate source by the steps of:
- selecting a magnesium silicate source selected from:
- olivine, serpentine, pyroxene, amphiboles, phyllosilicates, clays, and combinations thereof,
- subjecting the selected magnesium silicate source to water digestion at a temperature of less than 120° C. and wherein the ratio, by mass, of magnesium silicate source to water in the water digestion is 1 part magnesium silicate to 1 to 20 parts water to form a washed magnesium silicate;
- subjecting the washed magnesium silicate to acid digestion, to produce a digested solution, acid digestion comprising mixing the washed magnesium silicate at a temperature of less than 120° C. with hydrochloric acid or sulfuric acid sufficient to decrease the pH of the mixture to −1-6 and, recovering evolved hydrogen gas during acid digestion;
- completing a base wash by increasing the digested solution pH by addition of an alkali solution at a temperature of less than 120° C., to produce a magnesium salt solution consisting of magnesium chloride, magnesium sulphate, or both magnesium chloride and magnesium sulphate, wherein the base wash comprises two pH increasing steps including:
- a first increase in digested solution pH by at least 1 to 3 pH greater than the digested solution pH and removing precipitated silica from the magnesium salt solution;
- and
- a subsequent pH increase in digested solution pH to a pH of 6.0 or higher and removing precipitated iron oxide from the magnesium salt solution;
- subjecting the magnesium salt solution to electrolysis at a temperature of less than 120° C.;
- and
- recovering magnesium hydroxide produced from electrolysis from an electrolysis cathode and oxygen and chlorine from an electrolysis anode.
Dependencies are inferred from the claim text.