Organosilicon compound, method for producing thereof, and use thereof
AssigneesDow Toray Co., Ltd., Dow Global Technologies LLC
InventorsEun Sil Jang, Takuya Ogawa, Tadashi Okawa
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Abstract
An organosilicon compound having not more than 200 silicon atoms per molecule is provided. The organosilicon compound is represented by the following average compositional formula (I): YaR1bSiO(4-a-b)/2 wherein R1 is an alkyl group having 1 to 12 carbon atoms, alkenyl group having 2 to 12 carbon atoms, aryl group having 6 to 20 carbon atoms, alkoxy group having 1 to 6 carbon atoms, or a hydroxyl group; Y is a specific acylphosphinate residue; and subscripts a and b are numbers satisfying the following conditions: 0<a≤2, 0<b≤3, and a≤b. The organosilicon compound is compatible with organopolysiloxanes and is useful as a photo-initiator for various types of photo-curable compositions.
Claims7
A method for producing an organosilicon compound having not more than 200 silicon atoms per molecule, and represented by the following average compositional formula (I):
- YaR1bSiO(4-a-b)/2 (I)
- wherein R1 is an alkyl group having 1 to 12 carbon atoms, alkenyl group having 2 to 12 carbon atoms, aryl group having 6 to 20 carbon atoms, alkoxy group having 1 to 6 carbon atoms, or a hydroxyl group;
- Y is an acylphosphinate residue represented by the following general formula (II):
- wherein R2 is a non-substituted or halogen-substituted alkyl group having 1 to 12 carbon atoms, a non-substituted or halogen-substituted aryl group having 6 to 20 carbon atoms, an aralkyl group having 7 to 20 carbon atoms, or an alkoxy group having 1 to 6 carbon atoms;
- R3 is a linear or branched alkylene group having 1 to 12 carbon atoms;
- R4 is an alkylene group having 2 to 6 carbon atoms;
- Ar is a non-substituted, an alkoxy-substituted, or a halogen-substituted aryl group having 6 to 20 carbon atoms;
- and subscript m is an integer of from 0 to 100;
- and
- subscripts a and b are numbers satisfying the following conditions:
- 0<a≤2, 0<b≤3, and a≤b;
- the method comprising the following steps:
- i) reacting an organosilicon compound represented by the following average compositional formula (IV):
- ZaR1bSiO(4-a-b)/2 (IV)
- wherein R1 and subscripts a and b are each as described above;
- and Z is a group represented by the following general formula (V):
- wherein R3, R4 and subscript m are each as described above;
- with an organophosphine compound represented by the following general formula (VI):
- wherein R2 is as described above;
- and X are the same or different halogen atoms, to obtain a reaction product;
- and then
- ii) reacting the reaction product of step i) with a carboxylic halide represented by the following general formula (VII):
- wherein X and Ar are each as described above.
Dependencies are inferred from the claim text.