# US 12,016,229 B2 · Electroluminescent display-panel manufacturing method

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- Number: US 12,016,229 B2
- Document ID: US12016229B2
- Status: Granted
- Kind: B2
- Application number: 17/546,010
- Filed: 2021-12-08
- Published: 2022-06-30
- Granted: 2024-06-18
- Earliest claimed: 2017-03-30
- Assignees: Qualtec Co., Ltd.
- Applicants: Qualtec Co., Ltd.
- Inventors: Hiroshi Takahara; Yuki Nagata
- Web page: https://patentgrep.com/patent/US12016229B2

## CPC

- H10K 59/30: Devices specially adapted for multicolour light emission
- G09F 9/00: Indicating arrangements for variable information in which the information is built-up on a support by selection or combination of individual elements (in which the variable information is permanently attached to a movable support G09F11/00; abacus G06C1/00; slide-rules G06G1/00)
- G09F 9/30: in which the desired character or characters are formed by combining individual elements (panels comprising a number of electrodes in a single cell controlling light arriving from an independent light source, e.g. electro-optical or magneto-optical cell, G02F1/00)
- H05B 33/10: Apparatus or processes specially adapted to the manufacture of electroluminescent light sources
- H10K 50/13: comprising stacked EL layers within one EL unit
- H10K 50/15: Hole transporting layers
- H10K 59/35: comprising red-green-blue [RGB] subpixels
- H10K 59/80524: {Transparent cathodes, e.g. comprising thin metal layers}
- H10K 59/876: {comprising a resonant cavity structure, e.g. Bragg reflector pair}
- H10K 59/878: {comprising reflective means}
- H10K 59/8791: {Arrangements for improving contrast, e.g. preventing reflection of ambient light}
- H10K 71/166: {using selective deposition, e.g. using a mask}
- H10K 71/421: {using coherent electromagnetic radiation, e.g. laser annealing}
- H10K 2101/30: Highest occupied molecular orbital [HOMO], lowest unoccupied molecular orbital [LUMO] or Fermi energy values
- H10K: ORGANIC ELECTRIC SOLID-STATE DEVICES
- G09F: DISPLAYING; ADVERTISING; SIGNS; LABELS OR NAME-PLATES; SEALS
- H05B: ELECTRIC HEATING; ELECTRIC LIGHT SOURCES NOT OTHERWISE PROVIDED FOR; CIRCUIT ARRANGEMENTS FOR ELECTRIC LIGHT SOURCES, IN GENERAL

## Abstract

In EL display panels fabricated by vapor deposition, a vapor-deposition fine mask is employed to form red, green, and blue pixels. An issue, however, has been that misregistration of the vapor-deposition fine mask occurs, lowering manufacturing yields. To resolve this issue, on a thin-film transistor (TFT) substrate, red, green, and blue pixel electrodes are fashioned in matrix form. The TFT substrate is conveyed into a vapor-deposition chamber. Under a vacuum, an organic evaporation source is employed to codeposit a light-emitting layer composed of a host material and a red guest material on the TFT substrate display screen. An ultraviolet laser beam generated by a laser device is optically guided into the vapor-deposition chamber through a laser window and directed on the light-emitting layer formed onto the green and blue pixel electrodes. Positional selecting on the green and blue pixels is carried out by controlling a mirror galvanometer.

## Claims

### Claim 1

A method of manufacturing an electroluminescent (EL) display panel in which pixels of a first color, pixels of a second color, and pixels of a third color are disposed in matrix form, the EL display panel manufacturing method comprising:
a step of forming a first light-emitting layer on pixels of at least any of said colors;
a step of directing an ultraviolet laser beam into the first light-emitting layer over a given pixel,
a step of in an optical amplifier circuit photoelectrically converting into a signal voltage fluorescence or phosphorescence emitted by the first light-emitting layer under excitation by being irradiated with the ultraviolet laser beam:
a step of inputting the signal voltage into a laser control circuit for controlling the intensity of the ultraviolet laser beam, and with the laser control circuit detecting the relative strength of the fluorescence or phosphorescence emitted by the first light-emitting to detect whether the fluorescence or phosphorescence is a predetermined intensity setting or within a predetermined intensity range, to determine that the first light-emitting layer on the given pixel has become reformed; and
a step of, upon determining that the first light-emitting layer on the given pixel has become reformed, shifting the ultraviolet laser beam to a position on the first-light-emitting layer over a next pixel.

### Claim 2 (depends on 1)

The EL display panel manufacturing method set forth in claim 1, wherein the ultraviolet laser beam and the fluorescence or phosphorescence are separated with an optical filter.

### Claim 3 (depends on 1)

The EL display panel manufacturing method set forth in claim 1, wherein
the ultraviolet laser beam is from a pulsed-mode laser device;
the wavelength of the laser beam is from at least 310 nm to not more than 400 nm; and
the laser beam irradiates the same location on the first light-emitting layer with a plurality of pulses.

### Claim 4 (depends on 1)

The EL display panel manufacturing method set forth in claim 1, further including a step of forming a second light-emitting layer on pixels of any color among the pixels of the first color, the pixels of the second color, and the pixels of the third color; wherein
the first light-emitting layer is formed onto at least the second light-emitting layer;
the first light-emitting layer is formed commonly on the pixels of the first color, the pixels of the second color, and the pixels of the third color; and
the second light-emitting layer is formed utilizing a vapor-deposition fine mask.

### Claim 5 (depends on 1)

The EL display panel manufacturing method set forth in claim 1, wherein:
the first light-emitting layer contains a guest material and a host material;
in the ultraviolet laser-beam reformed first light-emitting layer, among the three relationships,
i. guest-material bandgap being greater than host-material bandgap,
ii. in terms of relative dispositions of highest occupied molecular orbitals (HOMOs) in a guest material and in a host material, guest-material HOMO disposition being lower than host-material HOMO disposition, and
iii. in terms of lowest unoccupied molecular orbitals (LUMOs) in a guest material and in a host material, guest-material LUMO disposition being higher than host-material LUMO disposition,
at least one or more relationship holds.

### Claim 6 (depends on 1)

The EL display panel manufacturing method set forth in claim 1, wherein:
the first light-emitting layer is formed by codeposition of host materials and guest materials; and
the guest material is of absorptivity with respect to the ultraviolet laser beam that is greater than that of the host material.

### Claim 7 (depends on 1)

The EL display panel manufacturing method set forth in claim 1, wherein the first light-emitting layer is irradiated with the ultraviolet laser beam via a slit in a slit mask.

### Claim 8 (depends on 1)

The EL display panel manufacturing method set forth in claim 1, further including a step of forming a second light-emitting layer on pixels of any color among the pixels of the first color, the pixels of the second color, and the pixels of the third color; wherein
the first light-emitting layer is formed onto at least the second light-emitting layer;
the first light-emitting layer is formed commonly on the pixels of the first color, the pixels of the second color, and the pixels of the third color; and
a thermal transfer technique is utilized to form the second light-emitting layer.

### Claim 9 (depends on 1)

The EL display panel manufacturing method set forth in claim 1, wherein:
the step of forming a first light-emitting layer is carried out within a high-vacuum chamber; and
in the step of directing an ultraviolet laser beam onto the first light-emitting layer, the ultraviolet laser beam is introduced through a window in the high-vacuum chamber.

### Claim 10 (depends on 5)

The EL display panel manufacturing method set forth in claim 5, wherein:
a hole-transport layer is formed on an underlayer of the first light-emitting layer; and
the guest material is of absorptivity with respect to the first light that is greater than that of the host material.

### Claim 11 (depends on 5)

The EL display panel manufacturing method set forth in claim 5, wherein:
a layer emitting blue light is formed on the pixels of a third color;
a hole-transport layer is formed on an underlayer of the blue light-emitting layer; and
said hole-transport layer is of film thickness that is thicker than that of hole-transport layers on the pixels of the other colors.