# US 12,015,181 B2 · Electrolyte sheet for solid oxide fuel cell, manufacturing method for electrolyte sheet for solid oxide fuel cell, and single cell for solid oxide fuel cell

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- Number: US 12,015,181 B2
- Document ID: US12015181B2
- Status: Granted
- Kind: B2
- Application number: 17/673,319
- Filed: 2022-02-16
- Published: 2022-06-02
- Granted: 2024-06-18
- Earliest claimed: 2019-08-22
- Assignees: Murata Manufacturing Co., Ltd.
- Applicants: Murata Manufacturing Co., Ltd.
- Inventors: Hideaki Nakai
- Web page: https://patentgrep.com/patent/US12015181B2

## CPC

- H01M 8/1016: characterised by the electrolyte material (H01M8/12 takes precedence)
- C04B 35/486: Fine ceramics
- H01M 2300/0071: Oxides
- Y02E 60/50: Fuel cells
- Y02P 70/50: Manufacturing or production processes characterised by the final manufactured product
- H01M: PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- C04B: LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE {(roofing granules E04D7/005)}; CERAMICS (devitrified glass-ceramics C03C10/00); REFRACTORIES; TREATMENT OF NATURAL STONE
- Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02P: CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS

## Abstract

An electrolyte sheet for solid oxide fuel cells that includes a ceramic plate body having a warpage height of not more than 300 μm, wherein a maximum value among values of 100×Q/LX, 100×R/LY, and 100×S/LX is not greater than 1, where Q is a maximum difference between a second side D2 and a second virtual straight line V2 in an X coordinate, R is a maximum difference between a third side D3 and a third virtual straight line V3 in a Y coordinate, S is a maximum difference between a fourth side D4 and a fourth virtual straight line V4 in the X coordinate, LX is a length of a virtual rectangle in an X-axis direction, and LY is a length of the virtual rectangle in a Y-axis direction.

## Claims

### Claim 1

An electrolyte sheet for solid oxide fuel cells, the electrolyte sheet comprising:
a ceramic plate body having a warpage height of not more than 300 μm,
the ceramic plate body having a shape defined by four sides in clockwise order in a plan view from a thickness direction of the ceramic plate body, the sides including a first side, a second side meeting the first side at a first corner, a third side meeting the second side at a second corner, and a fourth side meeting the third side at a third corner and meeting the first side at a fourth corner,
wherein in an XY coordinate system of the ceramic plate body in the plan view from the thickness direction with an X axis being a first virtual straight line approximated with 10 points on the first side, a Y axis being a second virtual straight line perpendicular to the first virtual straight line and passing through a point with an X coordinate representing an average of X coordinates of 10 points on the second side, and a virtual origin being an intersection of the first virtual straight line and the second virtual straight line, a third virtual straight line parallel to the first virtual straight line and passing through a point with a Y coordinate representing an average of Y coordinates of 10 points on the third side and a fourth virtual straight line perpendicular to the first virtual straight line and passing through a point with an X coordinate representing an average of X coordinates of 10 points on the fourth side are defined such that a maximum value among values of 100×Q/LX, 100×R/LY, and 100×S/LX is not greater than 1, where Q is a maximum difference between the second side and the second virtual straight line in the X coordinate, R is a maximum difference between the third side and the third virtual straight line in the Y coordinate, S is a maximum difference between the fourth side and the fourth virtual straight line in the X coordinate, LX is a length of a virtual rectangle in an X-axis direction, and LY is a length of the virtual rectangle in a Y-axis direction, the virtual rectangle being defined by the first virtual straight line, the second virtual straight line, the third virtual straight line, and the fourth virtual straight line.

### Claim 2 (depends on 1)

The electrolyte sheet for solid oxide fuel cells according to claim 1, wherein the ceramic plate body contains sintered scandia-stabilized zirconia.

### Claim 3 (depends on 1)

The electrolyte sheet for solid oxide fuel cells according to claim 1, wherein the ceramic plate body has a thickness of 30 μm to 200 μm.

### Claim 4 (depends on 1)

The electrolyte sheet for solid oxide fuel cells according to claim 1, wherein the ceramic plate body has a first main surface and a second main surface opposite the first main surface, and one or both of the first main surface and the second main surface include scattered recesses.

### Claim 5 (depends on 1)

The electrolyte sheet for solid oxide fuel cells according to claim 1, wherein the warpage height of the ceramic plate body is not more than 200 μm.

### Claim 6 (depends on 1)

The electrolyte sheet for solid oxide fuel cells according to claim 1, wherein the maximum value among the values of 100×Q/LX, 100×R/LY, and 100×S/LX is not greater than 0.5.

### Claim 7 (depends on 1)

A unit cell for solid oxide fuel cells, the unit cell comprising:
a fuel electrode;
an air electrode; and
the electrolyte sheet for solid oxide fuel cells according to claim 1 between the fuel electrode and the air electrode.

### Claim 8

A method of producing an electrolyte sheet for solid oxide fuel cells, the method comprising:
pressing together an unsintered plate body containing a ceramic material powder and a resin layer containing a resin powder by hydrostatic pressure to produce an unsintered body; and
firing the unsintered body to burn off the resin layer and sinter the unsintered plate body into a ceramic plate body.

### Claim 9 (depends on 8)

The method of producing an electrolyte sheet for solid oxide fuel cells according to claim 8, wherein in the producing of the unsintered body, the unsintered plate body and the resin layer are preheated at 60° C. or higher and lower than 100° C. for at least five minutes before being pressed together by the hydrostatic pressure.

### Claim 10 (depends on 8)

The method of producing an electrolyte sheet for solid oxide fuel cells according to claim 8, wherein the ceramic material powder contains scandia-stabilized zirconia powder.

### Claim 11 (depends on 8)

The method of producing an electrolyte sheet for solid oxide fuel cells according to claim 8, wherein the resin powder has a spherical shape.

### Claim 12 (depends on 8)

The method of producing an electrolyte sheet for solid oxide fuel cells according to claim 8, wherein the ceramic plate body has a warpage height of not more than 300 μm,
the ceramic plate body has a shape defined by four sides in clockwise order in a plan view from a thickness direction of the ceramic plate body, the sides including a first side, a second side meeting the first side at a first corner, a third side meeting the second side at a second corner, and a fourth side meeting the third side at a third corner and meeting the first side at a fourth corner,
wherein in an XY coordinate system of the ceramic plate body in the plan view from the thickness direction with an X axis being a first virtual straight line approximated with 10 points on the first side, a Y axis being a second virtual straight line perpendicular to the first virtual straight line and passing through a point with an X coordinate representing an average of X coordinates of 10 points on the second side, and a virtual origin being an intersection of the first virtual straight line and the second virtual straight line, a third virtual straight line parallel to the first virtual straight line and passing through a point with a Y coordinate representing an average of Y coordinates of 10 points on the third side and a fourth virtual straight line perpendicular to the first virtual straight line and passing through a point with an X coordinate representing an average of X coordinates of 10 points on the fourth side are defined such that a maximum value among values of 100×Q/LX, 100×R/LY, and 100×S/LY is not greater than 1, where Q is a maximum difference between the second side and the second virtual straight line in the X coordinate, R is a maximum difference between the third side and the third virtual straight line in the Y coordinate, S is a maximum difference between the fourth side and the fourth virtual straight line in the X coordinate, LX is a length of a virtual rectangle in an X-axis direction, and LY is a length of the virtual rectangle in a Y-axis direction, the virtual rectangle being defined by the first virtual straight line, the second virtual straight line, the third virtual straight line, and the fourth virtual straight line.

### Claim 13 (depends on 12)

The method of producing an electrolyte sheet for solid oxide fuel cells according to claim 12, wherein the warpage height of the ceramic plate body is not more than 200 μm.

### Claim 14 (depends on 12)

The method of producing an electrolyte sheet for solid oxide fuel cells according to claim 12, wherein the maximum value among the values of 100×Q/LX, 100×R/LY, and 100×S/LX is not greater than 0.5.

### Claim 15 (depends on 8)

The method of producing an electrolyte sheet for solid oxide fuel cells according to claim 8, wherein the ceramic plate body has a thickness of 30 μm to 200 μm.

### Claim 16 (depends on 8)

The method of producing an electrolyte sheet for solid oxide fuel cells according to claim 8, wherein the ceramic plate body has a first main surface and a second main surface opposite the first main surface, and one or both of the first main surface and the second main surface include scattered recesses.

### Claim 17 (depends on 8)

A method of producing a unit cell for solid oxide fuel cells, the method comprising:
forming the electrolyte sheet for solid oxide fuel cells according to claim 8;
forming a green sheet for a fuel electrode on a first main surface of the electrolyte sheet;
forming a green sheet for an air electrode on a second main surface of the electrolyte sheet opposite the first main surface; and
firing the electrolyte sheet having the green sheet for the fuel electrode and the green sheet for the air electrode to form the unit cell.