# US 12,014,878 B2 · Conductive paste including metal portions having different melting points and multilayer ceramic component using the same > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 12,014,878 B2 - Document ID: US12014878B2 - Status: Granted - Kind: B2 - Application number: 17/528,575 - Filed: 2021-11-17 - Published: 2023-02-23 - Granted: 2024-06-18 - Earliest claimed: 2021-08-20 - Assignees: Samsung Electro-Mechanics Co., Ltd. - Applicants: Samsung Electro-Mechanics Co., Ltd. - Inventors: Chung Hyeon Ryu; Hyo Kyong Seo; Jun Ho Yun; Ye Ji Hwang; Seung Been Kim - Web page: https://patentgrep.com/patent/US12014878B2 ## CPC - H01G 4/30: Stacked capacitors (H01G4/33 takes precedence) - H01G 2/065: {for surface mounting, e.g. chip capacitors} - H01G 4/008: Selection of materials - H01G 4/0085: {Fried electrodes} - H01G 4/012: Form of non-self-supporting electrodes - H01G 4/12: Ceramic dielectrics {(H01G4/085 takes precedence)} - H01G 4/2325: {characterised by the material of the terminals} - H01G: CAPACITORS; CAPACITORS, RECTIFIERS, DETECTORS, SWITCHING DEVICES, LIGHT-SENSITIVE OR TEMPERATURE-SENSITIVE DEVICES OF THE ELECTROLYTIC TYPE (selection of specified materials as dielectric H01B3/00; capacitors having potential barriers H10D1/62, H10K10/10) ## Abstract A conductive paste includes a core including a first metal and a shell including a second metal having a melting point higher than that of the first metal and enclosing a surface of the core. A multilayer ceramic component includes an external electrode having a sintered electrode layer made of the conductive paste. ## Claims ### Claim 1 A conductive paste, comprising: a glass; a plurality of cores comprising a first metal; and a plurality of shells comprising a second metal having a melting point higher than that of the first metal, and respectively enclosing surfaces of the plurality of cores, wherein adjacent shells, among the plurality of shells, directly contact each other such that adjacent cores, among the plurality of cores, are spaced apart from each other, and wherein at least one shell, among the plurality of shells other than the adjacent shells, directly contacts one of the adjacent shells. ### Claim 2 (depends on 1) The conductive paste of claim 1, wherein the first metal is copper (Cu), and the second metal is nickel (Ni). ### Claim 3 (depends on 1) The conductive paste of claim 1, wherein, in a conductive particle, a diameter of the core is greater than a thickness of the shell. ### Claim 4 A multilayer ceramic component, comprising: a capacitor body; and a plurality of external electrodes including a plurality of sintered electrode layers disposed on the capacitor body and spaced apart from each other, respectively, wherein each of the plurality of sintered electrode layers includes a conductive material, wherein the conductive material includes a plurality of first metal portions comprising a first metal, and a plurality of second metal portions comprising a second metal having a melting point higher than that of the first metal, wherein the plurality of second metal portions respectively surround the plurality of first metal portions and are connected thereto, wherein adjacent second metal portions, among the plurality of second metal portions, directly contact each other such that adjacent first metal portions, among the plurality of first metal portions, are spaced apart from each other, wherein at least one second metal portion, among the plurality of second metal portions other than the adjacent second metal portions, directly contacts one of the adjacent second metal portions, and wherein at least one of the plurality of sintered electrode layers further comprises glass in which the plurality of first metal portions are dispersed. ### Claim 5 (depends on 4) The multilayer ceramic component of claim 4, wherein the first metal is copper (Cu) and the second metal is nickel (Ni). ### Claim 6 (depends on 4) The multilayer ceramic component of claim 4, wherein, in the conductive material, a diameter of the plurality of first metal portions is respectively greater than a thickness of the plurality of second metal portions. ### Claim 7 (depends on 4) The multilayer ceramic component of claim 4, wherein, in the conductive material, a diameter of the plurality of first metal portions is 3.5 μm or less. ### Claim 8 (depends on 4) The multilayer ceramic component of claim 4, wherein each of the plurality of external electrodes includes a plating layer disposed on the sintered electrode layer, and the plating layer includes tin (Sn). ### Claim 9 (depends on 8) The multilayer ceramic component of claim 8, wherein the plating layer is disposed to be in direct contact with the sintered electrode layer. ### Claim 10 (depends on 4) The multilayer ceramic component of claim 4, wherein the capacitor body includes a plurality of dielectric layers and a plurality of first and second internal electrodes alternately disposed with the dielectric layers interposed therebetween. ### Claim 11 (depends on 10) The multilayer ceramic component of claim 10, wherein the capacitor body includes first and second surfaces opposing each other, and third and fourth surfaces connected to the first and second surfaces and opposing each other, wherein the plurality of sintered electrode layers include first and second sintered electrode layers connected to the first and second internal electrodes, respectively, and wherein the first and second sintered electrode layers include first and second connection portions disposed on the third and fourth surfaces of the capacitor body, respectively; and first and second band portions extending from the first and second connection portions to a portion of the first surface of the capacitor body, respectively. ### Claim 12 (depends on 4) The multilayer ceramic component of claim 4, wherein each of the plurality of sintered electrode layers further comprises glass in which the plurality of first metal portions are dispersed. ### Claim 13 (depends on 12) The multilayer ceramic component of claim 12, wherein one or more of the plurality of first metal portions are spaced apart from the glass by the plurality of second metal portions, respectively. ### Claim 14 (depends on 4) The multilayer ceramic component of claim 4, wherein each of the plurality of sintered electrode layers further comprises a plurality of third metal portions including the second metal and spaced apart from the plurality of first metal portions. ### Claim 15 (depends on 4) The multilayer ceramic component of claim 4, wherein an average diameter of the plurality of first metal portions is 3.5 μm or less.