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US 12,011,709 B2Granted
Method of improving selective hydrogenation of unsaturated hydrocarbon in aromatic fraction through catalyst pretreatment
AssigneesSK Innovation Co., Ltd., SK Geo Centric Co., Ltd.
InventorsSang Il Lee, Ji Hoon Lee
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Abstract
Disclosed is a method for providing improved hydrogenation activity by pretreating a catalyst in a three-step manner before selective hydrogenation of unsaturated hydrocarbons in an aromatic fraction in the presence of an oxide-type bimetallic (particularly nickel-molybdenum) supported catalyst.
Claims19
A method for preparing a selective hydrogenation catalyst for an unsaturated hydrocarbon in an aromatic fraction, which comprises the steps of:
- step a) providing a calcined catalyst containing nickel and molybdenum;
- step b) sulfiding the calcined catalyst containing nickel and molybdenum to give a sulfided catalyst containing nickel and molybdenum;
- step c) carrying out an oxidation treatment of the sulfided catalyst containing nickel and molybdenum at a temperature exceeding 250° C. and below 700° C. to give an oxidized catalyst containing nickel and molybdenum;
- and
- step d) carrying out a reduction treatment of the oxidized catalyst containing nickel and molybdenum to give a reduced catalyst containing nickel and molybdenum.
2 more elements
Dependencies are inferred from the claim text.