# US 12,009,552 B2 · Nonaqueous electrolyte secondary battery

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- Number: US 12,009,552 B2
- Document ID: US12009552B2
- Status: Granted
- Kind: B2
- Application number: 18/189,248
- Filed: 2023-03-24
- Published: 2023-08-03
- Granted: 2024-06-11
- Earliest claimed: 2019-09-26
- Assignees: Toyota Jidosha Kabushiki Kaisha
- Applicants: Toyota Jidosha Kabushiki Kaisha
- Inventors: Kosuke Iwase
- Web page: https://patentgrep.com/patent/US12009552B2

## CPC

- H01M 10/4235: {Safety or regulating additives or arrangements in electrodes, separators or electrolyte (H01M10/4242 takes precedence)}
- H01M 50/581: in response to temperature
- H01M 4/13: Electrodes for accumulators with non-aqueous electrolyte, e.g. for lithium-accumulators; Processes of manufacture thereof
- H01M 10/0525: Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
- H01M 10/0585: of accumulators having only flat construction elements, i.e. flat positive electrodes, flat negative electrodes and flat separators
- H01M 10/0587: of accumulators having only wound construction elements, i.e. wound positive electrodes, wound negative electrodes and wound separators
- H01M 50/406: Moulding; Embossing; Cutting
- H01M 50/417: Polyolefins
- H01M 50/463: Separators, membranes or diaphragms characterised by their shape
- H01M 50/489: Separators, membranes, diaphragms or spacing elements inside the cells, characterised by their physical properties, e.g. swelling degree, hydrophilicity or shut down properties
- H01M 50/531: Electrode connections inside a battery casing
- H01M 2200/10: Temperature sensitive devices
- Y02E 60/10: Energy storage using batteries
- Y02P 70/50: Manufacturing or production processes characterised by the final manufactured product
- H01M: PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02P: CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS

## Abstract

An electrode body of a secondary battery described herein includes: a core portion where electrode mixture layers of a plurality of electrode sheets are laminated; terminal connecting portions where respective current collector foil exposed portions are laminated, and a mixture layer non-facing portion where the electrode mixture layer faces the current collector foil exposed portion, the mixture layer non-facing portion being formed in a boundary between the terminal connecting portion and the core portion. In the secondary battery described herein, a short-circuit promoting portion having a predetermined depth (d) is formed in a separator provided between the electrode sheets in the mixture layer non-facing portion. Hereby, before a battery temperature rapidly increases to a high-temperature range due to occurrence of internal short-circuit between the electrode mixture layers, internal short-circuit is caused between the electrode mixture layer and the current collector foil exposed portion, so that charging can be stopped.

## Claims

### Claim 1

A nonaqueous electrolyte secondary battery comprising:
a separator having a first surface and a second surface;
an electrode body in which a plurality of electrode sheets is laminated via the separator;
a pair of electrode terminals electrically connected to the electrode body, and
an inorganic particle-containing layer containing inorganic particles disposed on the first surface of the separator; wherein:
each of the electrode sheets is a sheet-shaped electrode in which an electrode mixture layer is formed on a surface of a current collector foil, the each of the electrode sheets including a current collector foil exposed portion in which the current collector foil is exposed, the current collector foil exposed portion being formed in a corresponding one of side edge portions, in a width direction, of the each of the electrode sheets;
the electrode body includes
a core portion where the electrode mixture layers of the electrode sheets are laminated in a central part of the electrode body in the width direction,
terminal connecting portions to which the electrode terminals are connected, respectively, the terminal connecting portions being formed in both side edge portions of the electrode body in the width direction such that respective current collector foil exposed portions are laminated, and
a mixture layer non-facing portion formed in at least one of boundaries of the core portion with the terminal connecting portions, the mixture layer non-facing portion being configured such that the electrode mixture layer faces the current collector foil exposed portion; and
a short-circuit promoting portion constituted by a recessed portion having a depth of 30% or more of a thickness of the separator is formed in the separator provided between the electrode sheets in the mixture layer non-facing portion.

### Claim 2 (depends on 1)

The nonaqueous electrolyte secondary battery according to claim 1, wherein the short-circuit promoting portion is formed on the first surface of the separator, on which the inorganic particle-containing layer is disposed.

### Claim 3 (depends on 1)

The nonaqueous electrolyte secondary battery according to claim 1, wherein the short-circuit promoting portion is formed on the second surface of the separator, on which the inorganic particle-containing layer is not disposed.

### Claim 4 (depends on 1)

The nonaqueous electrolyte secondary battery according to claim 1, wherein the short-circuit promoting portion is an elongated groove extending along a side edge of the core portion.

### Claim 5 (depends on 1)

The nonaqueous electrolyte secondary battery according to claim 1, wherein:
joining portions where the terminal connecting portions are joined to the electrode terminals, respectively, are formed in respective connection parts of the terminal connecting portions with the electrode terminals; and
a total area of the short-circuit promoting portion is 25% or more of an area of a joining portion closer to the short-circuit promoting portion out of the joining portions.

### Claim 6 (depends on 1)

The nonaqueous electrolyte secondary battery according to claim 1, wherein the short-circuit promoting portion is formed in the separator placed on an outermost side in a thickness direction of the electrode body.

### Claim 7 (depends on 1)

The nonaqueous electrolyte secondary battery according to claim 1, wherein the short-circuit promoting portion is formed in the separator placed on an inner side in a thickness direction of the electrode body.
