# US 12,009,522 B2 · Anode for lithium metal battery and lithium metal battery comprising the same

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- Number: US 12,009,522 B2
- Document ID: US12009522B2
- Status: Granted
- Kind: B2
- Application number: 16/500,633
- Filed: 2018-12-21
- Published: 2020-03-26
- Granted: 2024-06-11
- Earliest claimed: 2017-12-22
- Assignees: LG Energy Solution, Ltd.
- Applicants: LG Chem, Ltd.
- Inventors: Jaewon Moon; Hyungkyun Yu; Hyung Seok Han; Ki Hoon Paeng
- Web page: https://patentgrep.com/patent/US12009522B2

## CPC

- H01M 4/742: {perforated material}
- H01M 4/134: Electrodes based on metals, Si or alloys
- H01M 4/382: {Lithium (H01M4/405 takes precedence)}
- H01M 4/661: {Metal or alloys, e.g. alloy coatings (H01M4/669 take precedence)}
- H01M 10/052: Li-accumulators
- H01M 10/0525: Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
- H01M 4/0404: {by coating on electrode collectors}
- H01M 4/0435: {Rolling or calendering}
- H01M 4/1395: of electrodes based on metals, Si or alloys
- H01M 2004/027: {Negative electrodes}
- Y02E 60/10: Energy storage using batteries
- H01M: PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

## Abstract

An anode for a lithium metal battery and a lithium metal battery that contains an anode for a lithium metal battery, wherein 1) using an anode current collector including multiple holes that, independently from each other, form first pores on one side of a metal plate and form second pores having relatively larger diameters than the first pores on the other side of the metal plate, penetrate inside the metal plate, and connect the first pores and the second pores, and 2) a lithium metal layer that is formed so as to face the first pores of the anode current collector. Another embodiment of the present invention provides a lithium metal battery designed such that a separator faces the second pores (pores having relatively large diameters) of the anode current collector, using the anode for a lithium metal battery of one embodiment.

## Claims

### Claim 1

An anode for a lithium metal battery, comprising
an anode current collector; and
a lithium metal layer positioned on the anode current collector,
wherein the anode current collector comprises:
a metal plate having a first side and a second side,
wherein the metal plate has a thickness ranging from 100 μm to 150 μm; and
multiple holes that, independently from each other, form first pores on the first side of the metal plate and form corresponding second pores on the second side of the metal plate,
wherein a diameter of the second pores is larger than a diameter of the corresponding first pores,
wherein the holes penetrate inside the metal plate and connect the first pores and the second pores, and
wherein the lithium metal layer faces the first pores of the anode current collector and is arranged only on the first side of the metal plate,
wherein the multiple holes, independently from each other, have a gradually decreasing constant diameter slope from the diameter of the second pore to the diameter of the first pore while penetrating inside the metal plate,
wherein the multiple holes, independently from each other, have an increasing diameter by 0.1 μm to 3 μm per 1 μm thickness of the metal plate from the diameter of the first pores to the diameter of the second pores, wherein the diameter of each of the first pores is independently 50 μm to 70 μm and wherein the diameter of each of the second pores is independently 200 μm to 350 μm.

### Claim 2 (depends on 1)

The anode for the lithium metal battery according to claim 1, wherein the multiple holes are, independently from each other, formed using soft molding, self-assembly of spherical particles, or photolithography.

### Claim 3 (depends on 1)

The anode for the lithium metal battery according to claim 1, wherein the multiple holes are, independently from each other, in the shape of a circular truncated cone, an elliptic truncated cone, or a truncated polypyramid.

### Claim 4 (depends on 1)

The anode for the lithium metal battery according to claim 1, wherein a volume occupied by the multiple holes in a total volume of 100 vol % including the metal plate and the multiple holes is 50 vol % to 90 vol %.

### Claim 5 (depends on 1)

The anode for the lithium metal battery according to claim 1, wherein the metal plate comprises one or more selected from the group consisting of copper, an alloy of copper and other metals.

### Claim 6 (depends on 1)

The anode for the lithium metal battery according to claim 1, wherein the metal plate is selected from the group consisting of a metal film, a metal sheet, or a metal foil.

### Claim 7

A lithium metal battery comprising:
an anode,
wherein the anode comprises an anode current collector; and
a lithium metal layer positioned on the anode current collector,
wherein the anode current collector comprises: a metal plate having a first side and a second side, wherein the metal plate has a thickness ranging from 100 μm to 150 μm; and multiple holes that, independently from each other, form first pores on the first side of the metal plate and form corresponding second pores on the second side of the metal plate,
wherein a diameter of the second pores is larger than a diameter of the corresponding first pores,
wherein the holes penetrate inside the metal plate and connect the first pores and the second pores,
wherein the multiple holes, independently from each other, have a gradually decreasing constant diameter slope from the diameter of the second pore to the diameter of the first pore while penetrating inside the metal plate, wherein the multiple holes, independently from each other, have an increasing diameter by 0.1 μm to 3 μm per 1 μm thickness of the metal plate from the diameter of the first pores to the diameter of the second pores, wherein the diameter of each of the first pores is independently 50 μm to 70 μm and wherein the diameter of each of the second pores is independently 200 μm to 350 μm, and
wherein the lithium metal layer faces the first pores of the anode current collector and is arranged only on the first side of the metal plate;
a separator facing the second pores of the anode current collector;
an electrolyte impregnated in the separator; and
a cathode facing the other side of the separator.

### Claim 8

An anode for a lithium metal battery, comprising
an anode current collector; and
a lithium metal layer positioned on the anode current collector,
wherein the anode current collector comprises:
a metal plate having a first side and a second side,
wherein the metal plate has a thickness ranging from 100 μm to 150 μm; and
multiple holes that, independently from each other, form first pores on the first side of the metal plate and form corresponding second pores on the second side of the metal plate,
wherein a diameter of the second pores is larger than a diameter of the corresponding first pores,
wherein the holes penetrate inside the metal plate and connect the first pores and the second pores, and
wherein the lithium metal layer faces the first pores of the anode current collector and is arranged only on the first side of the metal plate,
wherein the multiple holes, independently from each other, have a gradually decreasing constant diameter slope from the diameter of the second pore to the diameter of the first pore while penetrating inside the metal plate, wherein the slope of the diameter of the hole is 40° to 60°,
wherein the multiple holes, independently from each other, have an increasing diameter by 0.1 μm to 3 μm per 1 μm thickness of the metal plate from the diameter of the first pores to the diameter of the second pores, wherein the diameter of each of the first pores is independently 50 μm to 70 μm and wherein the diameter of each of the second pores is independently 200 μm to 350 μm.