# US 12,006,821 B2 · Bandgap detection of reactive components in fluids

> Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt

- Number: US 12,006,821 B2
- Document ID: US12006821B2
- Status: Granted
- Kind: B2
- Application number: 17/175,180
- Filed: 2021-02-12
- Published: 2021-06-03
- Granted: 2024-06-11
- Earliest claimed: 2021-02-12
- Assignees: Halliburton Energy Services, Inc.
- Applicants: Halliburton Energy Services, Inc.
- Inventors: Michael T. Pelletier; David L. Perkins; Christopher Michael Jones
- Web page: https://patentgrep.com/patent/US12006821B2

## CPC

- E21B 49/087: {Well testing, e.g. testing for reservoir productivity or formation parameters}
- G01V 8/12: using one transmitter and one receiver
- E21B 47/113: using electrical indications; using light radiations
- E21B 49/08: Obtaining fluid samples or testing fluids, in boreholes or wells
- G01N 21/77: by observing the effect on a chemical indicator
- G01N 27/12: of a solid body in dependence upon absorption of a fluid; of a solid body in dependence upon reaction with a fluid {, for detecting components in the fluid}
- G01N 33/2823: {Raw oil, drilling fluid or polyphasic mixtures}
- G01V 7/00: Measuring gravitational fields or waves; Gravimetric prospecting or detecting
- E21B 49/0875: {determining specific fluid parameters}
- G01N 2021/7773: {Reflection}
- G01N 2021/7783: {Transmission, loss}
- E21B: EARTH OR ROCK DRILLING; OBTAINING OIL, GAS, WATER, SOLUBLE OR MELTABLE MATERIALS OR A SLURRY OF MINERALS FROM WELLS
- G01V: GEOPHYSICS; GRAVITATIONAL MEASUREMENTS; DETECTING MASSES OR OBJECTS; TAGS (means for indicating the location of accidentally buried, e.g. snow-buried, persons A63B29/02)
- G01N: INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES (measuring or testing apparatus or processes other than immunoassay, involving enzymes or microorganisms C12M, C12Q)

## Abstract

The present application relates sensing reactive components in fluids by monitoring band gap changes to a material having interacted with the reactive components via physisorption and/or chemisorption. In some embodiments, the sensors of the present disclosure include the material as a reactive surface on a substrate. The band gap changes may be detected by measuring conductance changes and/or spectroscopic changes. In some instances, the sensing may occur downhole during one or more wellbore operations like drilling, hydraulic fracturing, and producing hydrocarbons.

## Claims

### Claim 1

A method for performing downhole measurements using a wellbore system, comprising:
measuring, in a downhole environment of a wellbore, at least one of a change of a bandgap and a rate of change of the bandgap of a reactive surface of a sensor of a wellbore system after the reactive surface of the sensor is contacted by a fluid having a reactive component, wherein the band structure of the reactive surface of the sensor is changed by the reactive component in the fluid; and
determining a concentration of the reactive component in the fluid based, at least in part, on the at least one of the change in the bandgap and the rate of change of the bandgap of the reactive surface.

### Claim 2 (depends on 1)

The method of claim 1, wherein the measuring comprises:
illuminating the reactive surface via light emitted by a light source;
detecting interacted light, wherein the interacted light is a product of reflection or transmission of the illuminating light and the reactive surface; and
determining the at least one of the change of the bandgap and the rate of change of the bandgap based, at least in part, on the interacted light.

### Claim 3 (depends on 2)

The method of claim 2, wherein the measuring further comprises:
determining at least one of intensity, wavelength, and frequency of the interacted light.

### Claim 4 (depends on 1)

The method of claim 1, further comprising:
measuring an electrical property of the reactive surface, wherein determining the concentration of the reactive component comprises determining the concentration of the reactive component based, at least in part, on the electrical property of the reactive surface.

### Claim 5 (depends on 4)

The method of claim 4, wherein measuring an electrical property of the reactive surface comprises measuring a conductance or a resistance of the reactive surface, and wherein determining the concentration of the reactive component based, at least in part, on the electrical property comprises determining the concentration of the reactive component based, at least in part, on the measured conductance or the measured resistance of the reactive surface.

### Claim 6 (depends on 1)

The method of claim 1, further comprising:
measuring at least one of a second change of a bandgap and a second rate of change of the bandgap of the reactive surface; and
determining a second concentration of the reactive component in the fluid based, at least in part, on the at least one of the second change in the bandgap and the second rate of change of the bandgap of the reactive surface.

### Claim 7 (depends on 6)

The method of claim 6, further comprising:
calculating, based on the determined concentration and the determined second concentration, at least one of a concentration of the reactive component over time and a cumulative amount of the reactive component; and
determining a parameter of wellbore operation based on the at least one of the concentration of the reactive component over time and a cumulative amount of the reactive component, wherein the parameter of wellbore operation comprises at least one of a wellbore tool lifetime, a wellbore tool replacement threshold, and a reactive component threshold.

### Claim 8 (depends on 1)

The method of claim 1, further comprising:
regenerating the reactive surface, wherein the regeneration comprises desorbing the reactive component from the reactive surface;
measuring at least one of a third change of a bandgap and a third rate of change of the bandgap of the reactive surface; and
determining a concentration of the reactive component in the fluid based, at least in part, on the at least one of the third change in the bandgap and the third rate of change of the bandgap.

### Claim 9 (depends on 8)

The method of claim 8, wherein desorbing the reactive component from the reactive surface comprises:
at least one of heating the reactive surface and supplying a purge fluid to the reactive surface.

### Claim 10 (depends on 1)

The method of claim 1, wherein determining a concentration of the reactive component in the fluid comprises determining a concentration of at least one of hydrogen sulfide, mercury, carbon dioxide, an acid, and a base.

### Claim 11 (depends on 1)

The method of claim 1, further comprising:
adjusting at least one parameter of a wellbore operation based on the determined concentration of the reactive component in the fluid.

### Claim 12 (depends on 1)

The method of claim 1, wherein the reactive surface comprises at least one of gold, nickel, copper, molybdenum, aluminum, tungsten, titanium, and a nonreactive matrix doped with particles reactive to the reactive component.

### Claim 13

An apparatus of a wellbore system deployed in a wellbore, comprising:
at least one detector;
at least one light source;
a substrate;
a reactive surface on the substrate;
a sensor;
a processor; and
a computer-readable medium having instructions stored thereon that are executable by the processor to cause the apparatus to,
determine at least one of a change of a bandgap and a rate of change of the bandgap of the reactive surface of the substrate of the apparatus of the wellbore system after the reactive surface is contacted by a fluid having a reactive component, wherein the band structure of the reactive surface is changed by the reactive component in the fluid, and
determine a concentration of the reactive component in the fluid based, at least in part, on the at least one of the change in the bandgap and the rate of change of the bandgap of the reactive surface.

### Claim 14 (depends on 13)

The apparatus of claim 13, wherein the sensor is fluidically coupled to a pump, and wherein the pump provides the fluid contacting the reactive surface.

### Claim 15 (depends on 13)

The apparatus of claim 13, wherein the reactive surface comprises at least one of gold, nickel, copper, molybdenum, aluminum, tungsten, titanium, and a nonreactive matrix doped with particles reactive to the reactive component of the fluid.

### Claim 16 (depends on 13)

The apparatus of claim 13, wherein the reactive surface varies in thickness.

### Claim 17 (depends on 13)

The apparatus of claim 13, wherein the reactive surface comprises particles arranged substantially in a monolayer on a substrate.

### Claim 18 (depends on 13)

The apparatus of claim 13, wherein the reactive surface comprises two or more types of particles and wherein each particle type is reactive to at least one reactive component of the fluid.

### Claim 19

An apparatus of a wellbore system, comprising:
a processor; and
a computer-readable medium having instructions stored thereon that are executable by the processor to cause the apparatus to,
measure, in a downhole environment of a wellbore, at least one of a change of a bandgap and a rate of change of the bandgap of a reactive surface of a sensor of the wellbore system after the reactive surface of the sensor is contacted by a fluid having a reactive component, wherein the band structure of the reactive surface of the sensor is changed by the reactive component in the fluid, and
determine a concentration of the reactive component in the fluid based, at least in part, on the at least one of the change in the bandgap and the rate of change of the bandgap of the reactive surface.

### Claim 20 (depends on 19)

The apparatus of claim 19,
wherein the instructions further compromise instructions to measure at an electrical property of the reactive surface based, at least in part, on electrical signals received from the reactive surface, and
wherein the instructions to determine the concentration of the reactive component further compromise instructions to determine the concentration of the reactive component based, at least in part, to measure the electrical property of the reactive surface.