# US 12,006,478 B2 · Contaminant removal with catalyst beds for LNG processing > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 12,006,478 B2 - Document ID: US12006478B2 - Status: Granted - Kind: B2 - Application number: 17/747,614 - Filed: 2022-05-18 - Published: 2022-11-24 - Granted: 2024-06-11 - Earliest claimed: 2021-05-18 - Assignees: ConocoPhillips Company - Applicants: ConocoPhillips Company - Inventors: Wesley R. Qualls; Christopher M. Widner; Peter N. Slater - Web page: https://patentgrep.com/patent/US12006478B2 ## CPC - C10G 25/05: Removal of non-hydrocarbon compounds, e.g. sulfur compounds - B01J 20/0285: {Sulfides of compounds other than those provided for in B01J20/045} - B01J 20/06: comprising oxides or hydroxides of metals not provided for in group B01J20/04 - B01J 20/324: {containing free carbon, e.g. activated carbon} - C10G 25/003: {Specific sorbent material, not covered by C10G25/02 or C10G25/03} - C10L 3/101: {Removal of contaminants} - B01J 2220/56: Use in the form of a bed - C10G 2300/1025: Natural gas - C10L 3/102: {of acid contaminants} - C10L 2290/10: Recycling of a stream within the process or apparatus to reuse elsewhere therein - C10L 2290/12: Regeneration of a solvent, catalyst, adsorbent or any other component used to treat or prepare a fuel - C10L 2290/541: Absorption of impurities during preparation or upgrading of a fuel - C10L 2290/542: Adsorption of impurities during preparation or upgrading of a fuel - C10L 2290/547: Filtration for separating fractions, components or impurities during preparation or upgrading of a fuel - C10G: CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION (cracking to hydrogen or synthesis gas C01B; cracking or pyrolysis of hydrocarbon gases to individual hydrocarbons or mixtures thereof of definite or specified constitution C07C; cracking to cokes C10B); RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES - B01J: CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS - C10L: FUELS NOT OTHERWISE PROVIDED FOR; NATURAL GAS; SYNTHETIC NATURAL GAS OBTAINED BY PROCESSES NOT COVERED BY SUBCLASSES C10G OR C10K; LIQUIFIED PETROLEUM GAS; USE OF ADDITIVES TO FUELS OR FIRES; FIRE-LIGHTERS ## Abstract Disclosed are systems and methods for processing liquefied natural gas (LNG). A LNG production system may include a contaminant removal process with one or more sets of sorbent beds co-loaded with a metal sulfide sorbent and/or metal oxide sorbent. In some examples, the contaminant removal process may include one or more molecular sieve dehydrators co-loaded with a 3A or 4A sieve and a 3A or 4A sieve impregnated with silver. The one or more sets of sorbent beds may be arranged at various locations throughout the LNG production system including upstream of or downstream of heavy component removal beds having activated carbon. In some instances, the LNG production system may include a regeneration process for moving heated fluid, typically feed gas, through a first heavy component removal bed while maintaining other heavy component removal beds online to reduce downtime for the LNG production system, increase production efficiency, and decrease an amount of greenhouse gases released from defrost and flare-offs. ## Claims ### Claim 1 A method for removing contaminants during liquid natural gas processing, the method comprising: introducing a natural gas feed into a first set of beds, the first set of beds co-loaded with a metal sulfide sorbent and a metal oxide sorbent; creating a partially filtered natural gas feed by removing first contaminants from the natural gas feed using the first set of beds; outputting the partially filtered natural gas feed to a second set of beds, the second set of beds disposed downstream from the first set of beds and loaded with activated carbon; creating a filtered natural gas feed by removing second contaminants from the partially filtered natural gas feed using the second set of beds; and outputting the filtered natural gas feed to one or more of a natural gas liquid stabilizer, a liquefaction cooler, and a regeneration gas heater. ### Claim 2 (depends on 1) The method of claim 1, wherein the first contaminants are mercury or mercury compounds and are adsorbed by the metal sulfide sorbent. ### Claim 3 (depends on 1) The method of claim 1, wherein the first contaminants are arsenic or arsenic compounds and are adsorbed by the metal oxide sorbent. ### Claim 4 (depends on 1) The method of claim 1, wherein the second contaminants are adsorbed by the activated carbon. ### Claim 5 (depends on 1) The method of claim 1, wherein the first set of beds are upstream from one or more molecular sieve dehydrators and the second set of beds are downstream from the one or more molecular sieve dehydrators. ### Claim 6 (depends on 1) The method of any of claim 1, wherein the first set of beds are non-regenerable sorbent beds. ### Claim 7 (depends on 1) The method of claim 1, wherein the second set of beds are regenerable and configured to stay online for liquid natural gas processing. ### Claim 8 (depends on 1) The method of claim 1, further comprising: receiving, from the first set of beds, the partially filtered natural gas feed at a heat exchanger; and directing a temperature controlled partially filtered natural gas feed from the heat exchanger and to the second set of beds. ### Claim 9 (depends on 1) The method of claim 1, further comprising: receiving, from the first set of beds, the partially filtered natural gas feed at one or more molecular sieve dehydrators; and directing a dehydrated partially filtered natural gas feed from the one or more molecular sieve dehydrators to the second set of beds. ### Claim 10 (depends on 1) The method of claim 1, further comprising: co-loading one or more molecular sieve dehydrators with a 3A or 4A molecular sieve and a 3A sieve impregnated with silver; arranging the one or more molecular sieve dehydrators upstream from the first set of beds; filtering using, the one or more molecular sieve dehydrators, the partially filtered natural gas feed to create a dehydrated and partially filtered natural gas feed; and directing the dehydrated and partially filtered natural gas feed to the second set of beds. ### Claim 11 (depends on 1) The method of claim 1, further comprising co-loading the activated carbon in the first set of beds. ### Claim 12 (depends on 11) The method of claim 11, wherein the first set of beds comprises a first set of sorbent beds and a second set of sorbent beds, the method further comprising; co-loading the second set of sorbent beds with the metal sulfide sorbent, the metal oxide sorbent, and the activated carbon; and arranging the second set of sorbent beds downstream from the first set of sorbent beds. ### Claim 13 A system for removing contaminants during liquid natural gas processing, the system comprising: a first set of beds configured to be co-loaded with a metal sulfide sorbent and a metal oxide sorbent, the metal sulfide sorbent and a metal oxide sorbent filtering first contaminants from a natural gas feed; and a second set of beds configured to be loaded with activated carbon, the activated carbon filtering second contaminants from the natural gas feed, a filtered natural gas feed created by the filtering of the first contaminants and the second contaminants from the natural gas feed, the filtered natural gas feed configured to be outputted from the second set of beds to one or more of a natural gas liquid stabilizer, a liquefaction cooler, and a regeneration gas heater. ### Claim 14 (depends on 13) The system of claim 13, wherein the second set of beds is downstream from the first set of beds. ### Claim 15 (depends on 13) The system of claim 13, further comprising at least one of: a vapor liquid separator for providing the natural gas feed to the first set of beds; an acid gas removal absorber for providing the natural gas feed to the first set of beds; a feed gas exchanger for providing the natural gas feed to the first set of beds; or one or more molecular sieve dehydrators for providing the natural gas feed to the first set of beds. ### Claim 16 (depends on 13) The system of claim 13, wherein the natural gas feed comprises an overhead vapor portion provided from a vapor liquid separator to the first set of beds. ### Claim 17 (depends on 13) The system of claim 13, wherein the second set of beds includes a first compound removal bed loaded with the activated carbon. ### Claim 18 (depends on 17) The system of claim 17, wherein the second set of beds includes a second compound removal bed loaded with the activated carbon arranged in parallel with the first compound removal bed; wherein the system further comprises: one or more valves arranged to isolate the first compound removal bed from the natural gas feed while maintaining a flow of the natural gas feed through the second compound removal bed; and one or more of a trim heater, a cooler, and a temperature-controlled heat exchanger arranged to cause heated gas to pass through the first compound removal bed when the first compound removal bed is isolated from the filtered natural gas feed.