# US 12,006,214 B2 · Integration of a hot oxygen burner with an auto thermal reformer

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- Number: US 12,006,214 B2
- Document ID: US12006214B2
- Status: Granted
- Kind: B2
- Application number: 17/211,148
- Filed: 2021-03-24
- Published: 2021-07-08
- Granted: 2024-06-11
- Earliest claimed: 2018-02-26
- Assignees: Praxair Technology, Inc.
- Applicants: Minish Mahendra Shah; Lawrence Bool
- Inventors: Minish Mahendra Shah; Lawrence Bool
- Web page: https://patentgrep.com/patent/US12006214B2

## CPC

- C01B 3/363: characterised by the burner
- C01B 3/382: Processes with two or more reaction steps, of which at least one is catalytic, e.g. steam reforming and partial oxidation
- C01B 2203/0211: containing a non-catalytic reforming step
- C01B 2203/0216: containing a non-catalytic steam reforming step
- C01B 2203/0244: the reforming step being an autothermal reforming step, e.g. secondary reforming processes
- C01B 2203/0811: by combustion of fuel
- C01B 2203/0827: at least part of the fuel being a recycle stream
- C01B 2203/1241: Natural gas or methane
- Y02P 20/129: Energy recovery, e.g. by cogeneration, H2recovery or pressure recovery turbines
- C01B: NON-METALLIC ELEMENTS; COMPOUNDS THEREOF; {METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C}
- Y02P: CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS

## Abstract

The present invention relates to integrating a hot oxygen burner with an auto thermal reformer of reducing in a system for generating synthesis gas.

## Claims

### Claim 1

A method for generating syngas in a thermal reactor, comprising:
introducing a first stream of fuel and oxygen in a hot oxygen burner to combust said fuel and generate a hot oxygen jet having a burner stoichiometric ratio (SR) value between 3 and 6 wherein the hot oxygen burner is integrated with the auto thermal reactor;
introducing a first hydrocarbon stream within a non-catalytic zone of the auto thermal reactor, wherein the first hydrocarbon stream is substantially entrained in the hot oxygen jet; reacting the first hydrocarbon stream with the hot oxygen jet, performing partial reforming of the hydrocarbon in the non-catalytic zone of the auto thermal reactor, and completing the reforming in a catalytic reaction zone of the auto thermal reactor, thereby forming a syngas which exits the reactor at a temperature below 2000° F. and with minimal soot formation.

### Claim 2 (depends on 1)

The method of claim 1, wherein a first stream of fuel stream as an opportunity fuel.

### Claim 3 (depends on 1)

The method of claim 1, further comprising:
routing a second stream of hydrocarbon to upstream of the catalytic reaction zone of the auto thermal reactor.
