# US 12,005,659 B2 · Method for manufacturing a coated lens > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 12,005,659 B2 - Document ID: US12005659B2 - Status: Granted - Kind: B2 - Application number: 18/145,182 - Filed: 2022-12-22 - Published: 2023-04-27 - Granted: 2024-06-11 - Earliest claimed: 2020-06-26 - Assignees: Carl Zeiss Vision International GmbH - Applicants: Carl Zeiss Vision International GmbH - Inventors: Waiz Karim; Andreu Llobera Adan; Emad Flear Aziz; Norbert Hugenberg - Web page: https://patentgrep.com/patent/US12005659B2 ## CPC - B29D 11/00009: {Production of simple or compound lenses} - B29D 11/00865: {Applying coatings; tinting; colouring (printing, marking or copying processes B41M; identification in general G09F3/00; producing decorative effects in general B44C; positioning or marking of lenses B24B13/0055)} - B29D 11/00442: {Curing the lens material} - G02B 1/14: Protective coatings, e.g. hard coatings - G02B 3/0012: {characterised by the manufacturing method} - B29D: PRODUCING PARTICULAR ARTICLES FROM PLASTICS OR FROM SUBSTANCES IN A PLASTIC STATE (making granules B29B9/00; making preforms B29B11/00) - G02B: OPTICAL ELEMENTS, SYSTEMS OR APPARATUS ## Abstract A method for manufacturing a coated lens by applying at least one single electromagnetic pulse to convert a coating precursor material into at least one coating. The electromagnetic pulse is delivered to the coating precursor material applied on a surface of an uncoated or precoated optical lens substrate. The at least one single electromagnetic pulse is applied from an electromagnetic source such as a flash lamp, a halogen lamp, a directed plasma arc, a laser, a microwave generator, an induction heater, an electron beam, a stroboscope, or a mercury lamp. ## Claims ### Claim 1 A method for manufacturing of a coated lens, the method comprising at least the steps of: applying at least one coating precursor material to at least one surface of an uncoated or precoated optical lens substrate; and applying at least one single electromagnetic pulse to an optical lens substrate having the at least one coating precursor material to dry and to harden and/or to sinter and/or to cure the at least one coating precursor material for converting the at least one coating precursor material into at least one coating, wherein within a range for a total process duration needed for drying and hardening and/or sintering and/or curing the at least one coating precursor material selected from the group of ranges consisting of: from 100 us to 10 min, from 300 us to 7 min, from 500 us to 5 min, from 1 ms to 3 min, at least one mechanical property and/or at least one optical property and/or at least one functional property of the coated lens is adjusted to meet a given requirement for at least one of the properties or to obtain a specific target value for at least one of the properties, wherein the given requirement for the at least one of the properties is met or the specific target value for the at least one of the properties is obtained during the total process duration needed for drying and hardening and/or sintering and/or curing the at least one coating precursor material. ### Claim 2 (depends on 1) The method according to claim 1, wherein the at least one mechanical property of the coated lens is adjusted by selecting between different target values for the mechanical property, and/or the at least one optical property of the coated lens is adjusted by selecting between different target values for the optical property, and/or the at least one functional property of the coated lens is adjusted by selecting between different target values for the functional property. ### Claim 3 (depends on 1) The method according to claim 1, wherein the mechanical property is selected from the group consisting of indentation hardness, scratch resistance, adhesion, delamination, crazing and water uptake of the optical lens substrate, wherein the optical property is selected from the group consisting of transmittance, absorbance and reflectance, preferably, from wavelengths ranging from 300 nm to 780 nm, clarity, and yellowing, wherein the functional property is selected from the group consisting of control of the surface wetting, the photochromic performance, the surface cleanability, tint absorption or uptake, the surface tension and the chemical composition, each of the coated lens. ### Claim 4 (depends on 1) The method according to claim 1, wherein the selection of the target value is performed by changing at least one process parameter within a recipe or by changing a combination of process parameters within a recipe. ### Claim 5 (depends on 1) The method according to claim 1, wherein the at least one coating precursor material is at least one selected from the group consisting of at least one primer coating precursor material, at least one hard coating precursor material and at least one photochromic coating precursor material. ### Claim 6 (depends on 1) The method according to claim 1, wherein the at least one coating precursor material does not comprise a photoinitiator. ### Claim 7 (depends on 1) The method according to claim 1, wherein the at least one hard coating precursor material comprises A) a) at least one silane derivative of the formula (III) R1R23-nSi(OR3)n, wherein R1 comprises an alkyl group, a cyclo alkyl group, an acyl group, an aryl group or an hetero aryl group, each of which may be substituted, R2 is an organic rest comprising an epoxide group, R=3 comprises an alkyl group, a cyclo alkyl group, an aryl group or a hetero aryl group, each of which may be substituted, n=2 or 3, and/or b) at least one hydrolysis product of the silane derivative of the formula (III), and/or c) at least one condensation product of the silane derivative of the formula (III), and/or d) any mixture of components a) to c); B) at least one colloidal inorganic oxide, hydroxide, oxide hydrate, fluoride and/or oxyfluoride; C) at least one epoxy component comprising at least two epoxy groups; and D) at least one catalyst system comprising at least one Lewis acid and at least one thermolatent Lewis base-adduct. ### Claim 8 (depends on 1) The method according to claim 1, wherein the at least one primer coating precursor material comprises i) at least one aqueous aliphatic, cycloaliphatic, aromatic or heteroaromatic polyurethane dispersion, at least one aqueous aliphatic, cycloaliphatic, aromatic or heteroaromatic polyurea dispersion, at least one aqueous aliphatic, cycloaliphatic, aromatic or heteroaromatic polyurethane-polyurea dispersion, at least one aqueous aliphatic, cycloaliphatic, aromatic or heteroaromatic polyester dispersion, ii) at least one solvent, and iii) optionally, at least one additive. ### Claim 9 (depends on 8) The method according to claim 8, wherein the at least one primer coating precursor material comprises the at least one aqueous aliphatic polyurethane dispersion or the at least one aqueous aliphatic polyester dispersion. ### Claim 10 (depends on 8) The method according to claim 8, wherein the at least one primer coating precursor material comprises the at least one aqueous aliphatic polyurethane dispersion. ### Claim 11 A method for manufacturing of a coated lens, the method comprising at least the steps of applying at least one coating precursor material to at least one surface of an uncoated or precoated optical lens substrate, drying and hardening and/or sintering and/or curing the at least one coating precursor material by applying at least one single electromagnetic pulse to an optical lens substrate having the coating precursor material to convert the at least one coating precursor material into at least one coating, wherein at least one mechanical property and/or at least one optical property and/or at least one functional property each of the coated lens is adjusted based on a recipe used for the conversion of the at least one coating precursor material into at least one coating, the recipe being a selection of a plurality of process parameters which are simultaneously or sequentially used to meet a requirement or to obtain a target value of exact one mechanical property and/or exact one optical property and/or exact one functional property. ### Claim 12 (depends on 11) The method according to claim 11, wherein the process parameters are selected of at least one from the group consisting of the wavelength of light used, the number of single electromagnetic pulses in an electromagnetic pulse train, the peak intensity of the at least one single electromagnetic pulse, the total process duration, the total dose delivered by the at least one single electromagnetic pulse, the number of micro-pulses within a one single electromagnetic pulse, the average duty cycle, the duration of the envelope, and the total number of repetitions of the at least one single electromagnetic pulse. ### Claim 13 (depends on 12) The method according to claim 12, wherein changing the process parameters within a recipe, or changing the combination of process parameters within a recipe, or changing at least one process parameter within a recipe each result in a variation of the target value of the mechanical property, and/or the target value of the optical property, and/or the target value of the functional property. ### Claim 14 A method for manufacturing a coated lens, the coated lens comprising an uncoated or precoated optical lens substrate and at least one coating, the method comprising the following steps: a) providing at least one uncoated or precoated optical lens substrate having a front surface and a back surface, the optical lens substrate having a first transmittance within a wavelength range A, b) applying at least one coating precursor material to at least one of the surfaces of the uncoated or precoated optical lens substrate, the coating precursor material having a second transmittance within a wavelength range B, c) applying at least one single electromagnetic pulse to the at least one surface of the uncoated or precoated optical lens substrate having the at least one coating precursor material resulting in the coated lens, the single electromagnetic pulse having a wavelength range C, wherein the wavelength range B of the second transmittance encompasses the wavelength range A of the first transmittance, the wavelength range C of the single electromagnetic pulse encompasses the wavelength range A of the first transmittance and the wavelength range B of the second transmittance, in the wavelength range A, the single electromagnetic pulse passes through the optical lens substrate and the coating precursor material, in the wavelength range B, the single electromagnetic pulse passes through the coating precursor material, in the wavelength range C not encompassing the wavelength range A, the part of the single electromagnetic pulse of the remaining wavelength C is at least partially absorbed by the optical lens substrate. ### Claim 15 (depends on 14) The method according to claim 14, wherein the at least one optical lens substrate is selected from the group consisting of a plano clear optical lens substrate or a corrective clear optical lens substrate, each having a transmittance of at least 70% in the wavelength range A of from 200 nm to 1100 nm; or a plano tinted optical lens substrate or a corrective tinted optical lens substrate, each having a transmittance in a range of from 10% to 90% in the wavelength range A of from 200 nm to 1100 nm. ### Claim 16 (depends on 14) The method according to claim 14, wherein the at least one coating precursor material has a transmittance of at least 75% in the wavelength range B of from 100 nm to 1100 nm. ### Claim 17 (depends on 14) The method according to claim 14, wherein the at least one single electromagnetic pulse has a wavelength ranging from 100 nm to 1100 nm. ### Claim 18 (depends on 14) The method according to claim 14, wherein in step c) the at least one single electromagnetic pulse is applied for a total process duration of a range of from 50 μs to 3 min. ### Claim 19 (depends on 14) The method according to claim 14, wherein in step c) the at least one single electromagnetic pulse is applied according to a recipe comprising at least one process parameter selected from the group consisting of the wavelength of each single electromagnetic pulse, the total dose delivered by at least one single electromagnetic pulse, the number of micro-pulses within a one single electromagnetic pulse, the average duty cycle, and the total number of repetitions of the at least one single electromagnetic pulse. ### Claim 20 (depends on 14) The method according to claim 14, wherein the resulting coated lens exhibits at least one mechanical property and/or at least one optical property and/or at least one functional property, each property having at least one target value. ### Claim 21 (depends on 20) The method according to claim 20, wherein the at least one target value is adjustable by changing at least one of the process parameters of the recipe. ### Claim 22 (depends on 20) The method according to claim 20, wherein the at least one target value for at least one mechanical property and/or for the at least one optical property and/or for the at least one functional property, each of the coated lens is adjustable in a range from 1% to 1000%, based on a given target value. ### Claim 23 (depends on 20) The method according to claim 20, wherein the at least one target value for at least one mechanical property and/or at least one optical property and/or at least one functional property of the coated lens is higher or lower in a range from 1 time to 275 times as compared to the highest or lowest achievable target value for the respective property of a coated lens obtained by applying heat below the threshold temperature of the uncoated or precoated optical lens substrate. ### Claim 24 (depends on 14) The method according to claim 14, the coated lens comprising an uncoated or precoated optical lens substrate and at least one coating, the method comprising the following steps: a) providing at least one uncoated or precoated optical lens substrate having a front surface and a back surface, the optical lens substrate having a transparency in a wavelength range of from 400 nm to 800 nm, b) applying at least one coating precursor material to at least one of the surfaces of the uncoated or precoated optical lens substrate, the coating precursor material having a transparency in a wavelength range of from 100 nm to 1100 nm, c) irradiating the at least one surface of the uncoated or precoated optical lens substrate having the at least one coating precursor material with at least one single electromagnetic pulse for a total process duration resulting in the coated lens, the single electromagnetic pulse having a wavelength range of 100 nm to 1100 nm, wherein the total process duration is in a range of from 50 μs to 20 min, in a wavelength range of from 400 nm to 800 nm, the at least one single electromagnetic pulse passes through the optical lens substrate with minimal or no absorption and through the coating precursor material with minimal or no absorption, in a wavelength range of from 100 nm to <400 nm and in a wavelength range of from >800 nm to 1100 nm, the single electromagnetic pulse is absorbed by the optical lens substrate with a transmittance of <80% and passes through the coating precursor material. ### Claim 25 (depends on 24) The method according to claim 24, wherein the total process duration is in a range of from 100 μs to 3 min.