# US 12,005,522 B2 · Continuous laser nanoforming device > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 12,005,522 B2 - Document ID: US12005522B2 - Status: Granted - Kind: B2 - Application number: 16/810,084 - Filed: 2020-03-05 - Published: 2020-09-24 - Granted: 2024-06-11 - Earliest claimed: 2019-03-18 - Assignees: Purdue Research Foundation - Applicants: Purdue Research Foundation - Inventors: Ramses Valentin Martinez; Debkalpa Goswami - Web page: https://patentgrep.com/patent/US12005522B2 ## CPC - B23K 26/356: by shock processing - B23K 26/08: Devices involving relative movement between laser beam and workpiece - C21D 10/005: {by laser shock processing} - B23K 2103/14: Titanium or alloys thereof - B23K 2103/42: {Plastics other than composite materials} - B23K 2103/52: {Ceramics} - B23K 2103/54: {Glass} - B23K: SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM - C21D: MODIFYING THE PHYSICAL STRUCTURE OF FERROUS METALS; GENERAL DEVICES FOR HEAT TREATMENT OF FERROUS OR NON-FERROUS METALS OR ALLOYS; MAKING METAL MALLEABLE, e.g. BY DECARBURISATION OR TEMPERING (surface treatment of metallic material involving at least one process provided for in class C23 and at least one process covered by this subclass C23F17/00; unidirectional solidification of eutectic materials or unidirectional demixing of eutectoid materials C30B) ## Abstract The present disclosure relates to a novel continuous laser nanoforming device, and the methods to make and use the continuous laser nanoforming device. ## Claims ### Claim 1 A continuous laser nanoforming device, comprising: a nanomold configured to continuously receive and transport a metallic film, wherein the metallic film includes a metal layer and an ablative layer; a laser generator configured to generate a laser beam to hit the ablative layer of the metallic film to generate a shockwave and thereby create a nanoformed metal from the metallic film as the metallic film moves relative to the laser generator; and a confinement layer configured to confine the shockwave during continuous motion of the metallic film relative to the confinement layer and the laser generator, wherein the confinement layer is configured to contact the ablative layer to press the metallic film against the nanomold while the metallic film moves relative to the confinement layer and the laser generator such that the confinement layer is disposed between the laser generator and the metallic film, and the laser beam is transferred through the confinement layer toward the ablative layer of the metallic film. ### Claim 2 (depends on 1) The continuous laser nanoforming device of claim 1, wherein the laser generator is a carbon dioxide (CO2) laser, a continuous laser, a pulsed laser, or a fiber laser operating in the visible or infrared spectrum. ### Claim 3 (depends on 1) The continuous laser nanoforming device of claim 1, wherein the laser generator is a carbon dioxide (CO2) laser generator. ### Claim 4 (depends on 1) The continuous laser nanoforming device of claim 1, wherein the confinement layer includes silicate glass, soda-lime glass, CaF2, ZnSe, or any other solid or liquid media transparent at wavelength of emission defined by the laser beam. ### Claim 5 (depends on 1) The continuous laser nanoforming device of claim 1, further including a rotary film feeder configured to transfer the metallic film to the nanomold. ### Claim 6 (depends on 1) The continuous laser nanoforming device of claim 1, further including a roll-to-roll system to transfer the nanoformed metal to a rigid, flexible, or stretchable substrate. ### Claim 7 (depends on 1) The continuous laser nanoforming device of claim 1, further including a roll-to-roll system to adhere the nanoformed metal to a rigid, flexible, or stretchable substrate. ### Claim 8 (depends on 1) The continuous laser nanoforming device of claim 1, wherein the nanomold is a thin nanopatterned metal, polymer, ceramic, glass, or any combination thereof. ### Claim 9 (depends on 1) The continuous laser nanoforming device of claim 1, wherein the nanomold is a metal-coated polymeric nanomold. ### Claim 10 (depends on 1) The continuous laser nanoforming device of claim 1, wherein the nanomold is a titanium-coated epoxy-based nanomold. ### Claim 11 (depends on 1) The continuous laser nanoforming device of claim 1, wherein the nanomold is coupled with one or more rollers, wherein the nanomold is configured to maintain continuous contact with the metallic film. ### Claim 12 (depends on 5) The continuous laser nanoforming device of claim 5, wherein the rotary film feeder includes one or a plurality of rollers. ### Claim 13 (depends on 1) The continuous laser nanoforming device of claim 1, wherein the ablative layer includes graphite. ### Claim 14 (depends on 1) The continuous laser nanoforming device of claim 1, further comprising a back support positioned adjacent to the confinement layer, wherein the nanomold and metallic film are configured to translate between the confinement layer and the back support, wherein the confinement layer is configured to press the metallic film and the nanomold against the back support as the metallic film and nanomold translate relative to the confinement layer and the back support. ### Claim 15 (depends on 1) The continuous laser nanoforming device of claim 1, wherein the confinement layer is movable relative to the metallic layer via linear actuation. ### Claim 16 A laser nanoforming device, comprising: a nanomold configured to continuously receive and transport a multilayer film, wherein the multilayer film includes a metal layer and an ablative layer; a first laser generator configured to direct a first laser beam onto the ablative layer of the multilayer film as the multilayer film moves relative to the first laser generator to produce a nanoformed material when the first laser beam generates a shockwave at a surface of the multilayer film; a confinement material disposed between the first laser generator and the multilayer film, wherein the confinement material is configured to press the multilayer film against the nanomold while the first laser beam is transferred through the confinement material toward the ablative layer such that the confinement material is configured to confine at least a portion of the shockwave during continuous motion of the multilayer film relative to the confinement material and the first laser generator; a rotary film feeder configured to join the nanoformed material with a substrate material; and a second laser generator configured to weld the nanoformed material to the substrate material. ### Claim 17 A laser nanoforming device, comprising: a rotary nanomold configured to continuously receive and transport a multilayer film, wherein the multilayer film includes a metal layer and an ablative layer; a laser generator configured to direct a laser beam onto the ablative layer of the multilayer film as the multilayer film moves relative to the laser generator to generate a shockwave and thereby produce a nanoformed material; a transparent confinement material disposed between the laser generator and the multilayer film, wherein the transparent confinement material is configured to transfer the laser beam therethrough toward the ablative layer during continuous motion of the multilayer film relative to the transparent confinement material and the laser generator; and a back support positioned adjacent to the transparent confinement material; wherein the rotary nanomold and multilayer film are configured to translate between the transparent confinement material and the back support, and wherein the transparent confinement material is configured to press the multilayer film and the rotary nanomold against the back support as the layer multilayer film and rotary nanomold translate relative to the transparent confinement material and the back support. ### Claim 18 (depends on 17) The laser nanoforming device of claim 17, wherein the transparent confinement material includes silicate glass, soda-lime glass, CaF2, ZnSe. ### Claim 19 (depends on 17) The laser nanoforming device of claim 17, further including a rotary film feeder configured to transfer the multilayer film to the rotary nanomold. ### Claim 20 (depends on 17) The laser nanoforming device of claim 17, wherein the ablative layer includes graphite.