# US 12,004,508 B2 · Concentrated low viscosity agricultural formulations

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- Number: US 12,004,508 B2
- Document ID: US12004508B2
- Status: Granted
- Kind: B2
- Application number: 15/761,946
- Filed: 2017-02-22
- Published: 2018-12-20
- Granted: 2024-06-11
- Earliest claimed: 2016-03-08
- Assignees: Indorma Ventures Oxides LLC
- Applicants: Indorama Ventures Oxides LLC
- Inventors: Alan J. Stern; Matthew T. Meredith; Zhidong Wang; Rowan Brown
- Web page: https://patentgrep.com/patent/US12004508B2

## CPC

- A01N 25/04: Dispersions, {emulsions, suspoemulsions, suspension concentrates} or gels (foams A01N25/16)
- A01N 25/30: characterised by the surfactants
- A01N 37/22: the nitrogen atom being directly attached to an aromatic ring system, e.g. anilides
- A01N 43/707: 1,2,3- or 1,2,4-triazines; Hydrogenated 1,2,3- or 1,2,4-triazines
- C08G 81/021: {Block or graft polymers containing only sequences of polymers of C08C or C08F}
- C08G 81/025: {containing polyether sequences}
- C08L 79/02: Polyamines
- C09B 67/009: {polymeric dispersing agent}
- C09D 11/03: characterised by features other than the chemical nature of the binder
- C08L 2201/56: Non-aqueous solutions or dispersions
- A01N: PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF (preservation of food or foodstuff A23); BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES (preparations for medical, dental or toiletry purposes which kill or prevent the growth or proliferation of unwanted organisms A61K); PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- C08G: MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08L: COMPOSITIONS OF MACROMOLECULAR COMPOUNDS (compositions based on polymerisable monomers C08F, C08G; artificial filaments or fibres D01F; textile treating compositions D06)
- C09B: ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES {, e.g. PIGMENTS}; MORDANTS; LAKES (fermentation or enzyme using processes to synthesise a desired chemical compound C12P)
- C09D: COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR (cosmetics A61K; processes for applying liquids or other fluent materials to surfaces, in general, B05D; staining wood B27K5/02; glazes or vitreous enamels C03C; natural resins, French polish, drying-oils, driers, turpentine, per se, C09F; polishing compositions other than French polish, ski waxes C09G; adhesives or use of materials as adhesives C09J; materials for sealing or packing joints or covers C09K3/10; materials for stopping leaks C09K3/12; processes for the electrolytic or electrophoretic production of coatings C25D)

## Abstract

The present disclosure provides a dispersant obtained from the reaction of a styrene maleic anhydride and a polyether monoamine. The dispersant may be combined with a pesticide and water to form an aqueous agricultural composition.

## Claims

### Claim 1

A non-aqueous dispersant obtained from the reaction of a styrene maleic anhydride copolymer having a styrene to maleic anhydride molar ratio of between 6.0:1.0 to 8.0:1.0 and a polyether monoamine represented by the formula
wherein R1 is a hydrocarbyl group, X1, X2, X3, are hydrogen, X4 is methyl, X5, and X6 in each occurrence are independently selected from the group consisting of: hydrogen, methyl and ethyl, p is 19, q is 3, and r is any integer between zero and about 100, including zero, and, s is either 0 or 1 and the polyether monoamine has a molar ratio of EO to PO greater than or equal to 58/8 and is water soluble and wherein the dispersant has a total solids content, in percent of less than about 60 and more than about 45.

### Claim 2 (depends on 1)

The non-aqueous dispersant of claim 1, wherein the polyether monoamine has a molecular weight between about 600 to about 3000.

### Claim 3 (depends on 1)

An aqueous agricultural composition comprising the non-aqueous dispersant of claim 1 and a pesticide.

### Claim 4 (depends on 3)

The aqueous agricultural composition of claim 3, wherein the non-aqueous dispersant is present in an amount from about 1%-5.5% by weight, based on the total weight of the aqueous agricultural composition.

### Claim 5 (depends on 3)

The aqueous agricultural composition of claim 3, wherein the pesticide is present in an amount of up to about 70% by weight, based on the total weight of the aqueous agricultural composition.

### Claim 6 (depends on 1)

A method for killing or inhibiting or repelling a pest comprising the steps of providing a pesticide in a pesticidally effective amount, providing an effective amount of the dispersant of claim 1, combining the pesticide with the dispersant and water to prepare an aqueous agrochemical formulation, and contacting the aqueous agrochemical formulation and the pest, wherein the effective amount of the dispersant is at least about 0.1% by weight based on the total weight of the aqueous agrochemical formulation.

### Claim 7 (depends on 1)

A pigment, ink or dye formulation comprising the non-aqueous dispersant of claim 1.

### Claim 8 (depends on 1)

A method for reducing Ostwald Ripening of an aqueous agricultural composition comprising adding the dispersant of claim 1 to the aqueous agricultural composition wherein the aqueous agricultural composition comprises a pesticidally effective amount of a pesticide.
