# US 12,002,968 B2 · Method of manufacturing catalyst slurry for fuel cells and method of manufacturing electrode for fuel cells using the same

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- Number: US 12,002,968 B2
- Document ID: US12002968B2
- Status: Granted
- Kind: B2
- Application number: 16/901,479
- Filed: 2020-06-15
- Published: 2021-06-10
- Granted: 2024-06-04
- Earliest claimed: 2019-12-10
- Assignees: Hyundai Motor Company; Kia Motors Corporation
- Applicants: Hyundai Motor Company; Kia Motors Corporation
- Inventors: Yoon Hwan Cho; Kook Il Han; Su Won Seol
- Web page: https://patentgrep.com/patent/US12002968B2

## CPC

- H01M 4/926: {on carbon or graphite}
- H01M 4/8647: {consisting of more than one material, e.g. consisting of composites}
- H01M 4/8668: {Binders}
- H01M 4/8814: {Temporary supports, e.g. decal}
- H01M 4/8828: {Coating with slurry or ink}
- H01M 4/8882: {Heat treatment, e.g. drying, baking}
- H01M 4/9041: {Metals or alloys (H01M4/92 takes precedence)}
- H01M 4/9083: {on carbon or graphite}
- H01M 4/921: {Alloys or mixtures with metallic elements}
- H01M 4/8835: {Screen printing}
- Y02E 60/50: Fuel cells
- H01M: PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

## Abstract

The present disclosure relates to a method of manufacturing catalyst slurry for fuel cells capable of greatly improving efficiency in use of catalyst metal and a method of manufacturing an electrode for fuel cells using the catalyst slurry manufactured using the method. Specifically, the method of manufacturing catalyst slurry for fuel cells includes preparing a catalyst including a porous carrier and catalyst metal, introducing the catalyst, a solvent, and an ionomer into a chamber, and infiltrating the ionomer into pores of the carrier.

## Claims

### Claim 1

A method of manufacturing catalyst slurry for fuel cells, the method comprising:
preparing a catalyst comprising a porous carrier and catalyst metal;
introducing the catalyst, a solvent, and an ionomer into a chamber; and
infiltrating the ionomer into pores of the carrier;
wherein the carrier comprises pores depressed inward from an outer surface of the carrier, the pores comprising a plurality of pore inlets each having an average diameter of 5 nm to 30 nm;
wherein the ionomer comprises a polymer having a radius of gyration of a polymer chain of 5 nm or less;
wherein the infiltrating of the ionomer into pores of the carrier comprises stirring contents of the chamber while applying heat and pressure thereto;
wherein a temperature of the contents of the chamber is increased to 25° C. to 80° C.; and
wherein the pressure applied to the contents of the chamber is 2 bar to 200 bar.

### Claim 2 (depends on 1)

The method according to claim 1, wherein the carrier comprises one selected from a group consisting of graphite, active carbon, carbon black, carbon nanotube, carbon nanofiber, carbon nanowire, and a combination thereof.

### Claim 3 (depends on 1)

The method according to claim 1, wherein the catalyst metal comprises:
platinum (Pt); or
at least one or an alloy of two or more selected from a group of platinum (Pt), iridium (Ir), ruthenium (Ru), palladium (Pd), nickel (Ni), cobalt (Co), and yttrium (Y).

### Claim 4 (depends on 1)

The method according to claim 1, wherein the catalyst is introduced into the chamber, negative pressure is applied to the chamber, and the solvent and the ionomer are introduced into the chamber together with inert gas.

### Claim 5 (depends on 1)

The method according to claim 1, wherein the solvent comprises one selected from a group consisting of distilled water, ethanol, propanol, butanol, ethylene glycol, and a combination thereof.

### Claim 6 (depends on 1)

The method according to claim 1, wherein the ionomer comprises:
a fluorine-based resin comprising a single polymer, a cross-linking polymer, a graft polymer, a copolymer, or a blend of one or more selected from a group consisting of perfluorosulfonic acid and perfluorocarboxylic acid;
a non-fluorine-based resin comprising a single polymer, a cross-linking polymer, a graft polymer, a copolymer, or a blend of one or more selected from a group consisting of polyarylene ether, polyether ketone, polyether ether ketone, polyether sulfone, polyether ether sulfone, polyazole, polyvinyl alcohol, polyphenylene oxide, polyphenylene sulfide, polysulfone, polycarbonate, polystyrene, polyimide, polyamide, polyquinoxaline, and polybenzimidazole; and
a combination thereof.

### Claim 7 (depends on 1)

The method according to claim 1, wherein inert gas is introduced into the chamber in order to apply the pressure to the contents of the chamber.

### Claim 8 (depends on 1)

The method according to claim 1, wherein the contents of the chamber are stirred for 24 hours to 48 hours.

### Claim 9 (depends on 1)

The method according to claim 1, wherein the catalyst metal is coupled to an outer surface of the carrier and to an inner surface of each of the pores, and
the ionomer is infiltrated into the pores of the carrier and contacts catalyst metal coupled to the inner surface of each of the pores of the carrier.

### Claim 10 (depends on 1)

A method of manufacturing an electrode for fuel cells comprising coating the catalyst slurry manufactured using the method according to claim 1 on a substrate to manufacture the electrode.

### Claim 11 (depends on 10)

The method according to claim 10, wherein the substrate is release paper comprising one selected from a group consisting of polyethylene naphthalate (PEN), polyethylene terephthalate (PET), polytetrafluoroethylene (PTFE), and a combination thereof.

### Claim 12 (depends on 10)

The method according to claim 10, wherein the catalyst slurry is coated using a screen printing method, a spray coating method, a coating method using a doctor blade, a gravure coating method, a deep coating method, a silk screen method, a painting method, or a coating method using a slot die.

### Claim 13 (depends on 10)

The method according to claim 10, further comprising drying the electrode at 100° C. to 200° C. for 5 minutes to 24 hours.