# US 12,002,962 B2 · Electrode for electrochemical device comprising dry electrode film and method for manufacturing the same

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- Number: US 12,002,962 B2
- Document ID: US12002962B2
- Status: Granted
- Kind: B2
- Application number: 17/881,879
- Filed: 2022-08-05
- Published: 2023-02-09
- Granted: 2024-06-04
- Earliest claimed: 2021-08-06
- Assignees: LG Energy Solution, Ltd.
- Applicants: LG Energy Solution, Ltd.
- Inventors: Seong-Wook Kang; Jae-Sung Han; Dong-Mok Shin; Dong-Oh Shin; Kyung-Hwan Yoon; Kwang-Ho Yoo
- Web page: https://patentgrep.com/patent/US12002962B2

## CPC

- H01M 4/623: {fluorinated polymers}
- H01M 4/0404: {by coating on electrode collectors}
- H01M 4/0416: {involving impregnation with a solution, dispersion, paste or dry powder (H01M4/0438 takes precedence)}
- H01M 4/0435: {Rolling or calendering}
- H01M 4/0471: {involving thermal treatment, e.g. firing, sintering, backing particulate active material, thermal decomposition, pyrolysis}
- H01M 4/622: {being polymers}
- H01M 10/05: Accumulators with non-aqueous electrolyte (H01M10/39 takes precedence)
- H01M 10/0525: Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
- H01M 10/058: Construction or manufacture
- Y02E 60/10: Energy storage using batteries
- H01M: PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION

## Abstract

Disclosed is a method for manufacturing a dry electrode. The method allows determination of the micro-fibrilization degree of a binder resin from the crystallinity of the binder resin. Based on this, the processing conditions of mixed powder for electrode or an electrode film may be controlled. In this manner, it is possible to check and control the processing conditions easily and efficiently. In addition, the method for manufacturing a dry electrode includes a kneading step using a kneader under a low speed and high temperature and pulverization step. Therefore, there is no problem of blocking of a flow path caused by aggregation of the ingredients, which is favorable to mass production.

## Claims

### Claim 1

An electrode for an electrochemical device, comprising:
a dry free-standing electrode film obtained by a dry manufacturing process using no solvent, wherein the dry electrode film comprises an electrode active material, a conductive material, and a binder resin,
wherein the binder resin contained in the dry electrode film has a crystallinity of 10% or less,
wherein the dry electrode film has a tensile strength of 0.5 MPa or more and 10 MPa or less in the machine direction (MD).

### Claim 2 (depends on 1)

The electrode for an electrochemical device according to claim 1, wherein the dry electrode film has a tensile elongation of 2% or more and 30% or less.

### Claim 3 (depends on 1)

The electrode for an electrochemical device according to claim 1, wherein the dry electrode film has a porosity of 20-50 vol %.

### Claim 4

A method for manufacturing an electrode for an electrochemical device, the method comprising:
(a) preparing a powdery blend comprising an electrode active material, a conductive material and a binder resin;
(b) kneading the powdery mixture at 70-200° C. to prepare mixture lumps;
(c) pulverizing the mixture lumps to obtain mixed powder for electrode; and
(d) calendering the mixed powder for electrode to obtain a free-standing-type dry electrode film, wherein the binder resin contained in the dry electrode film obtained from the calendering (d) has a crystallinity (d) of 10% or less,
wherein the method is a dry manufacturing process using no solvent.

### Claim 5 (depends on 4)

The method for manufacturing the electrode for an electrochemical device according to claim 4, wherein the binder resin contained in the mixed powder for electrode obtained from the pulverizing (c) has a crystallinity (c) of 20% or less.

### Claim 6 (depends on 4)

The method for manufacturing the electrode for an electrochemical device according to claim 4, wherein the binder resin contained in the mixture obtained from preparing the powdery blend (a) has a crystallinity (a) of 50% or less.

### Claim 7 (depends on 4)

The method for manufacturing the electrode for an electrochemical device according to claim 4, wherein the preparing the powdery blend (a) is carried out at 500-30,000 rpm.

### Claim 8 (depends on 4)

The method for manufacturing the electrode for an electrochemical device according to claim 4, wherein the kneading (b) is carried out under a rotation speed of 100 rpm or less.

### Claim 9 (depends on 4)

The method for manufacturing the electrode for an electrochemical device according to claim 4, wherein the kneading (b) is carried out under a pressure of 0.5 kgf/cm2 to 10 kgf/cm2.

### Claim 10 (depends on 4)

The method for manufacturing the electrode for an electrochemical device according to claim 4, wherein the kneading (b) is carried out under a pressure of an atmospheric pressure or more.

### Claim 11 (depends on 1)

The electrode for an electrochemical device according to claim 1, wherein the binder resin comprises polytetrafluoroethylene (PTFE), polyvinylidene fluoride (PVDF), polyolefin, or a mixture of two or more of them.

### Claim 12 (depends on 1)

The electrode for an electrochemical device according to claim 1, which further comprises a current collector, wherein the dry electrode film is disposed on at least one surface or both surfaces of the current collector.

### Claim 13 (depends on 4)

The method for manufacturing the electrode for an electrochemical device according to claim 4, which further comprises preparing a current collector, disposing the dry electrode film on at least one surface of the current collector and carrying out lamination.

### Claim 14 (depends on 1)

A secondary battery comprising the dry electrode as defined in claim 1, wherein the dry electrode is a positive electrode, and an electrode assembly comprising the positive electrode, a negative electrode and a separator is received in a battery casing together with a lithium-containing non-aqueous electrolyte.