# US 12,002,671 B2 · Electrode arrangement

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- Number: US 12,002,671 B2
- Document ID: US12002671B2
- Status: Granted
- Kind: B2
- Application number: 17/830,984
- Filed: 2022-06-02
- Published: 2022-09-15
- Granted: 2024-06-04
- Earliest claimed: 2019-05-21
- Assignees: Thermo Fisher Scientific (Bremen) GmbH
- Applicants: Thermo Fisher Scientific (Bremen) GmbH
- Inventors: Alexander A. Makarov; Wilko Balschun; Jan-Peter Hauschild; Denis Chernyshev; Eduard V. Denisov
- Web page: https://patentgrep.com/patent/US12002671B2

## CPC

- H01J 49/063: {Multipole ion guides, e.g. quadrupoles, hexapoles}
- H01J 49/0045: {characterised by the fragmentation or other specific reaction}
- H01J 49/068: {Mounting, supporting, spacing, or insulating electrodes}
- H01J 49/4215: {Quadrupole mass filters (H01J49/4225 takes precedence)}
- H01J 49/4225: {Multipole linear ion traps, e.g. quadrupoles, hexapoles}
- H01J: ELECTRIC DISCHARGE TUBES OR DISCHARGE LAMPS (spark-gaps H01T; electric arc lamps H05B31/00; particle accelerators H05H)

## Abstract

The present invention provides an electrode arrangement 10, 10′ for an ion trap, ion filter, an ion guide, a reaction cell or an ion analyser. The electrode arrangement 10, 10′ comprises an RF electrode 12a, 12b, 12a′, 12b′ mechanically coupled to a dielectric material 11. The RF electrode 12a, 12b, 12a′, 12b′ is mechanically coupled to the dielectric material 11 by a plurality of separators 13 that are spaced apart and configured to define a gap between the RF electrode 12a, 12b, 12a′, 12b′ and the dielectric material 11. Each of the plurality of separators 13 comprises a projecting portion 13b and the dielectric material 11 comprises corresponding receiving portions 11a such that on coupling of the RF electrode 12a, 12b, 12a′, 12b′ to the dielectric material 11, the projecting portion 13b of each separator 13 is received within the corresponding receiving portion 11a of the dielectric material 11. The present invention also relates to an ion trap comprises the electrode arrangement 10, 10′ and a method of manufacturing the electrode arrangement 10, 10′.

## Claims

### Claim 1

An electrode arrangement for an ion trap, ion filter, an ion guide, a reaction cell or an ion analyser, the electrode arrangement comprising:
an RF electrode mechanically coupled to a dielectric material; and
at least one DC electrode located between the dielectric material and the RF electrode;
wherein the RF electrode is mechanically coupled to the dielectric material by a plurality of separators that are spaced apart and configured to define a gap between the RF electrode and the dielectric material and wherein each of the plurality of separators comprises a projecting portion and the dielectric material comprises corresponding receiving portions such that on coupling of the RF electrode to the dielectric material, the projecting portion of each separator is received within the corresponding receiving portion of the dielectric material;
wherein the RF electrode has a surface opposing the dielectric material;
wherein the DC electrode extends across the dielectric material such that at least a part of the DC electrode lies directly between the surface of the RF electrode and the dielectric material; and
wherein the proportion of the surface area of the surface of the RF electrode which is shielded from the dielectric material by the DC electrode is at least 50%.

### Claim 2 (depends on 1)

The electrode arrangement of claim 1, wherein the gap defined by the separators is between the surface of the RF electrode opposing the dielectric material and the dielectric material.

### Claim 3 (depends on 1)

The electrode arrangement of claim 1, wherein:
the proportion of the surface area of the surface of the RF electrode which is shielded from the dielectric material by the DC electrode is at least 80%.

### Claim 4 (depends on 1)

The electrode arrangement of claim 1, wherein the DC electrode is segmented.

### Claim 5 (depends on 1)

The electrode arrangement of claim 1, wherein the plurality of separators are electrically conductive.

### Claim 6 (depends on 1)

The electrode arrangement of claim 1, wherein the plurality of separators are spaced apart along the surface of the RF electrode.

### Claim 7 (depends on 1)

The electrode arrangement of claim 1, wherein each projecting portion extends from the surface of the RF electrode opposing the dielectric material.

### Claim 8 (depends on 1)

The electrode arrangement of claim 1, wherein each corresponding receiving portion comprises an opening formed within the dielectric material.

### Claim 9 (depends on 8)

The electrode arrangement of claim 8, wherein each opening is a through-hole extending through the dielectric material such that on coupling of the RF electrode to the dielectric material, each projecting portion extends through the corresponding through-hole.

### Claim 10 (depends on 1)

The electrode arrangement of claim 1, wherein each separator comprises a head portion from which the projecting portion extends, wherein the head portion is of greater diameter than the projecting portion.

### Claim 11 (depends on 10)

The electrode arrangement of claim 10, wherein a diameter of the corresponding receiving portion is the same as or greater than that of the projecting portion and smaller than that of the head portion.

### Claim 12 (depends on 1)

The electrode arrangement of claim 1, wherein the DC electrode is located on the surface of the dielectric material opposing the RF electrode.

### Claim 13 (depends on 1)

The electrode arrangement of claim 1, wherein the DC electrode extends along the entirety of the surface of the dielectric material opposing the RF electrode, except for exposed portions of the dielectric material, wherein the exposed portions comprise the area of the dielectric material in contact with and/or adjacent to each separator when the RF electrode is coupled to the dielectric material.

### Claim 14 (depends on 13)

The electrode arrangement of claim 13, wherein the exposed portions have grooves therein.

### Claim 15 (depends on 1)

The electrode arrangement of claim 1, wherein the RF electrode, the DC electrode and the dielectric material are parallel.

### Claim 16 (depends on 1)

The electrode arrangement of claim 1, wherein the dielectric material is glass, ceramic or printed circuit board.

### Claim 17 (depends on 1)

The electrode arrangement of claim 1, wherein each separator is permanently secured to the RF electrode.

### Claim 18 (depends on 17)

The electrode arrangement of claim 17, wherein each separator is welded to the RF electrode.

### Claim 19 (depends on 1)

The electrode arrangement of claim 1, wherein the RF electrode comprises a plurality of openings corresponding to the projecting portions of the plurality of separators such that on coupling the RF electrode to the dielectric material, each projecting portion is received within each opening of the RF electrode.

### Claim 20 (depends on 1)

The electrode arrangement of claim 1, wherein each separator is configured to be connected to an RF voltage supply.
