# US 12,000,774 B2 · Gas analyzer

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- Number: US 12,000,774 B2
- Document ID: US12000774B2
- Status: Granted
- Kind: B2
- Application number: 17/823,200
- Filed: 2022-08-30
- Published: 2023-03-16
- Granted: 2024-06-04
- Earliest claimed: 2021-09-15
- Assignees: Thermo Environmental Instruments Inc.
- Applicants: Thermo Environmental Instruments LLC
- Inventors: Yongquan Li; Brian Chia; Robert Bailey
- Web page: https://patentgrep.com/patent/US12000774B2

## CPC

- G01N 21/031: {Multipass arrangements}
- G01N 21/31: Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry {(G01N21/72 takes precedence)}
- G01N 33/0027: {concerning the detector}
- G01N 21/05: Flow-through cuvettes (G01N21/09 takes precedence; handling fluid samples G01N1/10)
- G01N 2201/062: LED's
- G01N 2201/0624: Compensating variation in output of LED source
- G01N 2201/0633: Directed, collimated illumination
- G01N 2201/0636: Reflectors
- G01N 2201/0691: Modulated (not pulsed supply)
- G01N 2201/0696: Pulsed
- G01N 2201/1211: for temperature
- Y02A 50/20: Air quality improvement or preservation, e.g. vehicle emission control or emission reduction by using catalytic converters
- G01N: INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES (measuring or testing apparatus or processes other than immunoassay, involving enzymes or microorganisms C12M, C12Q)
- Y02A: TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE

## Abstract

An embodiment of a gas analyzer is described that comprises a light source configured to produce a substantially collimated first beam with a diverging angle of less than about 15 degrees; a gas cell comprising an inlet configured to introduce a gas into the gas cell, an outlet configured to remove the gas from the gas cell, and a plurality of mirrors configured to reflect the substantially collimated first beam within the gas cell; and a detector configured to generate a signal in response to the substantially collimated first beam.

## Claims

### Claim 1

A gas analyzer, comprising:
an LED light source attached to a board and configured to produce a substantially collimated first beam with a first level of energy and a small diverging angle, and a second beam comprising a second level of energy that is different from the first level of energy;
a reference sensor mounted to the board adjacent to the LED light source, wherein the reference sensor detects the second level of energy of the second beam;
a processing system configured to compensate for variation in the level of energy of the substantially collimated first beam using the detected level of energy of the second beam, wherein the variation of the first and second energy levels is substantially equal and associated with temperature fluctuation of the LED light source;
a gas cell comprising an inlet configured to introduce a gas into the gas cell, an outlet configured to remove the gas from the gas cell, a first lens, a plurality of mirrors configured to reflect the substantially collimated first beam within the gas cell, and a second lens; and
a detector configured to generate a signal in response to the substantially collimated first beam.

### Claim 2 (depends on 1)

The gas analyzer of claim 1, wherein:
each of the mirrors is configured to re-focus the reflected substantially collimated first beam.

### Claim 3 (depends on 1)

The gas analyzer of claim 1, wherein:
an energy level of the substantially collimated first beam at the detector is substantially equal to an energy level of the substantially collimated first beam produced by the light source.

### Claim 4 (depends on 1)

The gas analyzer of claim 1, wherein:
each of the mirrors comprises a dielectric coating configured to provide greater than 99% reflectivity of the substantially collimated first beam.

### Claim 5 (depends on 1)

The gas analyzer of claim 1, wherein:
the substantially collimated first beam comprises a band width of about 10 nm.

### Claim 6 (depends on 1)

The gas analyzer of claim 1, wherein:
the substantially collimated first beam comprises a peak value of about 405 nm.

### Claim 7 (depends on 1)

The gas analyzer of claim 1, wherein:
the gas cell comprises a pass line distance of about 2 meters.

### Claim 8 (depends on 1)

The gas analyzer of claim 1, wherein:
the substantially collimated first light beam is reflected about 20 times in the gas cell.

### Claim 9 (depends on 1)

The gas analyzer of claim 1, wherein:
the LED light source produces the second beam in an opposite direction from the substantially collimated first beam.

### Claim 10 (depends on 1)

The gas analyzer of claim 1, wherein:
the second level of energy comprises a small level of energy compared to the first level of energy.

### Claim 11 (depends on 1)

The gas analyzer of claim 1, further comprising:
a thermo electric cooler configured to maintain the temperature of the LED light source, wherein the processing system provides instruction to the thermo electric cooler to compensate for the variation in the level of energy of the substantially collimated first beam.

### Claim 12 (depends on 11)

The gas analyzer of claim 11, wherein:
the processing system maintains a range of temperature of the LED light source around a set temperature, wherein the set temperature is selectable.

### Claim 13 (depends on 12)

The gas analyzer of claim 12, further comprising:
a temperature sensor configured to detect an ambient temperature, wherein the set temperature comprises the ambient temperature.

### Claim 14 (depends on 1)

The gas analyzer of claim 1, wherein:
wherein the first lens is configured to focus the first beam so that diverging angle remains substantially within a reflective area of each of the mirrors.

### Claim 15 (depends on 1)

The gas analyzer of claim 1, wherein:
wherein the second lens is configured to produce a focal point on an active area of the detector to maximize the collection efficiency of light.

### Claim 16 (depends on 1)

The gas analyzer of claim 1, wherein:
wherein the small diverging angle is less than about 15 degrees.
