# US 12,000,660 B1 · Thermal energy storage system with a spray of phase change material and method of its operation > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 12,000,660 B1 - Document ID: US12000660B1 - Status: Granted - Kind: B1 - Application number: 18/286,850 - Filed: 2022-03-30 - Published: 2024-06-20 - Granted: 2024-06-04 - Earliest claimed: 2021-04-14 - Assignees: Stiesdal Storage A/S - Applicants: Stiesdal Storage A/S - Inventors: Henrik Stiesdal - Web page: https://patentgrep.com/patent/US12000660B1 ## CPC - F28D 20/0056: {using solid heat storage material (F28D20/0052 takes precedence)} - F28D 20/025: {the latent heat storage material being in direct contact with a heat-exchange medium or with another heat storage material (F28D20/003 takes precedence)} - F01K 3/12: having two or more accumulators - F02C 1/10: Closed cycles - F02C 6/14: Gas-turbine plants having means for storing energy, e.g. for meeting peak loads - F28D 2020/0082: {Multiple tanks arrangements, e.g. adjacent tanks, tank in tank} - Y02E 60/14: Thermal energy storage - F28D: HEAT-EXCHANGE APPARATUS, NOT PROVIDED FOR IN ANOTHER SUBCLASS, IN WHICH THE HEAT-EXCHANGE MEDIA DO NOT COME INTO DIRECT CONTACT (fluid heaters having heat generating means and heat transferring means F24H; furnaces F27; details of heat-exchange apparatus of general) - F01K: STEAM ENGINE PLANTS; STEAM ACCUMULATORS; ENGINE PLANTS NOT OTHERWISE PROVIDED FOR; ENGINES USING SPECIAL WORKING FLUIDS OR CYCLES (gas-turbine or jet-propulsion plants F02; nuclear power plants, engine arrangements therein G21D) - F02C: GAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS (construction of turbines F01D; jet-propulsion plants F02K; construction of compressors or fans F04; generating combustion products of high pressure or high velocity F23R; using gas turbines in compression refrigeration plants F25B11/00) - Y02E: REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION ## Abstract An energy storage system comprises a hot thermal energy storage medium and a cold thermal energy storage medium, which are interconnected in a thermodynamic gas flow circuit with gas as a working fluid. An energy converter with a motor/generator system is functionally connected to a compressor/expander system for converting between electrical energy and thermal energy of the gaseous working fluid in the thermodynamic fluid circuit. A latent TES medium is thermally connected to the thermodynamic circuit for providing a lower limit for the temperature in the cold TES medium. Specifically, the latent TES medium is liquid, typically water, which is sprayed as droplets into a tank through which the gaseous working fluid flows at subzero temperatures to produce snow in order to efficiently heat the gas to the freezing point or above. ## Claims ### Claim 1 A method of operating a thermal energy storage, TES, system, wherein the TES system comprises, a thermodynamic gas flow circuit containing a working fluid that is not in liquid phase but maintained in gas phase throughout the gas flow circuit; a first TES container containing a first TES medium as a hot storage medium, wherein the first TES medium is in thermal connection with the gas flow circuit along a first gas flow path for exchange of thermal energy with the gaseous working fluid, wherein the first gas flow path is part of the gas flow circuit; a second TES container containing a second TES medium as a sensible cold storage medium for storing thermal energy and a second gas flow path through the second TES medium for exchange of thermal energy between the gaseous working fluid and the second TES medium, wherein the second gas flow path is part of the gas flow circuit; an energy converter for converting between electrical energy and thermal energy of the gaseous working fluid in the gas flow circuit; the energy converter comprising an electrical motor, an electrical generator, and a compressor/expander system, the compressor/expander system comprising a compressor and an expander, wherein the compressor is functionally connected to the motor for being driven by the motor during a charging period, and the expander is functionally connected to the generator for driving the generator during a discharging period; wherein the method comprises during a charging period, driving the compressor by the motor and adiabatically compressing the gaseous working fluid by the compressor, and circulating the gaseous working fluid through the gas flow circuit from the compressor through the first gas flow path, then through the expander, and then through the second gas flow path, and back to the compressor; wherein the TES system comprises a latent TES system, the latent TES system comprising a latent TES container that contains a latent TES medium, wherein a latent gas flow path extends through the latent TES container for exchange of thermal energy between the gaseous working fluid and the latent TES medium during the flow of the gaseous working fluid through the latent TES container along the latent gas flow path, wherein the latent gas flow path is part of the gas flow circuit and located between the compressor/expander system and the second TES container with respect to flow of the gaseous working fluid; wherein the latent TES container comprises a spray nozzle arranged for spraying the latent TES medium as atomized liquid droplets into the latent gas flow path; wherein the method comprises spraying the latent TES medium as atomized liquid droplets into the latent gas flow path during the charging period and heating the gaseous working fluid by transferring thermal energy from the atomized droplets to the gaseous working fluid and cooling the droplets into ice particles so as to provide a snow of the latent TES medium in the latent TES container. ### Claim 2 (depends on 1) The method according to claim 1, further comprising directing the latent gas flow path upwards through the spray. ### Claim 3 (depends on 1) The method according to claim 1, wherein the latent TES medium is water, and wherein the method comprises spraying liquid water into the latent gas flow path. ### Claim 4 (depends on 1) The method according to claim 1, wherein the first TES medium is a sensible TES medium, and the first gas flow path extends through the first TES medium for exchange of thermal energy between the first TES medium and the gaseous working fluid; wherein the method in the charging period comprises, guiding the gaseous working fluid from the second TES container to the compressor and adiabatically compressing the gaseous working fluid by the compressor for raising its temperature; guiding the compressed gaseous working fluid into the first TES container and transferring thermal energy from the gaseous working fluid to the first TES medium; after transfer of the thermal energy in the first TES container, guiding the gaseous working fluid to the expander and adiabatically expanding the gaseous working fluid by the expander to a pressure that causes the gaseous working fluid to attain a sub-zero temperature; guiding the gaseous working fluid with sub-zero temperature along the latent gas flow path through the latent TES container and spraying the latent medium as droplets into the latent gas flow path and freezing the droplets for heating the gaseous working fluid by the creation of snow; guiding the heated gaseous working fluid from the latent TES container into the second TES container and along the second gas flow path through the second TES medium and transferring thermal energy from the second TES medium to the gaseous working fluid. ### Claim 5 (depends on 1) The method according to claim 1, wherein the first TES container has a top and a bottom, and the first TES medium has an upper end and a lower end between the top and bottom of the first TES container, wherein the second TES container has a top and a bottom, and the second TES medium has an upper end and a lower end between the top and bottom of the second TES container, wherein the method comprises during a charging period: interconnecting the tops of the first and second TES containers through the compressor and the bottoms of the first and second TES containers through the expander, receiving the gaseous working fluid from the top of the second TES container by the compressor for the adiabatic compression, providing the compressed gaseous working fluid into the top of the first TES container and guiding it along the first flow path downwards from the top to the bottom of the first TES container through the first TES medium, receiving the gaseous working fluid from the bottom of the first TES container by the expander for the adiabatic expansion; guiding the gaseous working fluid from the expander through the latent TES container; receiving the gaseous working fluid by the bottom of the second TES container, and guiding it along the second flow path through the second TES medium, and by flow through the second TES medium towards the top of the second TES container prior to supplying it to the compressor again. ### Claim 6 (depends on 1) The method according to claim 1, wherein the method comprises providing the first TES container and the second TES container to only contain sensible TES media for thermal energy storage and no latent TES media for thermal energy storage, and wherein the method comprises storing thermal energy from the working fluid in the sensible TES media and keeping the TES containers free from latent heat storage. ### Claim 7 (depends on 1) The method according to claim 1, further comprising raising the temperature of the gaseous working fluid by the compressor during the charging to a temperature above 400° C. ### Claim 8 (depends on 1) The method according to claim 1, wherein the first TES medium or the second TES medium or both are gas permeable and the method comprises creating a flow of the gaseous working fluid through the first or the second TES medium or both, respectively, with direct contact between the gaseous working fluid and the first or the second TES medium or both. ### Claim 9 (depends on 1) The method according to claim 1, wherein the TES system comprises a gas cooling path as part of the gas flow circuit during the discharging period only, the gas cooling path being provided in gas flow direction between the second TES container and the compressor for cooling the gaseous working fluid prior to entering the compressor; wherein a snow injector is provided for injecting snow into the gaseous working fluid in the gas cooling path; wherein the method comprises, only in the discharging period, injecting snow into the gaseous working fluid while it flows through the gas cooling path and cooling the gaseous working fluid by the gaseous working fluid melting the snow prior to entering the compressor. ### Claim 10 (depends on 9) The method according to claim 9, wherein the method comprises, during the discharging period, providing snow that was produced during the charging period to the snow injector. ### Claim 11 A thermal energy storage, TES, system comprising: a thermodynamic gas flow circuit containing a working fluid that is not in liquid phase but maintained in gas phase throughout the gas flow circuit; a first TES container containing a first TES medium as a hot storage medium, wherein the first TES medium is in thermal connection with the gas flow circuit along a first gas flow path for exchange of thermal energy with the gaseous working fluid, wherein the first gas flow path is part of the gas flow circuit; a second TES container containing a second TES medium as a sensible cold storage medium for storing thermal energy and a second gas flow path through the second TES medium for exchange of thermal energy between the gaseous working fluid and the second TES medium, wherein the second gas flow path is part of the gas flow circuit; an energy converter for converting between electrical energy and thermal energy of the gaseous working fluid in the gas flow circuit; the energy converter comprising an electrical motor, an electrical generator, and a compressor/expander system, the compressor/expander system comprising a compressor and an expander, wherein the compressor is functionally connected to the motor for being driven by the motor during a charging period, and the expander is functionally connected to the generator for driving the generator during a discharging period; wherein the system is configured for driving the compressor by the motor during the charging period and adiabatically compressing the gaseous working fluid by the compressor, and circulating the gaseous working fluid through the gas flow circuit from the compressor through the first gas flow path, then through the expander, and then through the second gas flow path, and back to the compressor; wherein the TES system comprises a latent TES system, the latent TES system comprising a latent TES container that contains a latent TES medium, wherein a latent gas flow path extends through the latent TES container for exchange of thermal energy between the gaseous working fluid and the latent TES medium during the flow of the gaseous working fluid through the latent TES container along the latent gas flow path, wherein the latent gas flow path is part of the gas flow circuit and located between the compressor/expander system and the second TES container with respect to flow of the gaseous working fluid; wherein the latent TES container comprises a spray nozzle arranged for spraying the latent TES medium as atomized liquid droplets into the latent gas flow path during the charging period for heating the gaseous working fluid by transferring thermal energy from the atomized droplets to the gaseous working fluid and cooling the droplets into ice particles so as to provide a snow of the latent TES medium in the latent TES container.