# US 12,000,122 B2 · Atmospheric water harvesting system with cross-flow configuration

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- Number: US 12,000,122 B2
- Document ID: US12000122B2
- Status: Granted
- Kind: B2
- Application number: 17/673,780
- Filed: 2022-02-16
- Published: 2022-06-02
- Granted: 2024-06-04
- Earliest claimed: 2019-08-16
- Assignees: The Regents of the University of California
- Applicants: The Regents of the University of California
- Inventors: Omar M. Yaghi; Mathieu S. Prevot; Nikita Hanikel; Eugene A. Kapustin; Farhad Fathieh
- Web page: https://patentgrep.com/patent/US12000122B2

## CPC

- B01D 5/006: {with evaporation or distillation}
- E03B 3/28: from humid air (condensing of vapours in general B01D5/00; dehumidification of air for air-conditioning F24F3/14)
- B01D 1/0035: {Solar energy (for treatment of water C02F1/14)}
- B01D 53/0415: {Beds in cartridges}
- B01D 53/0438: {Cooling or heating systems}
- B01D 53/261: {by adsorption}
- B01D 53/28: Selection of materials for use as drying agents
- B01D 2253/204: Metal organic frameworks (MOF's)
- B01D 2258/06: Polluted air
- B01D 2259/4009: using hot gas
- Y02A 20/00: Water conservation; Efficient water supply; Efficient water use
- Y02A 20/212: Solar-powered wastewater sewage treatment, e.g. spray evaporation
- B01D: SEPARATION (separating solids from solids by wet methods B03B, B03D; by pneumatic jigs or tables B03B; by other dry methods B07; magnetic or electrostatic separation of solid materials from solid materials or fluids, separation by high-voltage electric fields B03C; centrifuges, vortex apparatus B04; presses per se for squeezing-out liquid from liquid-containing material B30B9/02; treatment of water C02F, e.g. softening by ion-exchange C02F1/42; {arrangements of air intake cleaners in gas turbine plants F02C7/05} ; arrangements or mounting of filters in air-conditioning, air-humidification or ventilation F24F13/28)
- E03B: INSTALLATIONS OR METHODS FOR OBTAINING, COLLECTING, OR DISTRIBUTING WATER (drilling wells, obtaining fluids in general from wells E21B; pipe-line systems in general F17D)
- Y02A: TECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE

## Abstract

Atmospheric water harvesting systems utilize a sorbent cartridge configured to hold water capture material. The sorbent cartridge is made up of a plurality of permeable trays and a plurality of spacers that are arranged to provide cross-flow for adsorption and desorption airflow pathways. The systems are used for harvesting water from surrounding air.

## Claims

### Claim 1

An atmospheric water harvesting system, wherein the system cycles between an adsorption mode followed by a desorption mode, the system comprising:
a plurality of trays, stacked one on top of each other,
wherein each tray has a permeable membrane that holds water capture material;
wherein the plurality of trays form a box with four sides,
wherein one side is an adsorption entry side, one side is an adsorption exit side, one side is a desorption entry side, and one side is a desorption exit side, and
wherein the adsorption entry side and the adsorption exit side opposite to each other, and the desorption entry side and the desorption exit side are opposite to each other;
a plurality of spacers positioned between every other tray on the adsorption entry side to create a set of adsorption channels;
a plurality of spacers positioned between every other tray on the desorption entry side to create a set of desorption channels,
wherein the set of adsorption channels are separated from and orthogonal to the set of desorption channels;
at least one heating element positioned externally to the plurality of trays;
at least one adsorption fans are positioned near the adsorption entry side,
at least one desorption fans are positioned near the desorption entry side,
a condenser positioned near the desorption exit side,
wherein, in the adsorption mode,
the at least one adsorption fans are configured to direct surrounding air through the adsorption channels, and
at least a portion of the water capture material on each tray adsorbs moisture from the surrounding air;
wherein, in the desorption mode,
the at least one heating element is configured to provide heated air, and
the at least one desorption fans are configured to direct heated air through the desorption channels that causes release of water vapor from at least a portion of the water capture material, and to direct released water vapor towards the condenser; and wherein the condenser is configured to condense the water vapor released through the desorption channels and to produce liquid water.

### Claim 2 (depends on 1)

The system of claim 1, wherein the at least one heating element comprises at least one solar heater, and wherein the at least one solar heater is configured to heat air surrounding the plurality of trays in the desorption mode to indirectly provide heat that causes release of water vapor from at least a portion of the water capture material therein.

### Claim 3 (depends on 1)

The system of claim 1, wherein, in the adsorption mode, the at least one adsorption fans are configured to further direct air out of the plurality of trays, and wherein the air released from the plurality of trays is heated by the at least one heating element to provide the heated air used in the desorption mode.

### Claim 4 (depends on 3)

The system of claim 3, further comprising:
a second plurality of trays, stacked one on top of each other,
wherein each tray has a permeable membrane that holds additional water capture material;
wherein the second plurality of trays form a box with four sides,
wherein one side is an adsorption entry side, one side is an adsorption exit side, one side is a desorption entry side, and one side is a desorption exit side, and
wherein the adsorption entry side and the adsorption exit side opposite to each other, and the desorption entry side and the desorption exit side are opposite to each other;
a second plurality of spacers positioned between every other tray on the adsorption entry side to create a second set of adsorption channels in the second plurality of trays;
a second plurality of spacers positioned between every other tray on the desorption entry side to create a second set of desorption channels in the second plurality of trays,
wherein the second set of adsorption channels are separated from and orthogonal to the second set of desorption channels;
at least one second adsorption fans are positioned near the adsorption entry side,
at least one second desorption fans are positioned near the desorption entry side,
wherein, in the adsorption mode,
the at least one second adsorption fans are configured to direct surrounding air through the second set of adsorption channels, and
at least a portion of the water capture material on each tray adsorbs moisture from the surrounding air;
wherein, in the desorption mode,
the at least one desorption fans are configured to direct the heated air through the second set of desorption channels that causes release of water vapor from at least a portion of the additional water capture material, and to direct released water vapor towards the condenser; and
wherein the condenser is configured to condense the water vapor released through the second set of desorption channels and to produce additional liquid water.

### Claim 5

An atmospheric water harvesting system, wherein the system cycles between an adsorption mode followed by a desorption mode, the system comprising:
a plurality of trays, stacked one on top of each other,
wherein each tray comprises a permeable membrane that holds water capture material, and
wherein the plurality of trays form a box with four sides,
wherein one side is an adsorption entry side, one side is an adsorption exit side, one side is a desorption entry side, and one side is a desorption exit side, and
wherein the adsorption entry side and the adsorption exit side opposite to each other, and the desorption entry side and the desorption exit side are opposite to each other;
at least one heating element positioned within the plurality of trays;
a plurality of spacers positioned between every other tray on the adsorption entry side to create a set of adsorption channels;
a plurality of spacers positioned between every other tray on the desorption entry side to create a set of desorption channels,
wherein the set of adsorption channels are separated from and orthogonal to the set of desorption channels;
at least one adsorption fans are positioned near the adsorption entry side;
at least one desorption fans are positioned near the desorption entry side;
a condenser positioned near the desorption exit side,
wherein, in the adsorption mode,
the at least one adsorption fans are configured to direct surrounding air through the adsorption channels, and
at least a portion of the water capture material on each tray adsorbs moisture from the surrounding air;
wherein, in the desorption mode,
the at least one heating element is configured to provide heat that causes release of water vapor from at least a portion of the water capture material, and
the at least one desorption fans direct released water vapor towards the condenser; and
wherein the condenser is configured to condense the water vapor released through the desorption channels and to produce liquid water.

### Claim 6 (depends on 5)

The system of claim 5, wherein the at least one heating element is incorporated into the plurality of trays, and in contact with at least a portion of the water capture material.

### Claim 7 (depends on 5)

The system of claim 5, wherein the at least one heating element is at least one resistive heater configured to directly heat the water capture material that causes release of water vapor from at least a portion of the water capture material in the plurality of trays in the desorption mode.

### Claim 8 (depends on 1)

The system of claim 1, further comprising a power source, wherein the power source comprises at least one solar panel, or an electrical power source, or a combination thereof.

### Claim 9 (depends on 1)

The system of claim 1, further comprising a water storage tank.

### Claim 10 (depends on 1)

The system of claim 1, further comprising:
at least one sensor, configured to detect the saturation level of the water capture material in the plurality of trays; and
at least one controller, configured to receive input from the at least one sensor regarding the saturation level of the water capture material in the plurality of trays, and to turn on the heating element when a predetermined saturation level is reached.

### Claim 11 (depends on 1)

The system of claim 1, wherein the water capture material comprises metal-organic framework.

### Claim 12 (depends on 1)

The system of claim 1, wherein the water capture material comprises MOF-801, MOF-841, aluminum fumarate, CAU-10, or MOF-303, or any combination thereof.

### Claim 13 (depends on 1)

A method of harvesting water from surrounding air using an atmospheric water harvesting system of claim 1, the method comprising:
directing surrounding air through the adsorption channels in the adsorption mode,
wherein at least a portion of the water capture material adsorbs moisture from the surrounding air;
heating air using the at least one heating element to produce heated air;
directing the heated air through the desorption channels to release water vapor from at least a portion of the water capture material in the desorption mode; and
condensing the released water vapor using the condenser to produce liquid water.

### Claim 14 (depends on 5)

A method of harvesting water from surrounding air using an atmospheric water harvesting system of claim 5, the method comprising:
directing surrounding air through the adsorption channels in the adsorption mode,
wherein at least a portion of the water capture material adsorbs moisture from the surrounding air;
heating air using the at least one heating element to produce heated air;
directing the heated air through the desorption channels to release water vapor from at least a portion of the water capture material in the desorption mode; and
condensing the released water vapor using the condenser to produce liquid water.

### Claim 15

A method of harvesting water from surrounding air using an atmospheric water harvesting system, wherein the system comprises: a plurality of trays stacked one on top of each other, wherein each tray comprises a permeable membrane that holds water capture material, and wherein the plurality of trays are arranged to form a set of adsorption channels and a set of desorption channels, wherein the set of adsorption channels are separated from and orthogonal to the set of desorption channels; at least one heating element positioned externally to the plurality of trays; and a condenser; and wherein the system cycles between an adsorption mode followed by a desorption mode,
the method comprising:
directing surrounding air through the adsorption channels in the adsorption mode,
wherein at least a portion of the water capture material adsorbs moisture from the surrounding air;
heating air using the at least one heating element to produce heated air;
directing the heated air through the desorption channels to release water vapor from at least a portion of the water capture material in the desorption mode; and
condensing the released water vapor using the condenser to produce liquid water; or
a method of harvesting water from surrounding air using an atmospheric water harvesting system, wherein the system comprises: a plurality of trays stacked one on top of each other, wherein each tray comprises a permeable membrane that holds water capture material, and wherein the plurality of trays are arranged to form a set of adsorption channels and a set of desorption channels, wherein the set of adsorption channels are separated from and orthogonal to the set of desorption channels; at least one heating element positioned within the plurality of trays; and a condenser; and wherein the system cycles between an adsorption mode followed by a desorption mode,
the method comprising:
directing surrounding air through the adsorption channels in the adsorption mode, wherein at least a portion of the water capture material adsorbs moisture from the surrounding air;
heating the water capture material using the at least one heating element in the desorption phase to release water vapor from at least a portion of the water capture material;
directing the released water vapor through the desorption channels towards the condenser; and
condensing the released water vapor using the condenser to produce liquid water.

### Claim 16 (depends on 15)

The method of claim 15, wherein the at least one heating element comprises at least one solar heater.

### Claim 17 (depends on 15)

The method of claim 15, wherein the at least one heating element comprises at least one resistive heater.

### Claim 18 (depends on 15)

The method of claim 15 further comprising collecting the liquid water, and storing the liquid water.

### Claim 19 (depends on 15)

The method of claim 15, wherein the water capture material comprises metal-organic framework.

### Claim 20 (depends on 15)

The method of claim 15, wherein the water capture material comprises MOF-801, MOF-841, aluminum fumarate, CAU-10, or MOF-303, or any combination thereof.
