Back to results
US 11,999,911 B2Granted
Catalyst for hydrogenation and method for preparing same
AssigneeHanwha Solutions Corporation
InventorsWoo Jin Park, Bong Sik Jeon, Yong Hee Lee, Eui Geun Jung
Life of this patent
Estimating the term…
Abstract
The present invention relates to a catalyst for hydrogenation and a method for preparing the same, and more specifically, provides a catalyst having improved activity by including copper and copper oxide as a promoter when a hydrogenation catalyst including nickel is prepared by using a deposition-precipitation (DP) method. Accordingly, a catalyst having high activity may be provided in a hydrogenation process of a hydrocarbon resin.
Claims14
A catalyst for hydrogenation, comprising:
- 50-80 parts by weight of nickel oxide;
- 0.01-5 parts by weight of copper oxide and 10-50 parts by weight of a silica carrier, wherein a particle size distribution of the catalyst has D10 of 2 μm or more, D50 of 5-7 μm, and D90 of 15 μm or less, and
- wherein a ratio between a weight of the copper oxide to a weight sum of the nickel oxide and the copper oxide is 0.01-2.0:100.
A method for preparing a catalyst for hydrogenation, comprising the steps of:
- preparing a first solution by dissolving a nickel precursor in a solvent, so that a weight concentration (g/L) of nickel in a solution is 25 to 250;
- preparing a second solution by adding a copper precursor to the first solution, so that a weight concentration (g/L) of copper in a solution is 0.01 to 5;
- preparing a third solution by adding a silica carrier to the second solution and dispersing the silica carrier, so that a weight concentration (g/L) of silica in a solution is 10 to 50;
- adding the third solution to a precipitation container and stirring and heating the third solution to a temperature to 50-120° C.;
- adding a pH control agent to the heated third solution and depositing the nickel and copper precursors on the solid silica carrier forming a precipitation;
- washing and filtering the supported catalyst and drying the supported catalyst at 100-200° C. for 5 to 24 hours;
- calcining the dried catalyst at a temperature of 200-500° C. in air;
- and
- activating the calcined catalyst by reducing the calcined catalyst to a temperature of 200-500° C. in a hydrogen atmosphere,
- wherein a particle size distribution of the catalyst has D10 of 2 μm or more, D50 of 5-7 μm, and D90 of 15 μm or less, and
- wherein the nickel is included in an amount of 50 parts by weight or more, and
- nickel oxide and copper oxide are included, wherein a ratio between a weight of the copper oxide to a weight sum of the nickel oxide and the copper oxide is 0.01-2.0:100.
9 more elements
Dependencies are inferred from the claim text.