# US 11,999,879 B2 · Adhesive film and display member comprising the same

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- Number: US 11,999,879 B2
- Document ID: US11999879B2
- Status: Granted
- Kind: B2
- Application number: 17/068,155
- Filed: 2020-10-12
- Published: 2021-02-04
- Granted: 2024-06-04
- Earliest claimed: 2015-06-30
- Assignees: Samsung SDI Co., Ltd.; Samsung Electronics Co., Ltd.
- Applicants: Samsung SDI Co., Ltd.; Samsung Electronics Co., Ltd.
- Inventors: Ik Hwan Cho; Ji Ho Kim; Jee Hee Kim; Ji Won Kang; Byeong Do Kwak; Yong Tae Kim; Il Jin Kim; Sung Hyun Mun; Hyung Rang Moon; Seon Hee Shin; Gwang Hwan Lee; Woo Jin Lee; Jae Hyun Han
- Web page: https://patentgrep.com/patent/US11999879B2

## CPC

- C09J 133/08: Homopolymers or copolymers of acrylic acid esters
- C09J 7/10: without carriers
- C09J 2203/318: for the production of liquid crystal displays
- C09J 2301/312: parameters being the characterizing feature
- C09J 2301/408: additives as essential feature of the adhesive layer
- C09J 2433/00: Presence of (meth)acrylic polymer
- C09J: ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES (preparation of glue or gelatine C09H)

## Abstract

An adhesive film and a display member including the same are disclosed. The adhesive film is formed of an adhesive composition including: a copolymer of a monomer mixture including a hydroxyl group-containing (meth)acrylate and a comonomer; and nanoparticles. The adhesive film has a creep at −20° C. of about 50 μm to about 100 μm and a gel fraction of about 50% to about 75%.

## Claims

### Claim 1

An adhesive film formed of a cured adhesive composition comprising: a copolymer of a monomer mixture comprising a hydroxyl group-containing (meth)acrylate and a comonomer; and nanoparticles, wherein the adhesive film has a creep at −20° C. of about 50 μm to about 100 μm and a storage modulus at −20° C. of about 30 kPa to about 100 kPa, wherein the nanoparticles have an average particle diameter of about 5 nm to about 400 nm, and
wherein the nanoparticles are present in an amount of about 0.1 parts by weight to about 10 parts by weight relative to 100 parts by weight of the monomer mixture,.
wherein the hydroxyl group-containing (meth)acrylate is a C1 to C20 alkyl group-containing (meth)acrylic acid ester having at least one hydroxyl group, a C5 to C20 cycloalkyl group-containing (meth)acrylic acid ester having at least one hydroxyl group, or a C6 to C20 aryl group-containing (meth)acrylic acid ester having at least one hydroxyl group, and
the comonomer includes at least one of alkyl (meth)acrylate monomers, ethylene oxide-containing monomers, propylene oxide-containing monomers, amine group-containing monomers, amide group-containing monomers, alkoxy group-containing monomers, phosphoric acid group-containing monomers, sulfonic acid group-containing monomers, phenyl group-containing monomers, or silane group-containing monomers.

### Claim 2 (depends on 1)

The adhesive film according to claim 1, wherein the hydroxyl group- containing (meth)acrylate is present in an amount of about 10 wt % to about 40 wt % in the monomer mixture.

### Claim 3 (depends on 1)

The adhesive film according to claim 1, wherein the adhesive film has a creep of about 60 μm to about 350 μm at 25° C.

### Claim 4 (depends on 1)

The adhesive film according to claim 1,
wherein the adhesive film has a T-peel strength of about 400 gf/in to about 4,000 gf/in with respect to a corona-treated PET film at 25° C., and
wherein the adhesive film has a T-peel strength of about 200 gf/in to about 3,000 gf/in with respect to a corona-treated PET film at 60° C.

### Claim 5 (depends on 1)

The adhesive film according to claim 1,
wherein the adhesive film has a storage modulus of about 10 kPa to about 100 kPa at 25° C., and
wherein the adhesive film has a storage modulus of about 10 kPa to about 100 kPa at 80° C.

### Claim 6 (depends on 1)

The adhesive film according to claim 1, wherein the adhesive film has a ratio of storage modulus at −20° C. to storage modulus at 25° C. of about 1:1 to 4:1.

### Claim 7 (depends on 1)

The adhesive film according to claim 1, wherein the adhesive film has a difference of about 55 kPa or less between storage modulus at −20° C. and storage modulus at 80° C.

### Claim 8 (depends on 1)

The adhesive film according to claim 1, wherein the adhesive film has a glass transition temperature (Tg) of about −35° C. to about −60° C.

### Claim 9 (depends on 1)

The adhesive film according to claim 1, wherein the adhesive film has a haze of about 5% or less at a thickness of 100 μm.

### Claim 10 (depends on 1)

A display member comprising:
an optical film; and
the adhesive film according to claim 1 attached to one or both surfaces of the optical film.

### Claim 11 (depends on 1)

The adhesive film according to claim 1, wherein
the hydroxyl group-containing (meth)acrylate includes at least one of 2-hydroxyethyl (meth)acrylate, 4-hydroxybutyl (meth)acrylate, 2-hydroxypropyl (meth)acrylate, 2-hydroxybutyl (meth)acrylate, and 6-hydroxyhexyl (meth)acrylate; and
the comonomer includes at least one of alkyl (meth)acrylate monomers including methyl acrylate, ethyl acrylate, isopropyl acrylate, n-butyl acrylate, iso-butyl acrylate, hexyl (meth)acrylate, heptyl (meth)acrylate, 2-ethylhexyl acrylate, dodecyl (meth)acrylate, polyethylene oxide monomethyl ether (meth)acrylate, polyethylene oxide monoethyl ether (meth)acrylate, polyethylene oxide monopropyl ether (meth)acrylate, polyethylene oxide monobutyl ether (meth)acrylate, polyethylene oxide monopentyl ether (meth)acrylate, polypropylene oxide monomethyl ether (meth)acrylate, polypropylene oxide monoethyl ether (meth)acrylate, polypropylene oxide monopropyl ether (meth)acrylate, monomethylaminoethyl (meth)acrylate, monoethylaminoethyl (meth)acrylate, monomethylaminopropyl (meth)acrylate, monoethylaminopropyl (meth)acrylate, 2-methoxyethyl (meth)acrylate, 2-methoxypropyl (meth)acrylate, 2-ethoxypropyl (meth)acrylate, 2-acetoacetoxyethyl (meth)acrylate, vinyltrimethoxysilane, or vinyltriethoxysilane.