# US 11,999,678 B2 · Process and plant for producing methanol

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- Number: US 11,999,678 B2
- Document ID: US11999678B2
- Status: Granted
- Kind: B2
- Application number: 18/080,394
- Filed: 2022-12-13
- Published: 2023-06-22
- Granted: 2024-06-04
- Earliest claimed: 2021-12-20
- Assignees: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
- Applicants: L'Air Liquide Société Anonyme pour l'Etude et l'Exploitation des Procédés Georges Claude
- Inventors: Marc Wagner; Timm Schuhmann; Frank Castillo-Welter; Tobias Oelmann
- Web page: https://patentgrep.com/patent/US11999678B2

## CPC

- C07C 29/152: characterised by the reactor used
- B01J 19/0013: {Controlling the temperature of the process}
- B01J 19/245: {placed in series}
- C07C 29/151: with hydrogen or hydrogen-containing gases
- B01J 2219/0004: Processes in series
- B01J 2219/00051: Controlling the temperature
- B01J 2219/00164: controlling the flow
- C07C: ACYCLIC OR CARBOCYCLIC COMPOUNDS
- B01J: CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS

## Abstract

The invention relates to a process and a plant for producing methanol in which a compressed make-up gas stream which contains at least one carbon oxide and hydrogen is combined with a residual gas to afford a synthesis gas stream and reacted to afford methanol. According to the invention the residual gas stream and the make-up gas stream are combined using a jet pump, wherein the compressed make-up gas stream is supplied to the jet pump as motive medium via its motive media connection at a pressure p1 and the residual gas stream is supplied to the jet pump as suction medium via its suction port at a pressure p3 and wherein the synthesis gas stream is discharged from the jet pump via its pressure port at a pressure p2 and subsequently supplied to the synthesis stage and wherein p1>p2>p3.

## Claims

### Claim 1

A process for producing methanol, comprising:
a) providing and compressing a make-up gas stream, wherein the make-up gas stream comprises at least one carbon oxide and hydrogen;
b) reacting a synthesis gas stream in a synthesis stage over a solid methanol synthesis catalyst, wherein raw methanol and a residual gas stream are obtained and wherein the raw methanol after cooling and condensation as liquid reaction product and the residual gas stream are discharged from the synthesis stage;
c) combining the residual gas stream with the make-up gas stream to obtain the synthesis gas stream,
wherein the residual gas stream and the make-up gas stream are combined using a jet pump, wherein the compressed make-up gas stream is supplied to the jet pump as motive medium via its motive media connection at a pressure p1 and the residual gas stream is supplied to the jet pump as suction medium via its suction port at a pressure p3 and wherein the synthesis gas stream is discharged from the jet pump via its pressure port at a pressure p2 and subsequently supplied to the synthesis stage and wherein p1>p2>p3.

### Claim 2 (depends on 1)

The process according to claim 1, wherein for a recirculation rate R defined as
R
=
Volume
⁢
flow
(
RG
)
Volume
⁢
flow
(
MG
)
,
0.3≤R≤2.0.

### Claim 3 (depends on 1)

The process according to claim 1, wherein the process comprises a plurality N of serially arranged synthesis stages, wherein the raw methanol after cooling and condensation as liquid reaction product is discharged from each of the synthesis stages and the residual gas stream is discharged from the last of the N synthesis stages.

### Claim 4 (depends on 3)

The process according to claim 3, wherein N≥2.

### Claim 5 (depends on 1)

The process according to claim 1, wherein the proportion of carbon dioxide in the carbon oxides in the make-up gas stream MG is at least 50% by volume.