# US 11,999,632 B2 · Quantum dot, display panel and display device

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- Number: US 11,999,632 B2
- Document ID: US11999632B2
- Status: Granted
- Kind: B2
- Application number: 17/534,328
- Filed: 2021-11-23
- Published: 2022-06-23
- Granted: 2024-06-04
- Earliest claimed: 2020-12-23
- Assignees: LG Display Co., Ltd.
- Applicants: LG Display Co., Ltd.
- Inventors: KyungKook Jang; DaBin Kim; SeungRyong Lee
- Web page: https://patentgrep.com/patent/US11999632B2

## CPC

- C01G 9/08: Sulfides
- C01G 9/006: {Compounds containing zinc, with or without oxygen or hydrogen, and containing two or more other elements}
- C01G 15/00: Compounds of gallium, indium or thallium
- C09K 11/565: {with zinc cadmium}
- C09K 11/70: containing phosphorus
- C09K 11/883: {with zinc or cadmium}
- G02B 5/20: Filters (polarising elements G02B5/30)
- H10H 20/8512: {Wavelength conversion materials}
- H10K 59/38: comprising colour filters or colour changing media [CCM]
- B82Y 20/00: Nanooptics, e.g. quantum optics or photonic crystals
- B82Y 30/00: Nanotechnology for materials or surface science, e.g. nanocomposites
- B82Y 35/00: Methods or apparatus for measurement or analysis of nanostructures
- B82Y 40/00: Manufacture or treatment of nanostructures
- C01P 2004/64: Nanometer sized, i.e. from 1-100 nanometer
- C01P 2006/60: Optical properties, e.g. expressed in CIELAB-values
- G02B 2207/101: Nanooptics
- G02F 1/133614: {using photoluminescence, e.g. phosphors illuminated by UV or blue light}
- G02F 2202/36: Micro- or nanomaterials
- H10H 20/0361: {of wavelength conversion means}
- H10H 20/8515: {not being in contact with the bodies}
- C01G: COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F (metal hydrides {monoborane, diborane or addition complexes thereof} C01B6/00; salts of oxyacids of halogens C01B11/00; peroxides, salts or peroxyacids C01B15/00; thiosulfates, dithionites, polythionates C01B17/64; compounds containing selenium, or tellurium C01B19/00; binary compounds of nitrogen with metals C01B21/06; azides C01B21/08; {compounds containing nitrogen, other non-metals and metal C01B21/082}; metal amides C01B21/092; nitrites C01B21/50; {compounds of noble gases C01B23/0005}; phosphides C01B25/08; salts of oxyacids of phosphorus C01B25/16; carbides C01B32/90; compounds containing silicon C01B33/00; compounds containing boron C01B35/00; compounds having molecular sieve properties but not having base-exchange properties C01B37/00; compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites, C01B39/00; cyanides C01C3/08; salts of cyanamide C01C3/16; thiocyanates C01C3/20)
- C09K: MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- G02B: OPTICAL ELEMENTS, SYSTEMS OR APPARATUS
- H10H: INORGANIC LIGHT-EMITTING SEMICONDUCTOR DEVICES HAVING POTENTIAL BARRIERS
- H10K: ORGANIC ELECTRIC SOLID-STATE DEVICES
- B82Y: SPECIFIC USES OR APPLICATIONS OF NANOSTRUCTURES; MEASUREMENT OR ANALYSIS OF NANOSTRUCTURES; MANUFACTURE OR TREATMENT OF NANOSTRUCTURES
- C01P: INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- G02F: OPTICAL DEVICES OR ARRANGEMENTS FOR THE CONTROL OF LIGHT BY MODIFICATION OF THE OPTICAL PROPERTIES OF THE MEDIA OF THE ELEMENTS INVOLVED THEREIN; NON-LINEAR OPTICS; FREQUENCY-CHANGING OF LIGHT; OPTICAL LOGIC ELEMENTS; OPTICAL ANALOGUE/DIGITAL CONVERTERS

## Abstract

A quantum dot includes a core, a first shell and a second shell. The core includes a group III-V compound. The first shell includes a second semiconductor nanocrystal. The second semiconductor nanocrystal includes zinc, selenium and a dopant including tellurium. The second shell includes a third semiconductor nanocrystal. The third semiconductor nanocrystal includes a II-VI compound.

## Claims

### Claim 1

A quantum dot, comprising:
a core including a group III-V compound;
a first shell including a second semiconductor nanocrystal, the second semiconductor nanocrystal including:
zinc,
selenium, and
a dopant including tellurium; and
a second shell including a third semiconductor nanocrystal, the third semiconductor nanocrystal including a II-VI compound,
wherein:
the dopant of tellurium is positioned at an interface between the first shell and the second shell;
the molar ratio of tellurium to selenium in the first shell is in a range of 5:95 to 50:50; and
the molar ratio of tellurium to zinc in the first shell is in a range of 6:94 to 35:65.

### Claim 2 (depends on 1)

The quantum dot according to claim 1, wherein the core comprises a first semiconductor nanocrystal including indium and phosphorus.

### Claim 3 (depends on 1)

The quantum dot according to claim 1, wherein the third semiconductor nanocrystal comprises zinc and sulfur.

### Claim 4 (depends on 1)

The quantum dot according to claim 1, wherein a maximum emission wavelength λmax of the quantum dot is in a range of 540 nm to 550 nm when the quantum dot is irradiated by light having a wavelength of 440 nm to 460 nm.

### Claim 5 (depends on 1)

The quantum dot according to claim 1, wherein a quantum yield of the quantum dot is 86% or more and a half width of the quantum dot is 40 nm or less.

### Claim 6

A display panel, comprising:
a light source configured to emit light having a wavelength of substantially 450 nm, the light having a first color; and
a wavelength conversion layer positioned on a path of the light emitted from the light source, the wavelength conversion layer including a quantum dot configured to convert the light having the first color into light having a second color, and the quantum dot including:
a core comprising a group III-V compound;
a first shell including a second semiconductor nanocrystal, the second semiconductor nanocrystal including:
zinc,
selenium, and
a dopant including tellurium; and
a second shell including a third semiconductor nanocrystal, the third semiconductor nanocrystal including a II-VI compound,
wherein:
the dopant of tellurium is positioned at an interface between the first shell and the second shell;
the molar ratio of tellurium to selenium in the first shell is in a range of 5:95 to 50:50; and
the molar ratio of tellurium to zinc in the first shell is in a range of 6:94 to 35:65.

### Claim 7 (depends on 6)

The display panel according to claim 6, wherein the first color is blue and the second color is green.

### Claim 8 (depends on 6)

The display panel according to claim 6, further comprising:
a color filter positioned on a path of the light having the second color.

### Claim 9

A display device, comprising a display panel and a controller configured to control the display panel, wherein the display panel comprises:
a light source configured to emit light having a wavelength of substantially 450 nm, the light having a first color; and
a wavelength conversion layer positioned on a path of the light emitted from the light source, the wavelength conversion layer including a quantum dot configured to convert the light having the first color into light having a second color, and the quantum dot including:
a core comprising a group III-V compound;
a first shell including a second semiconductor nanocrystal, the second semiconductor nanocrystal including:
zinc,
selenium, and
a dopant including tellurium; and
a second shell including a third semiconductor nanocrystal, the third semiconductor nanocrystal including a II-VI compound,
wherein:
the dopant of tellurium is positioned at an interface between the first shell and the second shell;
the molar ratio of tellurium to selenium in the first shell is in a range of 5:95 to
50:50; and
the molar ratio of tellurium to zinc in the first shell is in a range of 6:94 to 35:65.
