# US 11,998,734 B2 · Ring electrode with intermediate diffusion layer

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- Number: US 11,998,734 B2
- Document ID: US11998734B2
- Status: Granted
- Kind: B2
- Application number: 17/374,347
- Filed: 2021-07-13
- Published: 2022-01-13
- Granted: 2024-06-04
- Earliest claimed: 2020-07-13
- Assignees: Heraeus Deutschland GmbH & Co. KG
- Applicants: Heraeus Deutschland Gmbh & Co. KG
- Inventors: Markus Jung; Bernd Spaniol
- Web page: https://patentgrep.com/patent/US11998734B2

## CPC

- A61B 5/29: for permanent or long-term implantation
- A61N 1/056: {Transvascular endocardial electrode systems}
- A61N 1/05: for implantation or insertion into the body, e.g. heart electrode (A61N1/06 takes precedence)
- A61N 1/0551: {Spinal or peripheral nerve electrodes}
- B21C 37/06: of tubes or metal hoses; Combined procedures for making tubes, e.g. for making multi-wall tubes
- H01R 13/025: {formed by the conductors of a cable end}
- A61B 2562/125: characterised by the manufacture of electrodes
- H01R 2201/12: for medicine and surgery
- A61B: DIAGNOSIS; SURGERY; IDENTIFICATION (usefulness limited to only animals A61D)
- A61N: ELECTROTHERAPY; MAGNETOTHERAPY; RADIATION THERAPY; ULTRASOUND THERAPY (measurement of bioelectric currents A61B; surgical instruments, devices or methods for transferring non-mechanical forms of energy to or from the body A61B18/00; anaesthetic apparatus in general A61M; incandescent lamps H01K; infrared radiators for heating H05B)
- B21C: MANUFACTURE OF METAL SHEETS, WIRE, RODS, TUBES, PROFILES OR LIKE SEMI-MANUFACTURED PRODUCTS OTHERWISE THAN BY ROLLING; AUXILIARY OPERATIONS USED IN CONNECTION WITH METAL-WORKING WITHOUT ESSENTIALLY REMOVING MATERIAL
- H01R: ELECTRICALLY-CONDUCTIVE CONNECTIONS; STRUCTURAL ASSOCIATIONS OF A PLURALITY OF MUTUALLY-INSULATED ELECTRICAL CONNECTING ELEMENTS; COUPLING DEVICES; CURRENT COLLECTORS

## Abstract

One aspect relates to a method for producing a ring electrode, including providing an outer element including an outer tube; providing a first inner element, including a first inner tube having a first core made of a sacrificial material, a material of the outer element and a material of the first inner element having a similar microstructure to each other; providing a second inner element, including a second core made of a sacrificial material; forming a composite tube by arranging the first inner element and the second inner element inside the outer element, the first inner element and the second inner element being arranged eccentrically; drawing the composite tube in a longitudinal direction of the composite tube, the material of the outer element and the material of the first inner element retaining a similar microstructure; separating a composite tube disk from the composite tube; removing the sacrificial material of the first core; and removing the sacrificial material of the second core to obtain a contacting opening in the ring electrode.

## Claims

### Claim 1

A method for producing a ring electrode, comprising:
(a) providing an outer element comprising an outer tube,
(b) providing a first inner element, which comprises a first inner tube having a first core made of a sacrificial material,
the first inner tube comprising a diffusion agent on the outer side of the first inner tube, or the outer tube comprising a diffusion agent on the inner side of the outer tube,
(c) providing a second inner element, which comprises a second core made of a sacrificial material,
(d) forming a composite tube by arranging the first inner element and the second inner element inside the outer element, the first inner element and the second inner element being arranged eccentrically to each other,
(e) drawing the composite tube in a longitudinal direction of the composite tube,
(f) forming an integral connection between the outer element and the first inner element by means of the diffusion agent,
(g) separating a composite tube disk from the composite tube,
(h) removing the sacrificial material of the first core, and
(i) removing the sacrificial material of the second core to obtain a contacting opening in the ring electrode.

### Claim 2 (depends on 1)

The production method according to claim 1, wherein the composite tube is heated to connect the outer element to the first inner element and optionally the second inner element by diffusion bonding by means of the diffusion agent, wherein the composite tube is heated to at least 50% of the melting temperature of the diffusion agent.

### Claim 3 (depends on 1)

The production method according to claim 1, wherein the composite tube is heated to connect the outer element to the first inner element and the second inner element by diffusion bonding by means of the diffusion agent, wherein the composite tube is heated to at least 65% of the melting temperature of the diffusion agent.

### Claim 4 (depends on 1)

The production method according to claim 1, wherein the second inner element comprises a second inner tube which surrounds the second core, wherein the second inner tube further comprises a diffusion agent on the outer side of the second inner tube.

### Claim 5 (depends on 1)

The production method according to claim 1, wherein the diffusion agent is selected from the group consisting of Au, Pd, Ti, Ni, Co, Cr, Fe, Ag, and an active solder.

### Claim 6 (depends on 5)

The production method according to claim 5, wherein the diffusion agent has a lower melting point than the outer tube, the first inner tube or the second inner tube.

### Claim 7 (depends on 1)

The production method according to claim 1, wherein the outer tube, the first inner tube or the second inner tube are coated with the diffusion agent by means of electroplating, dip coating, CVD, PVD or by applying a film.

### Claim 8 (depends on 1)

The production method according to claim 1, wherein the diffusion agent is applied to the outer tube, the first inner tube or the second inner tube with a layer thickness of 100 nm to 100 μm.

### Claim 9 (depends on 1)

The production method according to claim 1, wherein in (e) the outer element and the first inner element and the second inner tube are each connected to each other without gaps.

### Claim 10 (depends on 1)

The production method according to claim 1, wherein the outer tube and the first inner tube and the second inner tube comprise a noble metal, a non-noble metal and/or a ceramic material, wherein the non-noble metal is Ti, MP35, 316L, 301 or 304.

### Claim 11 (depends on 1)

The production method according to claim 1, wherein the outer tube and the first inner tube and the second inner tube each substantially consist of the same material, or different materials.

### Claim 12 (depends on 1)

The production method according to claim 1, wherein the sacrificial material of the first core and/or the sacrificial material of the second core comprise a non-noble metal, Cu, Ni or Fe.

### Claim 13 (depends on 1)

A ring electrode produced by a method according to claim 1.

### Claim 14 (depends on 13)

An electrode system comprising a ring electrode according to claim 13 and a conductor element, wherein the conductor element is connected to a contacting opening in the ring electrode.

### Claim 15 (depends on 14)

The use of an electrode system according to claim 14 for producing an implantable medical sensor or stimulator.

### Claim 16 (depends on 13)

The use of a ring electrode according to claim 13 for producing an implantable medical sensor or stimulator.

### Claim 17

A composite tube for producing a ring electrode, comprising:
an outer element;
a first inner element; and
a second inner element;
wherein the outer element comprises an outer tube;
wherein the first inner element comprises a first inner tube with an outer side;
wherein the first inner element and the second inner element are arranged inside the outer element, and the first inner element and the second inner element are arranged eccentrically to each other to form a composite tube; and
wherein a diffusion agent is arranged on the outer side of the first inner tube or on the inner side of the outer tube.

### Claim 18 (depends on 17)

The composite tube according to claim 17, wherein the second inner element comprises a second inner tube which surrounds the second core, wherein the second inner tube further comprises a diffusion agent on the outer side of the second inner tube.

### Claim 19 (depends on 17)

The use of a composite tube according to claim 17 for producing an implantable medical sensor or stimulator.

### Claim 20

A ring electrode, comprising:
an outer element;
a first inner element; and
a second inner element;
wherein the outer element comprises an outer tube;
wherein the first inner element comprises a first inner tube with an outer side;
wherein the first inner element and the second inner element are arranged inside the outer element, and the first inner element and the second inner element are arranged eccentrically to each other to form a composite tube;
wherein the outer element, the first inner element and the second inner element are drawn together in a longitudinal direction of the composite tube; and
wherein the outer element is connected to the first inner element by an integral connection by means of a diffusion agent.