Secondary zinc-manganese dioxide batteries for high power applications
AssigneeResearch Foundation of the City University of New York
InventorsNilesh Ingale, Tal Sholklapper, Sanjoy Banerjee, Michael Nyce
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Abstract
In an embodiment, a secondary Zn—MnO2 battery comprises a battery housing, a MnO2 cathode, a Zn anode, and an electrolyte solution. The MnO2 cathode, the Zn anode, and the electrolyte solution are disposed within the battery housing, and the MnO2 cathode comprises a MnO2 cathode mixture and a current collector. The MnO2 cathode mixture is in electrical contact with at least a portion of an outer surface of the current collector, and the MnO2 cathode has a porosity of from about 5 vol. % to about 90 vol. %, based on the total volume of the MnO2 cathode mixture of the MnO2 cathode.
Claims28
A non-flow secondary Zn—MnO2 battery comprising:
- a battery housing;
- a MnO2 cathode, wherein a MnO2 cathode mixture comprises MnO2 in an amount of from 45 wt. % to 80 wt. %;
- a Zn anode;
- an electrode separator membrane disposed between the MnO2 cathode and the Zn anode;
- and
- an electrolyte solution,
- wherein the MnO2 cathode, the Zn anode, and the electrolyte solution are disposed within the battery housing,
- wherein the MnO2 cathode comprises a MnO2 cathode mixture and a current collector,
- wherein the MnO2 cathode mixture is in electrical contact with at least a portion of an outer surface of the current collector,
- wherein the MnO2 cathode has a porosity of from 5 vol. % to 90 vol. %, based on the total volume of the MnO2 cathode mixture of the MnO2 cathode, and
- wherein an amount of inert material in the MnO2 cathode and the Zn anode, a thickness of the electrode separator membrane, a binder in the MnO2 cathode or the Zn anode, a placement of a current collector tab on the current collector for the MnO2 cathode, and a size and shape of the MnO2 cathode and the Zn anode are configured to provide a current density during the discharging of greater than 180 mA/cm2, wherein the current density of the non-flow secondary Zn—MnO2 battery is an amount of current that passes through the non-flow secondary Zn—MnO2 battery per a total unit surface area of the MnO2 cathode and a non-flow cell Zn anode.
Dependencies are inferred from the claim text.