# US 11,994,481 B2 · Concentration measurement device

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- Number: US 11,994,481 B2
- Document ID: US11994481B2
- Status: Granted
- Kind: B2
- Application number: 17/434,963
- Filed: 2020-03-17
- Published: 2022-05-05
- Granted: 2024-05-28
- Earliest claimed: 2019-03-19
- Assignees: OMRON Corporation
- Applicants: OMRON Corporation
- Inventors: Susumu Kamiyama; Hajime Kano; Shinya Nakagawa; Hideyuki Nakao; Kenichi Handa; Takashi Kasai
- Web page: https://patentgrep.com/patent/US11994481B2

## CPC

- G01N 25/18: by investigating thermal conductivity (by calorimetry G01N25/20; by measuring change of resistance of an electrically-heated body G01N27/18)
- G01N 27/18: caused by changes in the thermal conductivity of a surrounding material to be tested (G01N27/20 takes precedence)
- G01N 33/0004: {Gaseous mixtures, e.g. polluted air}
- G01N 33/225: {Gaseous fuels, e.g. natural gas}
- G01N: INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES (measuring or testing apparatus or processes other than immunoassay, involving enzymes or microorganisms C12M, C12Q)

## Abstract

It is possible to reduce a decrease in accuracy of measuring the concentration of a measurement target gas even in a case where, in a mixture of gases, there is a gas greatly different from another gas in a rate of change in thermal conductivity with respect to temperature. The concentration measurement device includes a sensor configured to measure the concentration of a measurement target gas in a mixture of gases on the basis of thermal conductivity of the measurement target gas, the mixture of gases including two or more components, and a heating unit configured to heat the mixture of gases so that the concentration of the measurement target gas can be uniquely determined with respect to the thermal conductivity.

## Claims

### Claim 1

A concentration measurement device comprising:
a sensor configured to measure a concentration of a measurement target gas in a mixture of gases on the basis of thermal conductivity of the measurement target gas, the mixture of gases including two or more components; and
a heating unit configured to heat the mixture of gases so that the concentration of the measurement target gas can be uniquely determined with respect to the thermal conductivity,
wherein:
the sensor includes a pair of thermoelectromotive devices in which electromotive force according to temperature is generated and a heating unit that is placed between the pair of thermoelectromotive devices and that generates heat according to an applied voltage, and measures a flow rate of the mixture of gases according to the electromotive force generated in the pair of thermoelectromotive devices heated by the heating unit,
the concentration measurement device further includes a controller configured to control a voltage applied to the heating unit, and
the controller applies, to the heating unit, a second voltage higher than a first voltage that is applied when measuring a flow rate of the mixture of gases, and causes the sensor to measure a concentration of the measurement target gas.

### Claim 2 (depends on 1)

The concentration measurement device according to claim 1, the concentration measurement device further comprising a thermometer configured to measure temperature of the mixture of gases, wherein
the controller stores, for each temperature of the mixture of gases, a correspondence between a range in which the concentration of the measurement target gas can be uniquely determined on the basis of electromotive force generated in the thermoelectromotive device and a voltage applied to the heating unit, and
the controller acquires temperature of the mixture of gases measured by the thermometer and determines the second voltage by referring to the correspondence on the basis of the acquired temperature.

### Claim 3 (depends on 1)

The concentration measurement device according to claim 1, the concentration measurement device being configured to be applied to a concentrator configured to generate a concentrated gas in which concentrations of two or more predetermined components in air are increased, wherein
the mixture of gases is a concentrated gas concentrated by the concentrator, and
the measurement target gas is a gas including the two or more predetermined components included in the concentrated gas.

### Claim 4 (depends on 3)

The concentration measurement device according to claim 3,
wherein
the concentrator removes nitrogen from air including nitrogen, oxygen, and argon to generate a concentrated gas in which concentrations of oxygen and argon are increased,
the predetermined component includes oxygen and argon, and
the sensor is provided on a flow path through which the concentrator supplies the concentrated gas.
