# US 11,994,135 B2 · Method and apparatus for compressing a gas feed with a variable flow rate

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- Number: US 11,994,135 B2
- Document ID: US11994135B2
- Status: Granted
- Kind: B2
- Application number: 17/346,856
- Filed: 2021-06-14
- Published: 2022-12-15
- Granted: 2024-05-28
- Earliest claimed: 2021-06-14
- Assignees: Air Products and Chemicals, Inc.
- Applicants: Air Products and Chemicals, Inc.
- Inventors: David M. Espie; Gregory W. Henzler; Zhong-Xiang (John) Zhu; Graeme Richard Wilson
- Web page: https://patentgrep.com/patent/US11994135B2

## CPC

- F04D 17/12: Multi-stage pumps
- F04D 27/0223: {Control schemes therefor}
- C25B 1/04: by electrolysis of water
- C25B 15/081: {Supplying products to non-electrochemical reactors that are combined with the electrochemical cell, e.g. Sabatier reactor}
- F04D 25/16: Combinations of two or more pumps {; Producing two or more separate gas flows}
- F04D 27/02: Surge control {(surge detection F04D27/001)}
- F04D 27/0207: {by bleeding, bypassing or recycling fluids (influencing the boundary layer by an uncontrolled bleeding of the working fluid F04D29/681)}
- F04D 27/0269: {by changing flow path between different stages or between a plurality of compressors; load distribution between compressors}
- F04D 29/122: {especially adapted for elastic fluid pumps}
- F04D: NON-POSITIVE-DISPLACEMENT PUMPS (engine fuel-injection pumps F02M; ion pumps H01J41/12; electrodynamic pumps H02K44/02)
- C25B: ELECTROLYTIC OR ELECTROPHORETIC PROCESSES FOR THE PRODUCTION OF COMPOUNDS OR NON-METALS; APPARATUS THEREFOR (anodic or cathodic protection C23F13/00; single-crystal growth C30B)

## Abstract

Energy efficiency and/or operational stability of a multistage compression system comprising a plurality (N) of centrifugal compressors that is compressing a gas feed having a variable flow rate is improved by adjusting reversibly the load on each compressor in response to changes in the flow rate of the gas feed using a main recycle system to enable operation of the centrifugal compressors at turndown capacity during periods when the flow rate is below total turndown capacity for all of the compressors, and if necessary, using the local recycle systems in order to avoid activation of anti-surge control, and switching one or more centrifugal compressors into low power mode or shutdown mode as required.

## Claims

### Claim 1

A process for operating a multistage compression system compressing a gas feed having a variable flow rate,
said multistage compression system comprising a feed end, a plurality (N) of centrifugal compressors in parallel, a product end, and a main recycle system for recycling gas through the plurality (N) of centrifugal compressors, wherein each centrifugal compressor comprises an inlet, an outlet, and a local recycle system with anti-surge control for recycling gas from the outlet to the inlet, said process comprising:
(a) during periods when the gas feed is received by the multistage compression system at a flow equal to the total maximum capacity of a first number (n) of centrifugal compressors producing net compressed gas, operating said first number (n) of centrifugal compressors at full load for compressing the gas feed;
(b) during periods when the gas feed is received by the multistage compression system at a flow in a range from less than total maximum capacity of said first number (n) of centrifugal compressors to total turndown capacity of said first number (n) of centrifugal compressors, operating said first number (n) of centrifugal compressors at minimum load for compressing the gas feed, said minimum load being determined based on the flow of the gas feed;
(c) during periods when the gas feed is received by the multistage compression system at a flow in a range from less than total turndown capacity of the first number (n) of centrifugal compressors to more than total maximum capacity for a second number (n−1) of centrifugal compressors producing net compressed gas, recycling compressed gas using the main recycle system as required to maintain the load of said first number (n) of centrifugal compressors above the point at which the anti-surge controls are activated; and
(d) during periods when the gas feed is received by the multistage compression system at a flow equal to the total maximum capacity for said second number (n−1) of centrifugal compressors, unloading a centrifugal compressor to put said compressor into a low power mode or shutdown mode in which said compressor produces no net compressed gas, while simultaneously loading the remaining centrifugal compressors to maximum capacity,
wherein the process is reversible at any point, and wherein n is a whole number equal to or less than N.

### Claim 2 (depends on 1)

The process according to claim 1, wherein the gas for compression is hydrogen gas.

### Claim 3 (depends on 2)

The process according to claim 2, wherein the hydrogen gas is produced by electrolysis of water.

### Claim 4 (depends on 1)

The process according to claim 1, wherein the gas for compression is produced at least in part using electricity generated from at least one renewable energy source.

### Claim 5 (depends on 1)

The process according to claim 1, wherein during periods specified in (b) the turndown capacity of each centrifugal compressor is defined as the minimum flow of gas that can be compressed by the centrifugal compressor without activation of its anti-surge control.

### Claim 6 (depends on 1)

The process according to claim 1, wherein during periods specified in (b) the turndown capacity of each centrifugal compressor is from 60% or more of maximum gas flow through the centrifugal compressor.

### Claim 7 (depends on 1)

The process according to claim 1, wherein during periods specified in (b) the flow of the gas feed is distributed uniformly across all (n) centrifugal compressors at minimum load.

### Claim 8 (depends on 1)

The process according to claim 1, wherein during periods specified in (c) the amount of recycling of compressed gas is maintained at a minimum amount to conserve electricity.

### Claim 9 (depends on 1)

The process according to claim 1, wherein during periods specified in (d) the unloading of the centrifugal compressor comprises first reducing the flow of net compressed gas through said centrifugal compressor to zero using the local recycle system, and second reducing the load of said centrifugal compressor.

### Claim 10 (depends on 1)

The process according to claim 1, wherein putting a centrifugal compressor in low power mode comprises reducing the rotor speed of the centrifugal compressor to a speed that is still sufficient to prevent contact of opposed seal faces of a dry gas seal within the centrifugal compressor.

### Claim 11 (depends on 1)

The process according to claim 1, wherein unloading to put a centrifugal compressor in said low power mode comprises reducing its rotor speed to within a range of from about 100 rpm to about 1500 rpm and operating such that it produces no net compressed gas.

### Claim 12 (depends on 1)

The process according to claim 1, wherein during operation in said low power mode the centrifugal compressor is operating with a power of about 20% or less relative to maximum power and producing no net compressed gas.

### Claim 13 (depends on 1)

A process for supplying compressed hydrogen gas for consumption in at least one downstream process, comprising:
producing said hydrogen gas from electrolysis of water,
compressing said hydrogen gas in a multistage compression system operated according to claim 1, and
feeding said compressed hydrogen gas to at least one downstream process for consumption in said downstream process(es).

### Claim 14 (depends on 13)

The process according to claim 13, wherein at least some of the compressed hydrogen gas is used to produce ammonia and/or methanol in the downstream process(es).

### Claim 15 (depends on 1)

An apparatus for operating a multistage compression system compressing a gas feed having a variable flow rate according to claim 1, said apparatus comprising:
a multistage compression system comprising a feed end, a plurality (N) of centrifugal compressors in parallel, a product end, and a main recycle system for recycling gas through the plurality (N) of centrifugal compressors, wherein each centrifugal compressor comprises an inlet, an outlet, and a local recycle system with anti-surge control that recycles gas from the outlet to the inlet;
a control system for controlling the load of each centrifugal compressor and for controlling the amount of recycling by the main recycle system and local recycle system, as required, based on the flow of the feed gas.

### Claim 16 (depends on 15)

The apparatus according to claim 15, comprising:
an electricity generation system for generating electricity from at least one renewable energy source, and wherein the gas for compression is produced at least in part using electricity generated from said electricity generation system.

### Claim 17 (depends on 15)

The apparatus according to claim 15, wherein the gas for compression is hydrogen gas, the apparatus comprising:
a plurality of electrolysers for producing said hydrogen gas,
wherein the electrolysers are powered at least in part by electricity generated from said electricity generation system, and
wherein said feed end of said multistage compression system is in fluid flow communication with said plurality of electrolysers.

### Claim 18 (depends on 15)

The apparatus according to claim 15, comprising at least one downstream processing unit for consuming compressed gas, said downstream processing unit(s) being in fluid flow communication with said outlet end of said multistage compression system.

### Claim 19 (depends on 15)

The apparatus according to claim 15, comprising:
a storage system for storing compressed gas, said storage system being in fluid flow communication with said outlet end of said multistage compression system and at least one compressor of said multistage compression system; and
a second control system for controlling pressure and flow of compressed gas from said multistage compression system to said storage system and for controlling pressure and flow of compressed gas from said storage system to said compressor(s) of said multistage compression system based on the flow of the gas feed to the multistage compression system.