# US 11,993,758 B2 · Tunable processes for the continuous refining of edible oils and fats > Agents: this data is available as JSON from the patentgrep API and MCP server — see https://patentgrep.com/llms.txt - Number: US 11,993,758 B2 - Document ID: US11993758B2 - Status: Granted - Kind: B2 - Application number: 17/660,549 - Filed: 2022-04-25 - Published: 2023-10-26 - Granted: 2024-05-28 - Earliest claimed: 2022-04-25 - Assignees: Chemtor, LP - Applicants: Chemtor, LP - Inventors: Rana K. Mohamed - Web page: https://patentgrep.com/patent/US11993758B2 ## CPC - C11B 3/06: with bases - B01J 19/0093: {Microreactors, e.g. miniaturised or microfabricated reactors (laboratory containers with capillary fluid transport in microfabricated channels or chambers B01L3/5027)} - C11B 3/006: {by extraction} - C11C 3/003: {by esterification of fatty acids with alcohols (C11C3/02 takes precedence)} - C07C 51/41: Preparation of salts of carboxylic acids ({C07C51/093 - C07C51/34 take precedence} preparation of soap C11D) - Y02W 30/74: Recovery of fats, fatty oils, fatty acids or other fatty substances, e.g. lanolin or waxes - C11B: PRODUCING, e.g. BY PRESSING RAW MATERIALS OR BY EXTRACTION FROM WASTE MATERIALS, REFINING OR PRESERVING FATS, FATTY SUBSTANCES, e.g. LANOLIN, FATTY OILS OR WAXES; ESSENTIAL OILS; PERFUMES (drying-oils C09F) - B01J: CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS - C11C: FATTY ACIDS FROM FATS, OILS OR WAXES; CANDLES; FATS, OILS OR FATTY ACIDS BY CHEMICAL MODIFICATION OF FATS, OILS, OR FATTY ACIDS OBTAINED THEREFROM - C07C: ACYCLIC OR CARBOCYCLIC COMPOUNDS - Y02W: CLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT ## Abstract A system for purifying edible oils includes a plurality of microchannel fiber reactors arranged in series. The edible oils may be first neutralized with an alkali solution and then washed with water to thereby remove impurities such as free fatty acids, mono- and diacylglycerols, phospholipids, glycolipids, trace metals, and unsaponifiable matter. The system allows for continuous, high-yield production of improved quality edible oils. ## Claims ### Claim 1 A method for purifying an edible oil, comprising: simultaneously introducing the edible oil comprising at least one impurity and an aqueous reactant solution into a first end of a first microchannel fiber reactor, the first microchannel fiber reactor having a plurality of fibers disposed therein; collecting reaction products from a reaction between the edible oil and the aqueous reactant solution in a first separator positioned proximate a second end of the first microchannel fiber reactor opposite the first end thereof, the reaction products comprising a neutralized oil and an aqueous effluent, the aqueous effluent comprising at least a portion of the at least one impurity; separately removing the neutralized oil and the aqueous effluent from the first separator; simultaneously introducing the neutralized oil and water into a first end of a second microchannel fiber reactor, the second microchannel fiber reactor having a plurality of fibers disposed therein; collecting wash reaction products from a reaction between the neutralized oil and water in a second separator positioned proximate a second end of the second microchannel fiber reactor opposite the first end thereof, the wash reaction products comprising a washed oil and a second aqueous effluent, the second aqueous effluent comprising water and at least one compound from the neutralized oil; wherein the wash reaction products further comprise a first pure edible oil and the wash reaction products form three distinct layers in the second separator. ### Claim 2 (depends on 1) The method of claim 1, wherein the edible oil is solid at room temperature and the method includes heating the edible oil to a temperature equal to or greater than a melting point of the edible oil. ### Claim 3 (depends on 1) The method of claim 1, wherein the aqueous reactant comprises an alkali solution. ### Claim 4 (depends on 1) The method of claim 1, further comprising washing the washed oil with water in a third microchannel fiber reactor to produce a second pure edible oil having a composition that is distinct from the first pure edible oil. ### Claim 5 (depends on 4) The method of claim 4, wherein the second pure edible oil has a higher content of free fatty acids than the first pure edible oil. ### Claim 6 (depends on 4) The method of claim 4, wherein the first edible oil has a different content of phospholipids as compared to the second edible oil. ### Claim 7 A method for purifying an edible oil, comprising: simultaneously introducing the edible oil comprising at least one impurity and an aqueous reactant solution into a first end of a first microchannel fiber reactor, the first microchannel fiber reactor having a plurality of fibers disposed therein; collecting reaction products from a reaction between the edible oil and the aqueous reactant solution in a first separator positioned proximate a second end of the first microchannel fiber reactor opposite the first end thereof, the reaction products comprising a neutralized oil and an aqueous effluent, the aqueous effluent comprising at least a portion of the at least one impurity; separately removing the neutralized oil and the aqueous effluent from the first separator; simultaneously introducing the neutralized oil and water into a first end of a second microchannel fiber reactor, the second microchannel fiber reactor having a plurality of fibers disposed therein; collecting wash reaction products from a reaction between the neutralized oil and water in a second separator positioned proximate a second end of the second microchannel fiber reactor opposite the first end thereof, the wash reaction products comprising a washed oil and a second aqueous effluent, the second aqueous effluent comprising water and at least one compound from the neutralized oil; wherein a weight ratio of free fatty acids in the washed oil to free fatty acids in the edible oil is less than 0.2. ### Claim 8 (depends on 7) The method of claim 7, wherein the edible oil is solid at room temperature and the method includes heating the edible oil to a temperature equal to or greater than a melting point of the edible oil. ### Claim 9 (depends on 7) The method of claim 7, wherein the aqueous reactant comprises an alkali solution. ### Claim 10 (depends on 7) The method of claim 7, wherein the washed oil is a first pure edible oil, the wash reaction products further comprise a raffinate and the wash reaction products form three distinct layers in the second separator wherein the raffinate forms a layer between the first pure edible oil and the second aqueous effluent. ### Claim 11 (depends on 10) The method of claim 10, further comprising washing the raffinate with water in a third microchannel fiber reactor to produce a second pure edible oil having a composition that is distinct from the first pure edible oil. ### Claim 12 (depends on 10) The method of claim 10, wherein the second pure edible oil has a higher content of free fatty acids than the first pure edible oil. ### Claim 13 (depends on 10) The method of claim 10, wherein the first edible oil has a different content of phospholipids as compared to the second edible oil.